Niobium Triselenide

Niobium triselenide is an inorganic compound belonging to the class of transition metal trichalcogenides. It has the formula NbSe₃. It was the first reported example of one-dimensional compound to exhibit the phenomenon of sliding charge density waves. Due to its many studies and exhibited phenomena in quantum mechanics, niobium triselenide has become the model system for quasi-1-D charge density waves.

Structure

Niobium triselenide has a highly anisotropic structure. The Nb⁴⁺ centers are bound within trigonal prisms defined by six Se ligands. Two pairs of these six Se atoms are bonded to each other to make the polyselenide ; the other two exist as the monatomic Se²⁻. The NbSe₆ prisms form infinite co-parallel chains. Although the prisms share the same coordination, the cell consists of three chain types repeated twice, where each chain is defined by its Se–Se bond length. The Se–Se bond lengths are 2.37, 2.48, and 2.91 angstroms.

Synthesis

The compound is prepared by the solid state reaction by heating niobium and selenium at 600 to 700 °C:
:Nb + 3 Se → NbSe₃
The resulting black crystals can contain NbSe₂ impurities. Samples can be purified by chemical vapor transport (CVT) between 650 and 700 °C. The lower limit of CVT was determined by the temperature at which NbSe₂ is no longer stable.

Properties

Measurements on NbSe₃ provided significant evidence for charge density wave (CDW) transport, CDW pinning, magnetism, Shubnikov-de Hass oscillations, and the Aharonov–Bohm effect.

The electrical resistivity of most metallic compounds decrease as temperature decreases. For the most part NbSe₃ follows this trend except two anomalies exist where electrical resistivity reaches two local maxima at and . The maxima result in a sharp decrease in electrical conductivity. This observation is explained by the charge density wave formations that open the gaps in the Fermi surface. The opening causes the 1-D linear system to behave more like a semiconductor and less like a metal, a transition commonly known as Peierls transition. NbSe₃ continues to be metallic despite the Peierls transition because the charge density wave formation does not completely remove the Fermi surface, a phenomenon known as imperfect Fermi surface nesting.

In the form of nanofibers, NbSe₃ exhibits superconductivity below .

Niobium triselenide has been considered as a cathode material for rechargeable lithium batteries due to its fibrous structure, high electrical conductivity, and high gravimetric and volumetric energy densities at room temperature.

References

{{selenium compounds

Niobium(IV) compounds
Selenides
Monolayers