Nikolai Semenov
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Nikolay Nikolayevich Semyonov (or Semënov), (russian: Никола́й Никола́евич Семёнов; – 25 September 1986) (often referred to in English as Semenoff, Semenov, Semionov, or Semyonova) was a Soviet physicist and chemist. Semyonov was awarded the 1956 Nobel Prize in Chemistry for his work on the mechanism of
chemical transformation A chemical substance is a form of matter having constant chemical composition and characteristic properties. Some references add that chemical substance cannot be separated into its constituent elements by physical separation methods, i.e., wi ...
.


Life and career

Semyonov was born in
Saratov Saratov (, ; rus, Сара́тов, a=Ru-Saratov.ogg, p=sɐˈratəf) is the largest city and administrative center of Saratov Oblast, Russia, and a major port on the Volga River upstream (north) of Volgograd. Saratov had a population of 901,36 ...
, the son of Elena Dmitrieva and Nikolai Alex Semyonov. He graduated from the department of physics of Petrograd University (1913–1917), where he was a student of Abram Fyodorovich Ioffe. In 1918, he moved to
Samara Samara ( rus, Сама́ра, p=sɐˈmarə), known from 1935 to 1991 as Kuybyshev (; ), is the largest city and administrative centre of Samara Oblast. The city is located at the confluence of the Volga and the Samara (Volga), Samara rivers, with ...
, where he was enlisted into
Kolchak Kolchak, Kolçak or Kolčák is a surname. Notable people with the surname include: * Iliash Kolchak ("Kolchak-Pasha") ( fl. before 1710–1743), Moldavian mercenary and military commander * Alexander Kolchak (1873–1920), Russian naval commande ...
's White Army during Russian Civil War. Semyonov published his first research paper in 1916 and became a lecturer at the University of Tomsk in western Siberia. After graduating from Saint Petersburg State University, he worked as an assistant and lecturer at the Tomsk and Tomsk University Institute of Technology, where he published his first research paper in 1916. He returned to western Siberia,
Petrograd Saint Petersburg ( rus, links=no, Санкт-Петербург, a=Ru-Sankt Peterburg Leningrad Petrograd Piter.ogg, r=Sankt-Peterburg, p=ˈsankt pʲɪtʲɪrˈburk), formerly known as Petrograd (1914–1924) and later Leningrad (1924–1991), i ...
and took charge of the electron phenomena laboratory of the Petrograd Physico-Technical Institute in 1920. He also became the vice-director of the institute. In 1921, he married philologist Maria Boreishe-Liverovsky (student of Zhirmunsky). She died two years later. On September 15-1924, Nikolay married Maria's niece, Natalia Nikolaevna Burtseva. They had two children, one son Yurii Nikolaevich and one daughter Ludmilla Nikolaevna. During that difficult time, Semyonov, together with Pyotr Kapitsa, discovered a way to measure the
magnetic field A magnetic field is a vector field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular to its own velocity and to ...
of an atomic nucleus (1922). Later the experimental setup was improved by Otto Stern and Walther Gerlach and became known as Stern–Gerlach experiment. In 1925, Semyonov, together with Yakov Frenkel, studied
kinetics Kinetics ( grc, κίνησις, , kinesis, ''movement'' or ''to move'') may refer to: Science and medicine * Kinetics (physics), the study of motion and its causes ** Rigid body kinetics, the study of the motion of rigid bodies * Chemical ki ...
of
condensation Condensation is the change of the state of matter from the gas phase into the liquid phase, and is the reverse of vaporization. The word most often refers to the water cycle. It can also be defined as the change in the state of water vapor to ...
and adsorption of vapors. In 1927, he studied ionisation in gases and published an important book, ''Chemistry of the Electron''. In 1928, he, together with Vladimir Fock, created a theory of thermal
disruptive discharge Electrical breakdown or dielectric breakdown is a process that occurs when an electrical insulating material, subjected to a high enough voltage, suddenly becomes an electrical conductor and electric current flows through it. All insulating mate ...
of dielectrics. In 1927, Semyonov studied the ionization of gases, the chemistry of the electron. In 1928, he created the theory of the broken discharge of dielectrics with Valdímir Fok. He lectured at the
Petrograd Polytechnical Institute Peter the Great St. Petersburg Polytechnic University, abbreviated as SPbPU (also, formerly "Saint Petersburg State Technical University", abbreviated as SPbSTU), is a Russian technical university located in Saint Petersburg. Other former names i ...
and was appointed Professor in 1928. In 1931, he organized the Institute of Physical Chemistry of the USSR Academy of Sciences (which moved to Chernogolovka in 1943) and became its first director. In 1932, he became a full member of the Soviet Academy of Sciences. The ideas of Semyonov have been applied in the science of reaction and production of polymerization reactions. His ideas are also applied in catalysis studies in biological systems. Semyonov married Natalya Nikolaevna Semyonov and together they both have a son and a daughter. Semyonov died on September 25, 1986 in Moscow, and was buried at the Novodevichy Cemetery.


Significant works

Semyonov's outstanding work on the mechanism of chemical transformation includes an exhaustive analysis of the application of the
chain A chain is a serial assembly of connected pieces, called links, typically made of metal, with an overall character similar to that of a rope in that it is flexible and curved in compression but linear, rigid, and load-bearing in tension. A c ...
theory to varied reactions (1934–1954) and, more significantly, to combustion processes. He proposed a theory of degenerate branching, which led to a better understanding of the phenomena associated with the induction periods of
oxidation process Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a d ...
es. He spent most of his career focusing and developing the field of chemical chain reactions. Semyonov wrote two important books outlining his work. ''Chemical Kinetics and Chain Reactions'' was published in 1934, with an English edition in 1935. It was the first book in the U.S.S.R. to develop a detailed theory of unbranched and branched chain reactions in chemistry. ''Some Problems of Chemical Kinetics and Reactivity'', first published in 1954, was revised in 1958; there are also English, American, German, and Chinese editions. He is the only Soviet/Russian Chemistry Nobel Laureate, who received the Nobel Prize in Chemistry (together with Sir Cyril Norman Hinshelwood) for his work in 1956. Semyonov had long been a supporter of the Communist Party and the Soviet Union. After the Bulletin of the Atomic Scientists accused the Soviet Union of heavy scientific censorship in 1953, he coauthored the Soviet response which denied all accusations. He is also noted as being the most famous signatory to a 1971 public letter from Soviet scientists to United States president Richard Nixon, on displeasure in the murder trial of Angela Davis. Semyonov trained Russian organometallic chemist
Alexandr Shilov Alexander Maxovich Shilov (russian: Александр Максович Шилов; born 6 October 1943) is a prominent Soviet and Russian portrait painter. Biography Shilov was born in Moscow, and between 1968 and 1973 studied at the Surikov ...
, who discovered platinum catalyzed C-H activation.


Honours and awards

* Orders of Lenin, nine times (incl. 1945, 1953, 1956, 1966, 1971, 1976, 1981) * Stalin Prize (1941, 1949) * Honorary Member of the
British Chemical Society The Chemical Society was a scientific society formed in 1841 (then named the Chemical Society of London) by 77 scientists as a result of increased interest in scientific matters. Chemist Robert Warington was the driving force behind its creation. ...
(1943) * Order of the Red Banner of Labour (1946) * Honorary member of the Indian Academy of Sciences (1954) * Nobel Prize in Chemistry (1956) * Foreign Member of the Royal Society of London (1958) * Member of the German Academy of Sciences Leopoldina (1959) * Honorary member of the
Hungarian Academy of Sciences The Hungarian Academy of Sciences ( hu, Magyar Tudományos Akadémia, MTA) is the most important and prestigious learned society of Hungary. Its seat is at the bank of the Danube in Budapest, between Széchenyi rakpart and Akadémia utca. Its ma ...
(1961) * Honorary member of the New York Academy of Sciences (1962) * Foreign member of the United States National Academy of Sciences (1963) * Honorary Member of the Romanian Academy (1965) *
Hero of Socialist Labour The Hero of Socialist Labour (russian: links=no, Герой Социалистического Труда, Geroy Sotsialisticheskogo Truda) was an honorific title in the Soviet Union and other Warsaw Pact countries from 1938 to 1991. It repre ...
, twice (1966, 1976) * Lomonosov Gold Medal (1969) * Lenin Prize (1976) * Order of the October Revolution (1986) * Medal "In commemoration of the centenary of the birth of Vladimir Ilyich Lenin" * Mendeleev Prize *5 total badges of the Order of Lenin *Honorary Member of The Soviet Academy of Sciences (1932) Semyonov was also an Honorary Doctor of several universities: Oxford (1960), Brussels (1962), London (1965), Budapest Technical University (1965), Polytechnic Institute of Milan (1964) and others.


See also

* Chain reaction * Chemical kinetics *
Chemical reaction network theory Chemical reaction network theory is an area of applied mathematics that attempts to model the behaviour of real-world chemical systems. Since its foundation in the 1960s, it has attracted a growing research community, mainly due to its applications ...
* Evans–Polanyi–Semenov principle


Reference

*Nikolay Semenov, https://persona.rin.ru/eng/view/f/0/28293/nikolay-semenov, Retrieved 27 October 2022 * Nikolay Semenov, https://www.nobelprize.org/prizes/chemistry/1956/semenov/biographical/, Retrieved 27 October 2022 * Nikolai Nikolayevich Semyonov, great physicist, chemist and mathematician, https://rinconeducativo.org/en/recursos-educativos/nikolai-nikolayevich-semionov-gran-fisico-quimico-y-matematico/, Retrieved 8 December * Nikolay Semyonov, https://www.nndb.com/people/542/000100242/ Retrieved 2019(Uns. Date Format)


External links

* including the Nobel Lecture, 11 December 1956 ''Some Problems Relating to Chain Reactions and to the Theory of Combustion'' * Semyonov's Nobel Lectur
Some Problems Relating to Chain Reactions and to the Theory of Combustion

Semyonov's Biography


{{DEFAULTSORT:Semyonov, Nikolay Nikolayevich 1896 births 1986 deaths Scientists from Saratov Saint Petersburg State University alumni Moscow Institute of Physics and Technology faculty Full Members of the USSR Academy of Sciences Foreign Members of the Royal Society Foreign associates of the National Academy of Sciences Members of the French Academy of Sciences Nobel laureates in Chemistry Heroes of Socialist Labour Recipients of the Order of Lenin Stalin Prize winners Lenin Prize winners Recipients of the Lomonosov Gold Medal Soviet chemists Soviet physicists Tomsk State University faculty Tomsk Polytechnic University faculty Members of the German Academy of Sciences Leopoldina Members of the German Academy of Sciences at Berlin Peter the Great St. Petersburg Polytechnic University faculty White movement people Soviet Nobel laureates