Oxycation
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In
chemistry Chemistry is the science, scientific study of the properties and behavior of matter. It is a natural science that covers the Chemical element, elements that make up matter to the chemical compound, compounds made of atoms, molecules and ions ...
, an oxycation is a
polyatomic ion A polyatomic ion, also known as a molecular ion, is a covalent bonded set of two or more atoms, or of a metal complex, that can be considered to behave as a single unit and that has a net charge that is not zero. The term molecule may or may not ...
with a
positive charge Electric charge is the physical property of matter that causes charged matter to experience a force when placed in an electromagnetic field. Electric charge can be ''positive'' or ''negative'' (commonly carried by protons and electrons respectiv ...
that contains
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as wel ...
.


Examples

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Dioxygenyl The dioxygenyl ion, , is a rarely-encountered oxycation in which both oxygen atoms have a formal oxidation state of . It is formally derived from oxygen by the removal of an electron: :O2 → + e− The energy change for this process is call ...
ion, *
Nitrosonium The nitrosonium ion is , in which the nitrogen atom is bonded to an oxygen atom with a bond order of 3, and the overall diatomic species bears a positive charge. It can be viewed as nitric oxide with one electron removed. This ion is usually obta ...
ion, *
Nitronium The nitronium ion, , is a cation. It is an onium ion because its nitrogen atom has +1 charge, similar to ammonium ion . It is created by the removal of an electron from the paramagnetic nitrogen dioxide molecule , or the protonation of nitric aci ...
ion, *
Vanadyl ion The vanadyl or oxovanadium(IV) cation, VO2+, is a functional group that is common in the coordination chemistry of vanadium. Complexes containing this functional group are characteristically blue and paramagnetic. A triple bond is proposed to ...
, VO2+, a very stable oxycation *
Uranyl The uranyl ion is an oxycation of uranium in the oxidation state +6, with the chemical formula . It has a linear structure with short U–O bonds, indicative of the presence of multiple bonds between uranium and oxygen. Four or more ligands may ...
ion, , all natural U6+ occurs in this form * Zirconyl ion, as a tetramer of r(OH)2sup>2+ See
category Category, plural categories, may refer to: Philosophy and general uses * Categorization, categories in cognitive science, information science and generally *Category of being * ''Categories'' (Aristotle) *Category (Kant) *Categories (Peirce) * ...
for a bigger list.


See also

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Oxyanion An oxyanion, or oxoanion, is an ion with the generic formula (where A represents a chemical element and O represents an oxygen atom). Oxyanions are formed by a large majority of the chemical elements. The formulae of simple oxyanions are determine ...
*
List of aqueous ions by element This table lists the ionic species that are most likely to be present, depending on pH, in aqueous solutions of binary salts of metal ions. The existence must be inferred on the basis of indirect evidence provided by modelling with experimental da ...


External links

* Cations {{Inorganic-compound-stub