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Olefin fiber is a synthetic fiber made from a
polyolefin A polyolefin is a type of polymer with the general formula (CH2CHR)n where R is an alkyl group. They are usually derived from a small set of simple olefins (alkenes). Dominant in a commercial sense are polyethylene and polypropylene. More special ...
, such as polypropylene or
polyethylene Polyethylene or polythene (abbreviated PE; IUPAC name polyethene or poly(methylene)) is the most commonly produced plastic. It is a polymer, primarily used for packaging (plastic bags, plastic films, geomembranes and containers including bott ...
. It is used in wallpaper, carpeting, ropes, and vehicle interiors. Olefin's advantages are its strength, colorfastness and comfort, its resistance to staining, mildew, abrasion, and sunlight, and its good bulk and cover.


History

Italy began production of olefin fibers in 1957. The chemist
Giulio Natta Giulio Natta (26 February 1903 – 2 May 1979) was an Italian chemical engineer and Nobel laureate. He won a Nobel Prize in Chemistry in 1963 with Karl Ziegler for work on high polymers. He also received a Lomonosov Gold Medal in 1969. Biography ...
successfully formulated olefin suitable for more textile applications. Both Natta and Karl Ziegler were later awarded the Nobel Prize for their work on transition metal catalysis of olefins to fiber, also known as Ziegler–Natta catalysis. Production of olefin fibers in the
U.S. The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territo ...
began in 1960. Olefin fibers account for 16% of all manufactured fibers.


Major fiber properties

Olefin fibers have great bulk and cover while having low specific gravity. This means “Warmth without the weight.” The fibers have low moisture absorption, but they can wick moisture and dry quickly. Olefin is abrasion, stain, sunlight, fire, and chemical resistant. It does not dye well, but has the advantage of being colorfast. Since Olefin has a low melting point, textiles can be thermally bonded. The fibers have the lowest static of all manufactured fibers and a medium luster. One of the most important properties of olefin is its strength. It keeps its strength in wet or dry conditions and is very resilient. The fiber can be produced for strength of different properties.


Production method

The
Federal Trade Commission The Federal Trade Commission (FTC) is an independent agency of the United States government whose principal mission is the enforcement of civil (non-criminal) antitrust law and the promotion of consumer protection. The FTC shares jurisdiction ov ...
's official definition of olefin fiber is “A manufactured fiber in which the fiber forming substance is any long-chain synthetic polymer composed of at least 85% by weight of
ethylene Ethylene ( IUPAC name: ethene) is a hydrocarbon which has the formula or . It is a colourless, flammable gas with a faint "sweet and musky" odour when pure. It is the simplest alkene (a hydrocarbon with carbon-carbon double bonds). Ethylene ...
,
propylene Propylene, also known as propene, is an unsaturated organic compound with the chemical formula CH3CH=CH2. It has one double bond, and is the second simplest member of the alkene class of hydrocarbons. It is a colorless gas with a faint petrole ...
, or other olefin units” Polymerization of propylene and ethylene gases, controlled with special catalysts, creates olefin fibers. Dye is added directly to the polymer before
melt spinning Melt spinning is a metal forming technique that is typically used to form thin ribbons of metal or alloys with a particular atomic structure. Some important commercial applications of melt spun metals include high-efficiency transformers (Amorp ...
is applied. Additives, polymer variations and different process conditions can create a range of characteristics. High pressure production, which uses ten tons per square inch, creates a film for molded materials. Low pressure production uses a low temperature with a catalyst and hydrocarbon solvent. This process is less expensive and produces a polyethylene polymer more for textile use. The polymer is then melted, spun, by a
spinneret A spinneret is a silk-spinning organ of a spider or the larva of an insect. Some adult insects also have spinnerets, such as those borne on the forelegs of Embioptera. Spinnerets are usually on the underside of a spider's opisthosoma, and are ...
into water, or air cooled. The fiber is drawn out to six times the spun length.
Gel spinning A gel is a semi-solid that can have properties ranging from soft and weak to hard and tough. Gels are defined as a substantially dilute cross-linked system, which exhibits no flow when in the steady-state, although the liquid phase may still di ...
is a new method in which a gel form of polyethylene polymers is used.


Physical and chemical structure


Physical

Olefin fibers can be multi- or monofilament and staple, tow, or film yarns. The fibers are colorless and round in cross section. This cross section can be modified for different end uses. The physical characteristics are a waxy feel and colorless.


Chemical

There are two types of polymers that can be used in olefin fibers. The first, polyethylene, is a simple linear structure with repeating units. These fibers are used mainly for ropes, twines and utility fabrics. The second type, polypropylene, is a three-dimensional structure with a backbone of carbon atoms. Methyl groups protrude from this backbone. Stereoselective polymerization orders these methyl groups to the same spatial placement. This creates a crystalline polypropylene polymer. The fibers made with these polymers can be used in apparel, furnishing and industrial products.


Manufacturers

The first commercial producer of an olefin fiber in the
United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territo ...
was Hercules, Inc. (FiberVisions). Other U.S. olefin fiber producers include Asota; American Fibers and Yarns Co; American Synthetic Fiber, LLC; Color-Fi; FiberVisions; Foss Manufacturing Co., LLC; Drake Extrusion; Filament Fiber Technology, Inc.; TenCate Geosynthetics; Universal Fiber Systems LLC.


Trademarks according to fabric use

Producer – Allied-Signal *A.C.E. – Tire cord, furniture webbing Producer – DuPont *CoolMax – Warm-weather and action wear *Hollofil, Quallofil – Fiberfill and insulating fibers *Sontara – Spunlaced nonwoven fabrics *Thermostat – Cold-weather wear *Thermoloft – Fiberfill and insulating fibers *
Tyvek Tyvek () is a brand of chemical synthesis, synthetic flashspun high-density polyethylene fibers. The name "Tyvek" is a registered trademark of the American multinational chemical company DuPont, which discovered and commercialized Tyvek in the l ...
– Used for house wraps to postal envelopes to clothing Producer – Trevira *ESP – Apparel and furnishings *Celwet – Nonwovens *Comfort Fiber – Staple fiber for apparel uses *Floor Guardian – Gym Floor Carpet Protection System *Loftguard – Staple fiber for industrial uses *Polar Guard *Lambda – Filament yarns with spun-yarn characteristics *Serene *Superba *Trevira HT – Marine and military uses; ropes, cordages *Trevira ProEarth – Recycled-content geotextiles *Trevira XPS – Carpeting *BTU – Cold-weather apparel Producer – 3M *
Thinsulate Thinsulate is a brand of synthetic fiber thermal insulation used in clothing. The word is a portmanteau of the words ''thin'' and ''insulate'', trademarked by 3M. The material is made by the 3M Corporation and was first sold in 1979. It was origi ...
– Cold-weather action wear


Uses


Apparel

Sports & active wear, socks, hoodies, thermal underwear; lining fabrics.


Home furnishing

Olefin can be used by itself or in blends for indoor and outdoor carpets, carpet tiles, and carpet backing. The fiber can also be used in upholstery, draperies, wall coverings, slipcovers, and floor coverings. It is often used in basements due to its quick-drying and mold-resistant properties.


Automotive

Olefin can be used for interior fabrics, sun visors, arm rests, door and side panels, trunks, parcel shelves, and resin replacement as binder fibers.


Industrial

In an industrial setting, olefin creates carpets; ropes, geo-textiles that are in contact with the soil, filter fabrics, bagging, concrete reinforcement, and heat-sealable paper (e.g. tea- and coffee-bags).


Care procedures

When dry-cleaned, many dry-cleaning solvents can swell Olefin fibers. Since Olefin dries quickly, line drying and low tumble drying with little or no heat is recommended. Since Olefin is not absorbent, waterborne stains do not present a problem. However, oily stains are difficult to remove, though lukewarm water, detergent, and bleach can be used to remove such stains. Olefin fiber has a low melting point (around 225 to 335 °F, depending on the polymer's grade) so care must be taken to iron these at a low temperature, as to prevent melting. Items such as outdoor carpets and other fabrics can be hosed off. Olefin is easy to recycle.


See also

*
Alkene In organic chemistry, an alkene is a hydrocarbon containing a carbon–carbon double bond. Alkene is often used as synonym of olefin, that is, any hydrocarbon containing one or more double bonds.H. Stephen Stoker (2015): General, Organic, a ...
* Elastolefin


References

{{DEFAULTSORT:Olefin Fiber Synthetic fibers