Oneillite is a rare mineral of the eudialyte group with the chemical formula .Mindat, Oneillite, http://www.mindat.org/min-11029.htmlJohnsen, O., Grice, J.D., and Gault, R.A., 1999. Oneillite: a new Ca-deficient and ''REE''-rich member of the eudialyte group from Mont Saint-Hilaire, Quebec, Canada. The Canadian Mineralogist 37, 1295-1301 The formula is based on the original one but extended to show the presence of cyclic silicate groups and domination of Si at the M4 site. The mineral has lowered symmetry (space group ''R''3, instead of more specific for the group ''R''3''m'' one) due to Ca-Mn ordering. Similar feature is displayed by some other eudialyte-group members: aqualite, labyrinthite, raslakite, and voronkovite. Oneillite is strongly enriched in

rare earth elements The rare-earth elements (REE), also called the rare-earth metals or (in context) rare-earth oxides or sometimes the lanthanides (yttrium and scandium are usually included as rare earths), are a set of 17 nearly-indistinguishable lustrous sil ...

(REE, mainly

cerium Cerium is a chemical element with the symbol Ce and atomic number 58. Cerium is a soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it often shows the +3 ...

), but REE do not dominate any of its sites.

Notes on chemistry

Rare earth elements in oneillite include

lanthanum Lanthanum is a chemical element with the symbol La and atomic number 57. It is a soft, ductile, silvery-white metal that tarnishes slowly when exposed to air. It is the eponym of the lanthanide series, a group of 15 similar elements between lant ...

neodymium Neodymium is a chemical element with the symbol Nd and atomic number 60. It is the fourth member of the lanthanide series and is considered to be one of the rare-earth metals. It is a hard, slightly malleable, silvery metal that quickly tarnishe ...

, and

yttrium Yttrium is a chemical element with the symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a " rare-earth element". Yttrium is almost always found in co ...

, with minor

praseodymium Praseodymium is a chemical element with the symbol Pr and the atomic number 59. It is the third member of the lanthanide series and is considered to be one of the rare-earth metals. It is a soft, silvery, malleable and ductile metal, valued for i ...

and

gadolinium Gadolinium is a chemical element with the symbol Gd and atomic number 64. Gadolinium is a silvery-white metal when oxidation is removed. It is only slightly malleable and is a ductile rare-earth element. Gadolinium reacts with atmospheric oxygen ...

. Other impurities are

potassium Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosph ...

, and minor amounts of

aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...

hafnium Hafnium is a chemical element with the symbol Hf and atomic number 72. A lustrous, silvery gray, tetravalent transition metal, hafnium chemically resembles zirconium and is found in many zirconium minerals. Its existence was predicted by Dmitri M ...

, strontium and

tantalum Tantalum is a chemical element with the symbol Ta and atomic number 73. Previously known as ''tantalium'', it is named after Tantalus, a villain in Greek mythology. Tantalum is a very hard, ductile, lustrous, blue-gray transition metal that ...

Occurrence and association

Oneillite is one of four eudialyte-group minerals discovered within alkaline rocks of

Mont Saint-Hilaire Mont Saint-Hilaire (English: Mount Saint-Hilaire; abe, Wigwômadenizibo; see for other names) is an isolated hill, high, in the Montérégie region of southern Quebec. It is about thirty kilometres east of Montreal, and immediately east of the ...

, Quebec, Canada. It associates with

aegirine Aegirine is a member of the clino pyroxene group of inosilicate minerals. Aegirine is the sodium endmember of the aegirine-augite series. Aegirine has the chemical formula Na Fe Si2 O6 in which the iron is present as Fe3+. In the aegirine-augit ...

albite Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicate ...

sodalite Sodalite ( ) is a tectosilicate mineral with the formula , with royal blue varieties widely used as an ornamental gemstone. Although massive sodalite samples are opaque, crystals are usually transparent to translucent. Sodalite is a member of t ...

, and

pyrite The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue giv ...

References

Cyclosilicates Sodium minerals Calcium minerals Manganese minerals Iron(II) minerals Zirconium minerals Niobium minerals Trigonal minerals Minerals in space group 146 {{silicate-mineral-stub