Metamictisation (sometimes called metamictization or metamiction) is a natural process resulting in the gradual and ultimately complete destruction of a

mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...

crystal structure In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystal, crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric pat ...

, leaving the mineral

amorphous In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid, glassy solid) is a solid that lacks the long-range order that is characteristic of a crystal. Etymology The term comes from the Greek ''a'' ("wi ...

. The affected material is therefore described as metamict. Certain minerals occasionally contain interstitial impurities of

radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consid ...

elements, and it is the

alpha radiation Alpha decay or α-decay is a type of radioactive decay in which an atomic nucleus emits an alpha particle (helium nucleus) and thereby transforms or 'decays' into a different atomic nucleus, with a mass number that is reduced by four and an atom ...

emitted from those compounds that is responsible for degrading a mineral's

crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...

structure through internal bombardment. The effects of metamictisation are extensive: other than negating any

birefringence Birefringence is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are said to be birefringent (or birefractive). The birefring ...

previously present, the process also lowers a mineral's

refractive index In optics, the refractive index (or refraction index) of an optical medium is a dimensionless number that gives the indication of the light bending ability of that medium. The refractive index determines how much the path of light is bent, or ...

hardness In materials science, hardness (antonym: softness) is a measure of the resistance to localized plastic deformation induced by either mechanical indentation or abrasion. In general, different materials differ in their hardness; for example hard ...

, and its

specific gravity Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water (molecule), wa ...

. The mineral's colour is also affected: metamict specimens are usually green, brown or blackish. Further, metamictisation diffuses the bands of a mineral's

absorption spectrum Absorption spectroscopy refers to spectroscopic techniques that measure the absorption of radiation, as a function of frequency or wavelength, due to its interaction with a sample. The sample absorbs energy, i.e., photons, from the radiating f ...

. Curiously and inexplicably, the one attribute which metamictisation does not alter is

dispersion Dispersion may refer to: Economics and finance *Dispersion (finance), a measure for the statistical distribution of portfolio returns *Price dispersion, a variation in prices across sellers of the same item *Wage dispersion, the amount of variatio ...

. All metamict materials are themselves radioactive, some dangerously so. An example of a metamict mineral is

zircon Zircon () is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is Zr SiO4. An empirical formula showing some of the r ...

. The presence of

uranium Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weak ...

and

thorium Thorium is a weakly radioactive metallic chemical element with the symbol Th and atomic number 90. Thorium is silvery and tarnishes black when it is exposed to air, forming thorium dioxide; it is moderately soft and malleable and has a high me ...

atoms substituting for zirconium in the crystal structure is responsible for the radiation damage in this case. Unaffected specimens are termed ''high zircon'' while metamict specimens are termed ''low zircon''. Other minerals known to undergo metamictisation include

allanite Allanite (also called orthite) is a sorosilicate group of minerals within the broader epidote group that contain a significant amount of rare-earth elements. The mineral occurs mainly in metamorphosed clay-rich sediments and felsic igneous rocks. ...

gadolinite Gadolinite, sometimes known as ytterbite, is a silicate mineral consisting principally of the silicates of cerium, lanthanum, neodymium, yttrium, beryllium, and iron with the formula . It is called gadolinite-(Ce) or gadolinite-(Y), depending on ...

ekanite Ekanite is an uncommon silicate mineral with chemical formula or . It is a member of the steacyite group. It is among the few gemstones that are naturally radioactive. Most ekanite is mined in Sri Lanka, although deposits also occur in Russia an ...

thorite Thorite, (Th,U)SiO4, is a rare nesosilicate of thorium that crystallizes in the tetragonal system and is isomorphous with zircon and hafnon. It is the most common mineral of thorium and is nearly always strongly radioactive. It was named in 1829 to ...

and

titanite Titanite, or sphene (from the Greek ''sphenos'' (σφηνώ), meaning wedge), is a calcium titanium nesosilicate mineral, Ca Ti Si O5. Trace impurities of iron and aluminium are typically present. Also commonly present are rare earth metals in ...

. Ekanite is almost invariably found completely metamict as thorium and uranium are part of its essential

chemical composition A chemical composition specifies the identity, arrangement, and ratio of the elements making up a compound. Chemical formulas can be used to describe the relative amounts of elements present in a compound. For example, the chemical formula for ...

. Metamict minerals can have their crystallinity and properties restored through prolonged annealing. A related phenomenon is the formation of

pleochroic halo A pleochroic halo, or radiohalo, is a microscopic, spherical shell of discolouration (pleochroism) within minerals such as biotite that occurs in granite and other igneous rocks. The halo is a zone of radiation damage caused by the inclusion of mi ...

s surrounding minute zircon inclusions within a crystal of

biotite Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron-endmember annite, and the magnesium-endmember phlogopite; more alumino ...

or other mineral. The spherical halos are produced by alpha particle radiation from the included uranium- or thorium-bearing species. Such halos can also be found surrounding

monazite Monazite is a primarily reddish-brown phosphate mineral that contains rare-earth elements. Due to variability in composition, monazite is considered a group of minerals. The most common species of the group is monazite-(Ce), that is, the cerium- ...

and other radioactive minerals.

References

Woodhead, James A., et al., ''The metamictization of zircon: Radiation dose-dependent structural characteristics,'' American Mineralogist, Volume 76, pages 74-82, 1991

External links

Metamictisation of natural zircon: accumulation versus thermal annealing of radioactivity-induced damage
Mineralogy Radioactivity {{Petrology-stub

See also

References

External links