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Oligoclase is a rock-forming
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...
belonging to the
plagioclase Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more prope ...
feldspar Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) feldsp ...
s. In chemical composition and in its crystallographic and physical characters it is intermediate between
albite Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicate ...
( Na Al Si3 O8) and anorthite ( CaAl2Si2O8). The albite:anorthite molar ratio of oligoclase ranges from 90:10 to 70:30. Oligoclase is a high sodium feldspar crystallizing in the
triclinic 180px, Triclinic (a ≠ b ≠ c and α ≠ β ≠ γ ) In crystallography, the triclinic (or anorthic) crystal system is one of the 7 crystal systems. A crystal system is described by three basis vectors. In the triclinic system, the crystal i ...
system. The
Mohs hardness The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. The scale was introduced in 1812 by t ...
is 6 to 6.5 and the
specific gravity Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water (molecule), wa ...
is 2.64 to 2.66. The
refractive indices In optics, the refractive index (or refraction index) of an optical medium is a dimensionless number that gives the indication of the light bending ability of that medium. The refractive index determines how much the path of light is bent, or ...
are: nα=1.533–1.543, nβ=1.537–1.548, and nγ=1.542–1.552. In color it is usually white, with shades of grey, green, or red. Oligoclase is a common mineral in the more
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
-rich varieties of
igneous rock Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main The three types of rocks, rock types, the others being Sedimentary rock, sedimentary and metamorphic rock, metamorphic. Igneous rock ...
and in many
metamorphic rock Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, causin ...
s.


Name and discovery

The name oligoclase was given by
August Breithaupt Johann Friedrich August Breithaupt (May 16, 1791 – September 22, 1873) was a German mineralogist and professor at Freiberg Mining Academy in Freiberg, Saxony. Biography He was born in Probstzella. He received his doctorate at the Universities ...
in 1826 from the grc, όλίγος, oligos, little, and grc, κλᾶν, klân, to break, because the mineral was thought to have a less perfect cleavage than albite. It had previously been recognized as a distinct species by J. J. Berzelius in 1824, and was named by him soda-spodumene (Natron-spodumen), because of its resemblance in appearance to
spodumene Spodumene is a pyroxene mineral consisting of lithium aluminium inosilicate, Li Al( Si O3)2, and is a source of lithium. It occurs as colorless to yellowish, purplish, or lilac kunzite (see below), yellowish-green or emerald-green hiddenite, pr ...
.


Occurrence

Perfectly colorless and transparent glassy material found at
Bakersville, North Carolina Bakersville is a town in Mitchell County, North Carolina, United States. The population was 464 at the 2010 census. It is the county seat of Mitchell County. History In prehistoric times, local mica deposits were extensively mined by Native Am ...
has occasionally been faceted as a
gemstone A gemstone (also called a fine gem, jewel, precious stone, or semiprecious stone) is a piece of mineral crystal which, in cut and polished form, is used to make jewelry or other adornments. However, certain rocks (such as lapis lazuli, opal, ...
. Another variety more frequently used as a gemstone is the
aventurine Aventurine is a form of quartz, characterised by its translucency and the presence of platy mineral inclusions that give it a shimmering or glistening effect termed ''aventurescence''. Background The most common color of aventurine is green, but ...
-feldspar or sun-stone found as reddish cleavage masses in
gneiss Gneiss ( ) is a common and widely distributed type of metamorphic rock. It is formed by high-temperature and high-pressure metamorphic processes acting on formations composed of igneous or sedimentary rocks. Gneiss forms at higher temperatures an ...
at
Tvedestrand is municipality in Agder county, Norway. It is located in the traditional district of Sørlandet. The administrative center is the town of Tvedestrand. There are many villages in the municipality including Dypvåg, Fiane, Gjeving, Gødders ...
in southern
Norway Norway, officially the Kingdom of Norway, is a Nordic country in Northern Europe, the mainland territory of which comprises the western and northernmost portion of the Scandinavian Peninsula. The remote Arctic island of Jan Mayen and t ...
; this presents a brilliant red to golden metallic glitter, due to the presence of numerous small scales of
hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
oriented within the feldspar structure. Oligoclase occurs, often accompanying
orthoclase Orthoclase, or orthoclase feldspar (endmember formula K Al Si3 O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture," because its two cleavage planes are at right angles t ...
, as a constituent of plutonic
igneous rock Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main The three types of rocks, rock types, the others being Sedimentary rock, sedimentary and metamorphic rock, metamorphic. Igneous rock ...
s such as
granite Granite () is a coarse-grained (phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies undergro ...
,
syenite Syenite is a coarse-grained intrusive igneous rock with a general composition similar to that of granite, but deficient in quartz, which, if present at all, occurs in relatively small concentrations (< 5%). Some syenites contain larger proport ...
, and
diorite Diorite ( ) is an intrusive igneous rock formed by the slow cooling underground of magma (molten rock) that has a moderate content of silica and a relatively low content of alkali metals. It is intermediate in composition between low-silic ...
. It occurs in porphyry and
diabase Diabase (), also called dolerite () or microgabbro, is a mafic, holocrystalline, subvolcanic rock equivalent to volcanic basalt or plutonic gabbro. Diabase dikes and sills are typically shallow intrusive bodies and often exhibit fine-graine ...
dikes Dyke (UK) or dike (US) may refer to: General uses * Dyke (slang), a slang word meaning "lesbian" * Dike (geology), a subvertical sheet-like intrusion of magma or sediment * Dike (mythology), ''Dikē'', the Greek goddess of moral justice * Dikes ...
and sills as well as in the
volcanic A volcano is a rupture in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface. On Earth, volcanoes are most often found where tectonic plates a ...
rocks
andesite Andesite () is a volcanic rock of intermediate composition. In a general sense, it is the intermediate type between silica-poor basalt and silica-rich rhyolite. It is fine-grained (aphanitic) to porphyritic in texture, and is composed predomi ...
and
trachyte Trachyte () is an extrusive igneous rock composed mostly of alkali feldspar. It is usually light-colored and aphanitic (fine-grained), with minor amounts of mafic minerals, and is formed by the rapid cooling of lava enriched with silica and al ...
, and in
mugearite Mugearite () is a type of oligoclase-bearing basalt, comprising olivine, apatite, and opaque oxides. The main feldspar in mugearite is oligoclase. Mugearite is a sodium-rich member of the alkaline magma series. In the TAS classification of volc ...
where its presence is a defining feature. It also occurs in gneiss. The best developed and largest crystals are those found with orthoclase,
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
,
epidote Epidote is a calcium aluminium iron sorosilicate mineral. Description Well developed crystals of epidote, Ca2Al2(Fe3+;Al)(SiO4)(Si2O7)O(OH), crystallizing in the monoclinic system, are of frequent occurrence: they are commonly prismatic in hab ...
, and
calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
in veins in granite at Arendal in Norway. The distinctive texture of
rapakivi granite Rapakivi granite is a hornblende-biotite granite containing large round crystals of orthoclase each with a rim of oligoclase (a variety of plagioclase). The name has come to be used most frequently as a textural term where it implies plagioclase r ...
is due to oligoclase rims on orthoclase
phenocryst 300px, feldspathic phenocrysts. This granite, from the Switzerland">Swiss side of the Mont Blanc massif, has large white plagioclase phenocrysts, triclinic minerals that give trapezoid shapes when cut through). 1 euro coins, 1 euro coin (diameter ...
s. Oligoclase is also found in
metamorphic rocks Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, caus ...
formed under transitional
greenschist Greenschists are metamorphic rocks that formed under the lowest temperatures and pressures usually produced by regional metamorphism, typically and 2–10 kilobars (). Greenschists commonly have an abundance of green minerals such as chlorite ...
to amphibolite facies conditions.


Schiller iridescence

Some examples are called moonstone and show Schiller iridescence due to the presence of
exsolution A solid solution, a term popularly used for metals, is a homogenous mixture of two different kinds of atoms in solid state and have a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The wor ...
lamellae on cooling in the peristerite
miscibility gap A miscibility gap is a region in a phase diagram for a mixture of components where the mixture exists as two or more phases – any region of composition of mixtures where the constituents are not completely miscible. The IUPAC Gold Book defines ...
, ~An5-An18.


References

* Hurlbut, Cornelius S.; Klein, Cornelis, 1985, ''Manual of Mineralogy'', 20th ed., Wiley,
Webmineral data




Gemstones Tectosilicates Sodium minerals Calcium minerals Feldspar Triclinic minerals {{silicate-mineral-stub