4-Isopropenylphenol is an
organic compound
In chemistry, organic compounds are generally any chemical compounds that contain carbon-hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The ...
with the formula . The molecule consists of a
2-propenyl group (CH
2=''C''-CH
3) affixed to the 4 position of
phenol
Phenol (also called carbolic acid) is an aromatic organic compound with the molecular formula . It is a white crystalline solid that is volatile. The molecule consists of a phenyl group () bonded to a hydroxy group (). Mildly acidic, it req ...
. The compound is an intermediate in the production of
bisphenol A
Bisphenol A (BPA) is a chemical compound primarily used in the manufacturing of various plastics. It is a colourless solid which is soluble in most common organic solvents, but has very poor solubility in water. BPA is produced on an industrial s ...
(BPA), 2.7 Mkg/y of which are produced annually (2007). It is also generated by the recycling of ''o,p''-BPA, a byproduct of the production of the ''p,p''-isomer of BPA.
Synthesis and reactions
The high-temperature hydrolysis of BPA gives the title compound together with phenol:
:
The compound can also be produced by catalytic dehydrogenation of
4-isopropylphenol.
4-Isopropenylphenol undergoes ''O''-protonation by
sulfuric acid
Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid ( Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen and hydrogen, with the molecular formu ...
, giving the
carbocation
A carbocation is an ion with a positively charged carbon atom. Among the simplest examples are the methenium , methanium and vinyl cations. Occasionally, carbocations that bear more than one positively charged carbon atom are also encountere ...
, which undergoes a variety of dimerization reactions.
References
{{DEFAULTSORT:Isopropenylphenol, p-
Phenols
Commodity chemicals
Isopropenyl compounds