Nikasil
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Nikasil is a trademarked electrodeposited
lipophilic Lipophilicity (from Greek λίπος "fat" and φίλος "friendly"), refers to the ability of a chemical compound to dissolve in fats, oils, lipids, and non-polar solvents such as hexane or toluene. Such non-polar solvents are themselves lipop ...
nickel Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive but large pieces are slow to ...
matrix
silicon carbide Silicon carbide (SiC), also known as carborundum (), is a hard chemical compound containing silicon and carbon. A semiconductor, it occurs in nature as the extremely rare mineral moissanite, but has been mass-produced as a powder and crystal sin ...
coating for engine components, mainly
piston engine A reciprocating engine, also often known as a piston engine, is typically a heat engine that uses one or more reciprocating pistons to convert high temperature and high pressure into a rotating motion. This article describes the common featu ...
cylinder liner In a reciprocating engine, the cylinder is the space in which a piston travels. The inner surface of the cylinder is formed from either a thin metallic liner (also called "sleeve") or a surface coating applied to the engine block. A piston is se ...
s.


Development

Nikasil was introduced by Mahle in 1967, and initially developed to allow
Wankel engine The Wankel engine (, ) is a type of internal combustion engine using an Eccentric (mechanism), eccentric rotary combustion engine, rotary design to convert pressure into rotating motion. It was invented by German engineer Felix Wankel, and desi ...
apex seals (
NSU Ro 80 The NSU Ro 80 is a four-door, front-engine executive sedan manufactured and marketed by the West German firm NSU from 1967 until 1977. Noted for innovative, aerodynamic styling by Claus Luthe and a technologically advanced powertrain, the Ro ...
, Citroën GS Birotor and Mercedes C111) to work directly against the
aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
housing Housing, or more generally, living spaces, refers to the construction and assigned usage of houses or buildings individually or collectively, for the purpose of shelter. Housing ensures that members of society have a place to live, whether it ...
. This coating allowed aluminium
cylinder A cylinder (from ) has traditionally been a three-dimensional solid, one of the most basic of curvilinear geometric shapes. In elementary geometry, it is considered a prism with a circle as its base. A cylinder may also be defined as an infin ...
s and
piston A piston is a component of reciprocating engines, reciprocating pumps, gas compressors, hydraulic cylinders and pneumatic cylinders, among other similar mechanisms. It is the moving component that is contained by a cylinder and is made gas-tig ...
s to work directly against each other with low wear and
friction Friction is the force resisting the relative motion of solid surfaces, fluid layers, and material elements sliding against each other. There are several types of friction: *Dry friction is a force that opposes the relative lateral motion of t ...
. Unlike other methods, including
cast iron Cast iron is a class of iron–carbon alloys with a carbon content more than 2%. Its usefulness derives from its relatively low melting temperature. The alloy constituents affect its color when fractured: white cast iron has carbide impuriti ...
cylinder liners, Nikasil allowed very large cylinder bores with tight
tolerances Engineering tolerance is the permissible limit or limits of variation in: # a physical dimension; # a measured value or physical property of a material, manufacturing, manufactured object, system, or service; # other measured values (such as t ...
. This made it possible for existing engine designs to be expanded easily. The aluminium cylinders also gave a much better
heat conductivity The thermal conductivity of a material is a measure of its ability to heat conduction, conduct heat. It is commonly denoted by k, \lambda, or \kappa. Heat transfer occurs at a lower rate in materials of low thermal conductivity than in materials ...
than cast iron liners, an important attribute for a high-output engine. The coating was further developed as a replacement for hard-chrome plated cylinder bores for Mercury Marine Racing, Kohler Engines, and as a repair replacement for factory-chromed snowmobiles, dirt bikes, ATVs, watercraft and automotive V8 liners/bores. Nikasil is short for Nickel Silicon Carbide.
Silicon carbide Silicon carbide (SiC), also known as carborundum (), is a hard chemical compound containing silicon and carbon. A semiconductor, it occurs in nature as the extremely rare mineral moissanite, but has been mass-produced as a powder and crystal sin ...
is a very hard ceramic (much harder than steel) that can be dissolved in nickel. The nickel solution can then be
electroplated Electroplating, also known as electrochemical deposition or electrodeposition, is a process for producing a metal coating on a solid substrate through the reduction of cations of that metal by means of a direct electric current. The part to be ...
onto the aluminium cylinder bore. The piston rings will then rub off the exposed nickel, leaving a very hard layer of silicon carbide to prevent the cast iron/steel
piston rings A piston ring is a metallic split ring that is attached to the outer diameter of a piston in an internal combustion engine or steam engine. The main functions of piston rings in engines are: # Sealing the combustion chamber so that there is mini ...
directly contacting the aluminium cylinder. With this setup, the engine tolerances can be much tighter for better performance. The cylinder must be re-plated after it is re-bored, but Nikasil is extremely durable, so the cylinder does not need to be reworked as often as an iron or chrome cylinder.


Applications

Porsche Dr. Ing. h.c. F. Porsche AG, usually shortened to Porsche (; see #Pronunciation, below), is a German automobile manufacturer specializing in high-performance sports cars, SUVs and sedans, headquartered in Stuttgart, Baden-Württemberg, Germany ...
started using Nikasil on the 1970
917 __NOTOC__ Year 917 ( CMXVII) was a common year starting on Wednesday (link will display the full calendar) of the Julian calendar. Events By place Byzantine Empire * August 20 – Battle of Achelous: A Byzantine expeditionary fo ...
race car, and later on the 1973 911 RS. Porsche also used it on production cars, but for a short time switched to
Alusil Alusil as a hypereutectic aluminium- silicon alloy (EN AC-AlSi17Cu4Mg / EN AC-48100 or A390) contains approximately 78% aluminium and 17% silicon. This alloy was theoretically conceived in 1927 by Schweizer & Fehrenbach, of the Badener Metall-War ...
due to cost savings for their base
911 911 or 9/11 may refer to: Dates * AD 911 * 911 BC * September 11 ** 9/11, the September 11 attacks of 2001 ** 11 de Septiembre, Chilean coup d'état in 1973 that outed the democratically elected Salvador Allende * November 9 Numbers * 91 ...
. Nikasil cylinders were always used for the 911 Turbo and RS models. Nikasil coated aluminium cylinders allowed Porsche to build
air-cooled engine Air-cooled engines rely on the circulation of air directly over heat dissipation fins or hot areas of the engine to cool them in order to keep the engine within operating temperatures. In all combustion engines, a great percentage of the heat ge ...
s that had the highest
specific output Specific output is a measure of internal combustion engine performance. It describes the efficiency of an engine in terms of the brake horsepower it outputs relative to its displacement. The measure enables the comparison of differently sized engine ...
of any engine of their time. Nikasil was very popular in the 1990s. It was used by companies such as BMW,
Ducati Ducati Motor Holding S.p.A. () is the motorcycle-manufacturing division of Italian company Ducati, headquartered in Bologna, Italy. The company is directly owned by Italian automotive manufacturer Lamborghini, whose German parent company is Au ...
,
Jaguar The jaguar (''Panthera onca'') is a large cat species and the only living member of the genus '' Panthera'' native to the Americas. With a body length of up to and a weight of up to , it is the largest cat species in the Americas and the th ...
and
Moto Guzzi Moto Guzzi is an Italian motorcycle manufacturer and the oldest European manufacturer in continuous motorcycle production. Established in 1921 in Mandello del Lario, Italy, the company is noted for its historic role in Italy's motorcycling ma ...
in their new engine families. However, the
sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
found in much of the world's low-quality gasoline caused some Nikasil cylinders to break down over time, causing costly engine failures. Nikasil or similar coatings under other trademarks are also still widely used in racing engines, including those used in
Formula One Formula One (also known as Formula 1 or F1) is the highest class of international racing for open-wheel single-seater formula racing cars sanctioned by the Fédération Internationale de l'Automobile (FIA). The World Drivers' Championship, ...
and
ChampCar Champ Car World Series (CCWS) was the series sanctioned by Open-Wheel Racing Series Inc., or Champ Car, a sanctioning body for American open-wheel car racing that operated from 2004 to 2008. It was the successor to Championship Auto Racing Teams ...
. Suzuki uses a nickel phosphorus-silicon-carbide proprietary coating trademarked SCEM (Suzuki Composite Electro-chemical Material) to maximize cylinder size and improve heat dissipation in the TU250X,
Hayabusa was a robotic spacecraft developed by the Japan Aerospace Exploration Agency (JAXA) to return a sample of material from a small near-Earth asteroid named 25143 Itokawa to Earth for further analysis. ''Hayabusa'', formerly known as MUSES-C ...
, Honda NX250 Enduro, and other motorcycles.


See also

*
List of automotive superlatives Automotive superlatives include attributes such as the ''smallest'', ''largest'', ''fastest'', ''lightest'', ''best-selling'', and so on. This list (except for the firsts section) is limited to automobiles built after World War II, and lists sup ...
*
Nigusil Nigusil is a patented metal alloy created by Moto Guzzi for motorcycle cylinder liners. The name is an acronym for Nickel-Guzzi-Silicon. Moto Guzzi, having successfully created the first engine with a chromed cylinder lining, continued research ...
*
Alusil Alusil as a hypereutectic aluminium- silicon alloy (EN AC-AlSi17Cu4Mg / EN AC-48100 or A390) contains approximately 78% aluminium and 17% silicon. This alloy was theoretically conceived in 1927 by Schweizer & Fehrenbach, of the Badener Metall-War ...


References

{{reflist Engine technology Nickel alloys