Maskless lithography
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lithography Lithography () is a planographic method of printing originally based on the immiscibility of oil and water. The printing is from a stone (lithographic limestone) or a metal plate with a smooth surface. It was invented in 1796 by the German a ...
(MPL) is a
photomask A photomask is an opaque plate with holes or transparencies that allow light to shine through in a defined pattern. They are commonly used in photolithography and the production of integrated circuits (ICs or "chips") in particular. Masks are used ...
-less
photolithography In integrated circuit manufacturing, photolithography or optical lithography is a general term used for techniques that use light to produce minutely patterned thin films of suitable materials over a substrate, such as a silicon wafer, to protect ...
-like technology used to project or focal-spot write the image pattern onto a chemical resist-coated substrate (e.g.
wafer A wafer is a crisp, often sweet, very thin, flat, light and dry biscuit, often used to decorate ice cream, and also used as a garnish on some sweet dishes. Wafers can also be made into cookies with cream flavoring sandwiched between them. They ...
) by means of UV radiation or electron beam. In
microlithography Microlithography is a general name for any manufacturing process that can create a minutely patterned thin film of protective materials over a substrate, such as a silicon wafer, in order to protect selected areas of it during subsequent etchin ...
, typically
UV radiation Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nm (with a corresponding frequency around 30  PHz) to 400 nm (750  THz), shorter than that of visible light, but longer than X-rays. UV radiation i ...
casts an image of a time constant mask onto a photosensitive emulsion (or
photoresist A photoresist (also known simply as a resist) is a light-sensitive material used in several processes, such as photolithography and photoengraving, to form a patterned coating on a surface. This process is crucial in the electronic industry. T ...
). Traditionally, mask aligners, steppers, scanners, and other kinds of non-optical techniques are used for high speed
microfabrication Microfabrication is the process of fabricating miniature structures of micrometre scales and smaller. Historically, the earliest microfabrication processes were used for integrated circuit fabrication, also known as "semiconductor manufacturing" ...
of microstructures, but in case of MPL, some of these become redundant. Maskless lithography has two approaches to project a pattern:
rasterized In computer graphics, rasterisation (British English) or rasterization (American English) is the task of taking an Digital image, image described in a vector graphics format (shapes) and converting it into a raster image (a series of pixels, dots ...
and vectorized. In the first one it utilizes generation of a time-variant intermittent image on an electronically modifiable (virtual) mask that is projected with known means (also known as Laser Direct Imaging and other synonyms). In the vectored approach, direct writing is achieved by radiation that is focused to a narrow beam that is scanned in vector form across the resist. The beam is then used to directly write the image into the photoresist, one or more
pixel In digital imaging, a pixel (abbreviated px), pel, or picture element is the smallest addressable element in a raster image, or the smallest point in an all points addressable display device. In most digital display devices, pixels are the smal ...
s at a time. Also combinations of the two approaches are known, and it is not limited to optical radiation, but also extends into the UV, includes
electron-beam Cathode rays or electron beam (e-beam) are streams of electrons observed in discharge tubes. If an evacuated glass tube is equipped with two electrodes and a voltage is applied, glass behind the positive electrode is observed to glow, due to ele ...
s and also mechanical or thermal ablation via
MEMS Microelectromechanical systems (MEMS), also written as micro-electro-mechanical systems (or microelectronic and microelectromechanical systems) and the related micromechatronics and microsystems constitute the technology of microscopic devices, ...
devices.


Advantages

The MPL advantage is a high speed parallel manipulation of the pattern enabled by a large and cheap available computing capacity, which is not an issue with the standard approach that decouples to a slow, but precise structuring process for writing a mask from a fast and highly parallel copy process to achieve high replication throughputs as demanded by industry. A key advantage of maskless lithography is the ability to change lithography patterns from one run to the next, without incurring the cost of generating a new photomask. This may prove useful for
double patterning Multiple patterning (or multi-patterning) is a class of technologies for manufacturing integrated circuits (ICs), developed for photolithography to enhance the feature density. It is expected to be necessary for the 10 nm and 7 nm node se ...
or compensation of non-linear material behavior (e.g. when utilizing cheaper, non-crystalline substrate or to compensate for random placement errors of preceding structures).


Disadvantages

The main disadvantages are complexity and costs for the replication process, the limitation of rasterization in respect to oversampling causes aliasing artefact, especially with smaller structures (which may affect yield), while direct vector writing is limited in throughput. Also the digital throughput of such systems forms a bottleneck for high resolutions, i.e. structuring a 300mm diameter wafer with its area of ~707cm² requires about 10 TiB of data in a rasterized format without oversampling and thus suffers from step-artefacts (
aliasing In signal processing and related disciplines, aliasing is an effect that causes different signals to become indistinguishable (or ''aliases'' of one another) when sampled. It also often refers to the distortion or artifact that results when a ...
). Oversampling by a factor of 10 to reduce these artefacts adds another two orders of magnitude 1 PiB per single wafer that has to be transferred in ~1 min to the substrate to achieve
high volume manufacturing High may refer to: Science and technology * Height Height is measure of vertical distance, either vertical extent (how "tall" something or someone is) or vertical position (how "high" a point is). For example, "The height of that buildin ...
speeds. Industrial maskless lithography is therefore currently only widely found for structuring lower resolution substrates, like in
PCB PCB may refer to: Science and technology * Polychlorinated biphenyl, an organic chlorine compound, now recognized as an environmental toxin and classified as a persistent organic pollutant * Printed circuit board, a board used in electronics * ...
-panel production, where resolutions ~50µm are most common (at ~2000 times lower throughput demand on the components).


Forms

Currently, the main forms of maskless lithography are electron beam and optical. In addition, focused ion beam (FIB) systems have established an important niche role in failure analysis and defect repair. Also, systems based on arrays of mechanical and thermally ablative probe tips have been demonstrated.


Electron beam (e-beam)

The most commonly used form of maskless lithography today is
electron beam lithography Electron-beam lithography (often abbreviated as e-beam lithography, EBL) is the practice of scanning a focused beam of electrons to draw custom shapes on a surface covered with an electron-sensitive film called a resist (exposing). The electron ...
. Its widespread use is due to the wide range of electron beam systems available accessing an equally wide range of electron beam energies (~10 eV to ~100 keV). This is already being used in wafer-level production at
eASIC eASIC is a fabless semiconductor company offering new ASIC devices used in the production of customized silicon devices. eASIC specializes in offering new ASIC devices that are customized for specific applications and offer improved perform ...
, which uses conventional direct-write
electron beam lithography Electron-beam lithography (often abbreviated as e-beam lithography, EBL) is the practice of scanning a focused beam of electrons to draw custom shapes on a surface covered with an electron-sensitive film called a resist (exposing). The electron ...
to customize a single via layer for low-cost production of ASICs. Most maskless lithography systems currently being developed are based on the use of multiple electron beams. The goal is to use the parallel scanning of the beams to speed up the patterning of large areas. However, a fundamental consideration here is to what degree electrons from neighboring beams can disturb one another (from
Coulomb repulsion Coulomb's inverse-square law, or simply Coulomb's law, is an experimental law of physics that quantifies the amount of force between two stationary, electrically charged particles. The electric force between charged bodies at rest is conventiona ...
). Since the electrons in parallel beams are traveling equally fast, they will persistently repel one another, while the electron lenses act over only a portion of the electrons' trajectories.


Optical

Direct laser writing Multiphoton lithography (also known as direct laser lithography or direct laser writing) of polymer templates has been known for years by the photonic crystal community. Similar to standard photolithography techniques, structuring is accomplished ...
is a very popular form of optical maskless lithography, which offers flexibility, ease of use, and cost effectiveness in R&D processing (small batch production). The underlying technology uses spatial light modulating (SLM) micro-arrays based on glass to block laser pathway from reaching a substrate with a photoresist (in similar manner to digital micromirror devices). This equipment offers rapid patterning at sub-micrometer resolutions, and offers a compromise between performance and cost when working with feature sizes of approximately 200 nm or greater. Direct laser writing for microelectronics packaging, 3D electronics and heterogeneous integration were developed in 1995 at the Microelectronics and Computer Technology Corporation (or MCC) in Austin, Texas. The MCC system was fully integrated with precision control for 3D surfaces and artificial intelligence software with real-time machine learning and included laser wavelengths for standard i-line resist and DUV 248nm. The MCC system also included circuit editing capabilities for isolating circuits on a programmable wafer design. In 1999, the MCC system was advanced for use in MEMS manufacturing.
Interference lithography Interference lithography (or holographic lithography) is a technique for patterning regular arrays of fine features, without the use of complex optical systems or photomasks. Basic principle The basic principle is the same as in interferometry or ...
or holographic exposures are not maskless processes and therefore do not count as "maskless", although they have no 1:1 imaging system in between. Plasmonic direct writing lithography uses
localized surface plasmon A localized surface plasmon (LSP) is the result of the confinement of a surface plasmon in a nanoparticle of size comparable to or smaller than the wavelength of light used to excite the plasmon. When a small spherical metallic nanoparticle is irra ...
excitations via scanning probes to directly expose the photoresist. For improved image resolution,
ultraviolet Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nanometer, nm (with a corresponding frequency around 30 Hertz, PHz) to 400 nm (750 Hertz, THz), shorter than that of visible light, but longer than ...
light, which has a shorter wavelength than visible light, is used to achieve resolution down to around 100 nm. The main optical maskless lithography systems in use today are the ones developed for generating photomasks for the semiconductor and LCD industries. In 2013, a group at Swinburne University of Technology published their achievement of 9 nm feature size and 52 nm pitch, using a combination of two optical beams of different wavelengths. DLP technology can also be used for maskless lithography.


Focused ion beam

Focused ion beam Focused ion beam, also known as FIB, is a technique used particularly in the semiconductor industry, materials science and increasingly in the biological field for site-specific analysis, deposition, and ablation of materials. A FIB setup is a s ...
systems are commonly used today for sputtering away defects or uncovering buried features. The use of ion sputtering must take into account the redeposition of sputtered material.


Probe-tip contact

IBM Research IBM Research is the research and development division for IBM, an American multinational information technology company headquartered in Armonk, New York, with operations in over 170 countries. IBM Research is the largest industrial research org ...
has developed an alternative maskless lithography technique based on
atomic force microscopy Atomic force microscopy (AFM) or scanning force microscopy (SFM) is a very-high-resolution type of scanning probe microscopy (SPM), with demonstrated resolution on the order of fractions of a nanometer, more than 1000 times better than the op ...
. In addition, Dip Pen Nanolithography is a promising new approach for patterning submicrometer features.


Research


2000s

Technologies that enable maskless lithography is already used for the production of photomasks and in limited wafer-level production. There are some obstacles ahead of its use in high-volume manufacturing. First, there is a wide diversity of maskless techniques. Even within the electron-beam category, there are several vendors ( Multibeam, Mapper Lithography,
Canon Canon or Canons may refer to: Arts and entertainment * Canon (fiction), the conceptual material accepted as official in a fictional universe by its fan base * Literary canon, an accepted body of works considered as high culture ** Western ca ...
,
Advantest is a Japanese leading manufacturer of automatic test equipment (ATE) for the semiconductor industry, and a manufacturer of measuring instruments used in the design, production and maintenance of electronic systems including fiber optic and w ...
, Nuflare,
JEOL is a major developer and manufacturer of electron microscopes and other scientific instruments, industrial equipment and medical equipment. Its headquarters are in Tokyo, Japan, with 25 domestic and foreign subsidiaries and associated companies ...
) with entirely different architectures and beam energies. Second, throughput targets exceeding 10 wafers per hour still need to be met. Third, the capacity and ability to handle the large data volume ( Tb-scale) needs to be developed and demonstrated. In recent years
DARPA The Defense Advanced Research Projects Agency (DARPA) is a research and development agency of the United States Department of Defense responsible for the development of emerging technologies for use by the military. Originally known as the Adv ...
and
NIST The National Institute of Standards and Technology (NIST) is an agency of the United States Department of Commerce whose mission is to promote American innovation and industrial competitiveness. NIST's activities are organized into physical sci ...
have reduced support for maskless lithography in the U.S. There was a European program that would push the insertion of maskless lithography for IC manufacturing at the 32-nm ''half-pitch'' node in 2009. Project name was MAGIC, or "MAskless lithoGraphy for IC manufacturing", in frame of EC 7th Framework Programme (FP7). Due to the increased mask costs for
multiple patterning Multiple patterning (or multi-patterning) is a class of technologies for manufacturing integrated circuits (ICs), developed for photolithography to enhance the feature density. It is expected to be necessary for the 10 nm and 7 nm node se ...
, maskless lithography is once again prompts relevant research in this field.


DARPA (United States)

Since at least 2001
DARPA The Defense Advanced Research Projects Agency (DARPA) is a research and development agency of the United States Department of Defense responsible for the development of emerging technologies for use by the military. Originally known as the Adv ...
has invested in a variety of maskless patterning technologies including parallel e-beam arrays, parallel scanning probe arrays, and an innovative
e-beam lithography Electron-beam lithography (often abbreviated as e-beam lithography, EBL) is the practice of scanning a focused beam of electrons to draw custom shapes on a surface covered with an electron-sensitive film called a resist (exposing). The electron b ...
tool to enable low-volume manufacturing process. The technology is codenamed as Gratings of Regular Arrays and Trim Exposures (GRATE) (previously known as Cost Effective Low Volume Nanofabrication).


Economics


Foundries

In 2018 the Dutch and Russia jointly funded (
Rusnano Rusnano Group (russian: Роснано АО, lit=Rosnano plc.) is a Russian state-established and funded company. The Rusnano Group's mission is to create competitive nanotechnology-based industry in Russia. Rusnano invests directly and through i ...
) company Mapper Lithography producing multi e-beam maskless lithography MEMS components went bankrupt and was acquired by
ASML Holding ASML Holding N.V. (commonly shortened to ASML, originally standing for Advanced Semiconductor Materials Lithography) is a Dutch multinational corporation founded in 1984. ASML specializes in the development and manufacturing of photolithograph ...
, a major competitor at the time. The foundry producing devices is located near Moscow, Russia. As of early 2019 it was run by Mapper LLC. The Mapper Lithography originally was created at
Delft University of Technology Delft University of Technology ( nl, Technische Universiteit Delft), also known as TU Delft, is the oldest and largest Dutch public technical university, located in Delft, Netherlands. As of 2022 it is ranked by QS World University Rankings among ...
in 2000.


References


External links

*
35th European Mask and Lithography Conference
(EMLC 2019) {{DEFAULTSORT:Maskless Lithography Lithography (microfabrication)