Fuller's earth is any
clay
Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4).
Clays develop plasticity when wet, due to a molecular film of water surrounding the clay par ...
material that has the capability to decolorize oil or other liquids without the use of harsh chemical treatment.
Fuller's earth typically consists of palygorskite (
attapulgite
Palygorskite or attapulgite is a magnesium aluminium phyllosilicate with the chemical formula ) that occurs in a type of clay soil common to the Southeastern United States. It is one of the types of fuller's earth. Some smaller deposits of this ...
) or
bentonite
Bentonite () is an absorbent swelling clay consisting mostly of montmorillonite (a type of smectite) which can either be Na-montmorillonite or Ca-montmorillonite. Na-montmorillonite has a considerably greater swelling capacity than Ca-mon ...
.
Modern uses of fuller's earth include as absorbents for oil, grease, and animal waste (cat litter) and as a carrier for pesticides and fertilizers. Minor uses include filtering, clarifying, and decolorizing; active and inactive ingredient in beauty products; and as a filler in paint, plaster, adhesives, and pharmaceuticals.
It also has a number of uses in the film industry and on stage.
Etymology
The English name reflects the historic use of the material for
fulling
Fulling, also known as felting, tucking or walking ( Scots: ''waukin'', hence often spelled waulking in Scottish English), is a step in woollen clothmaking which involves the cleansing of woven or knitted cloth (particularly wool) to elimin ...
(cleaning and shrinking) wool, by textile workers known as ''fullers''.
In past centuries,
fullers kneaded fuller's earth and water into
woollen
Woolen (American English) or woollen (Commonwealth English) is a type of yarn made from carded wool. Woolen yarn is soft, light, stretchy, and full of air. It is thus a good insulator, and makes a good knitting yarn. Woolen yarn is in contrast t ...
cloth to absorb
lanolin
Lanolin (from Latin 'wool', and 'oil'), also called wool yolk, wool wax, or wool grease, is a wax secreted by the sebaceous glands of wool-bearing animals. Lanolin used by humans comes from domestic sheep breeds that are raised specifically fo ...
, oils, and other greasy impurities as part of the cloth finishing process.
The original spelling was without an apostrophe, but the apostrophe became more common in the 19th century, both before or after the ''s''. ''Fuller's earth'' is the most common spelling today, but both ''fullers earth'' and ''fullers' earth'' have been widely used.
Fuller's earth is also known by the following other names:
* ''Bleaching clay'',
probably because fulling whitened the cloth.
* ''Whitening clay'', particularly when used to treat facial pigmentation, such as
melasma
Melasma (also known as chloasma faciei,James, William; Berger, Timothy; Elston, Dirk (2005). ''Andrews' Diseases of the Skin: Clinical Dermatology''. (10th ed.). Saunders. . or the mask of pregnancy when present in pregnant women) is a tan or dark ...
.
* (
Hindustani: , ; ), widely used in the
Indian subcontinent
The Indian subcontinent is a list of the physiographic regions of the world, physiographical region in United Nations geoscheme for Asia#Southern Asia, Southern Asia. It is situated on the Indian Plate, projecting southwards into the Indian O ...
in cosmetics. The name comes from the city of
Multan
Multan (; ) is a city in Punjab, Pakistan, on the bank of the Chenab River. Multan is Pakistan's seventh largest city as per the 2017 census, and the major cultural, religious and economic centre of southern Punjab.
Multan is one of the List ...
, in modern-day
Pakistan
Pakistan ( ur, ), officially the Islamic Republic of Pakistan ( ur, , label=none), is a country in South Asia. It is the world's List of countries and dependencies by population, fifth-most populous country, with a population of almost 24 ...
, the area of its origin.
Occurrence and composition
Fuller's earth consists primarily of
hydrous aluminum silicates (clay minerals) of varying composition.
Common components are
montmorillonite
Montmorillonite is a very soft phyllosilicate group of minerals that form when they precipitate from water solution as microscopic crystals, known as clay. It is named after Montmorillon in France. Montmorillonite, a member of the smectite group, ...
,
kaolinite
Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral ...
, and
attapulgite
Palygorskite or attapulgite is a magnesium aluminium phyllosilicate with the chemical formula ) that occurs in a type of clay soil common to the Southeastern United States. It is one of the types of fuller's earth. Some smaller deposits of this ...
. Small amounts of other minerals may be present in fuller's earth deposits, including
calcite
Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
,
dolomite Dolomite may refer to:
*Dolomite (mineral), a carbonate mineral
*Dolomite (rock), also known as dolostone, a sedimentary carbonate rock
*Dolomite, Alabama, United States, an unincorporated community
*Dolomite, California, United States, an unincor ...
, and
quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
. In some localities fuller's earth refers to
calcium bentonite
Bentonite () is an Absorption (chemistry), absorbent swelling clay consisting mostly of montmorillonite (a type of smectite) which can either be Na-montmorillonite or Ca-montmorillonite. Na-montmorillonite has a considerably greater swelli ...
, which is altered volcanic ash composed mostly of montmorillonite.
In 2005, the United States was the largest producer of fuller's earth with an almost 70% world share followed at a distance by Japan and Mexico. In the United States fuller's earth is typically derived from deposits of volcanic ash of
Cretaceous
The Cretaceous ( ) is a geological period that lasted from about 145 to 66 million years ago (Mya). It is the third and final period of the Mesozoic Era, as well as the longest. At around 79 million years, it is the longest geological period of th ...
age and younger (glacial clays do not form fuller's earth).
Fuller's earth deposits have been mined in 24 states.
The first discovery of fuller's earth in the United States was near
Quincy, Florida
Quincy is a city in and the county seat of Gadsden County, Florida, United States. The population was 7,972 at the 2010 census, up from 6,982 at the 2000 census. Quincy is part of the Tallahassee metropolitan area.
History
Established in 1828, ...
, in 1893; previously it was imported from England. In 1939 mines near Quincy produced half the U.S. production.
In the United Kingdom, fuller's earth occurs mainly in England. It has been mined in the
Lower Greensand Group
The Lower Greensand Group is a geological unit present across large areas of Southern England. It was deposited during the Aptian and Albian stages of the Early Cretaceous. It predominantly consists of sandstone and unconsolidated sand that were ...
and the
Vale of White Horse
The Vale of White Horse is a local government district of Oxfordshire in England. It was historically a north-west projection of Berkshire. The area is commonly referred to as the 'Vale of ''the'' White Horse'. It is crossed by the Ridgeway Nat ...
,
Oxfordshire
Oxfordshire is a ceremonial and non-metropolitan county in the north west of South East England. It is a mainly rural county, with its largest settlement being the city of Oxford. The county is a centre of research and development, primarily ...
. The
Combe Hay
Combe Hay is a village and civil parishes in England, civil parish in the England, English Ceremonial Counties, county of Somerset. It falls within the Cotswolds, Cotswolds Area of Outstanding Natural Beauty. The parish has a population of 147.
...
Mine was a fuller's earth mine operating to the south of
Bath, Somerset
Bath () is a city in the Bath and North East Somerset unitary area in the county of Somerset, England, known for and named after its Roman-built baths. At the 2021 Census, the population was 101,557. Bath is in the valley of the River Avon, ...
, until 1979. Other sites south of Bath included
Frome
Frome ( ) is a town and civil parish in eastern Somerset, England. The town is built on uneven high ground at the eastern end of the Mendip Hills, and centres on the River Frome. The town, about south of Bath, is the largest in the Mendip d ...
, Lonsdale,
Englishcombe
Englishcombe is a village and civil parish in Bath and North East Somerset just south-west of Bath, England. The parish, which also includes the hamlets of Inglesbatch and Nailwell, had a population of 318 at the 2011 census.
History
A neolithi ...
,
Tucking Mill
Tucking Mill is a small hamlet (place), hamlet within the parish of Monkton Combe, Somerset, England. It lies on Midford Brook and was a key point on the now disused Somerset Coal Canal.
It is at the southern end of the Two Tunnels Greenway whi ...
, and
Duncorn Hill
Duncorn Hill is an English, landmark, rounded hill with a flat top close to the Fosse Way. It is located on a limestone plateau south of Bath, Somerset, Bath in Somerset and summits at above sea level. The hill's name derives from Celtic language ...
. Although these sites had been used since Roman times,
William Smith developed new methods for the identification of deposits of fuller's earth to the south of Bath. Other English sources include a mine near
Redhill, Surrey
Redhill () is a town in the borough of Reigate and Banstead within the county of Surrey, England. The town, which adjoins the town of Reigate to the west, is due south of Croydon in Greater London, and is part of the London commuter belt. The ...
(worked until 2000), and
Woburn, Bedfordshire
Woburn (, meaning twisted or crooked stream) is a town and civil parish in Bedfordshire, England. It is situated about southeast of the centre of Milton Keynes, and about south of junction 13 of the M1 motorway. At the 2011 census, it had a po ...
, where production ceased in 2004.
Hills, cliffs, and slopes that contain fuller's earth can be unstable, since this material can be
thixotropic
Thixotropy is a time-dependent shear thinning property. Certain gels or fluids that are thick or viscous under static conditions will flow (become thinner, less viscous) over time when shaken, agitated, shear-stressed, or otherwise stressed (ti ...
when saturated by heavy rainfall.
Historical significance
Fulling is an important step in the production of woolen garments, and can be traced back to ancient times. Cuneiform texts from
Mesopotamia
Mesopotamia ''Mesopotamíā''; ar, بِلَاد ٱلرَّافِدَيْن or ; syc, ܐܪܡ ܢܗܪ̈ܝܢ, or , ) is a historical region of Western Asia situated within the Tigris–Euphrates river system, in the northern part of the F ...
mention a raw material, ( akk, 𒅎𒌓, : 'gypsum, plaster'), literally "white earth", which was delivered to fullers for the finishing of cloth. There are several Biblical references to fulling (2 Kings 18:17; Isaiah 7:3 and 36:2; Malachi 3:2; Mark 9:3), but the materials used to whiten the fabric are not specified.
Pliny the Elder
Gaius Plinius Secundus (AD 23/2479), called Pliny the Elder (), was a Roman author, naturalist and natural philosopher, and naval and army commander of the early Roman Empire, and a friend of the emperor Vespasian. He wrote the encyclopedic '' ...
mentions several types of fuller's earth ( in Latin) from a variety of locations, each with different properties and therefore different uses.
The first references to fulling mills are from
Persia
Iran, officially the Islamic Republic of Iran, and also called Persia, is a country located in Western Asia. It is bordered by Iraq and Turkey to the west, by Azerbaijan and Armenia to the northwest, by the Caspian Sea and Turkmeni ...
, and by the time of the
Crusades
The Crusades were a series of religious wars initiated, supported, and sometimes directed by the Latin Church in the medieval period. The best known of these Crusades are those to the Holy Land in the period between 1095 and 1291 that were in ...
in the late eleventh century, fulling mills were active throughout the medieval world.
The use of fuller's earth across the Indian subcontinent dates back to at least 1879.
While its household use and transportation by local carts in the
Sindh
Sindh (; ; ur, , ; historically romanized as Sind) is one of the four provinces of Pakistan. Located in the southeastern region of the country, Sindh is the third-largest province of Pakistan by land area and the second-largest province ...
region predates the 1800s, export by rail was first recorded in 1929 in
British India
The provinces of India, earlier presidencies of British India and still earlier, presidency towns, were the administrative divisions of British governance on the Indian subcontinent. Collectively, they have been called British India. In one ...
.
Uses
In addition to its original use in the
fulling
Fulling, also known as felting, tucking or walking ( Scots: ''waukin'', hence often spelled waulking in Scottish English), is a step in woollen clothmaking which involves the cleansing of woven or knitted cloth (particularly wool) to elimin ...
of raw fibers, fuller's earth is now utilized in a number of industries.
Most important applications make use of the minerals' natural absorbent properties in products sold as absorbents or
filters
Filter, filtering or filters may refer to:
Science and technology
Computing
* Filter (higher-order function), in functional programming
* Filter (software), a computer program to process a data stream
* Filter (video), a software component tha ...
.
* Treatment for
poisoning
A poison can be any substance that is harmful to the body. It can be swallowed, inhaled, injected or absorbed through the skin. Poisoning is the harmful effect that occurs when too much of that substance has been taken. Poisoning is not to ...
. Even given the risk of salmonella, the clay content of soil could save the life of a person exposed to
paraquat
Paraquat (trivial name; ), or ''N'',''N''′-dimethyl-4,4′-bipyridinium dichloride (systematic name), also known as methyl viologen, is an organic compound with the chemical formula C6H7N)2l2. It is classified as a viologen, a family of redox ...
, for example, as paraquat is intended to break down in soil.
*
Decontamination
Decontamination (sometimes abbreviated as decon, dcon, or decontam) is the process of removing contaminants on an object or area, including chemicals, micro-organisms or radioactive substances. This may be achieved by chemical reaction, disinfecti ...
: Fuller's earth is used by military and civil emergency service personnel to decontaminate the clothing and equipment of servicemen and CBRN (chemical, biological, radiological, nuclear) responders who have been contaminated with
chemical agents
A chemical weapon (CW) is a specialized munition that uses chemicals formulated to inflict death or harm on humans. According to the Organisation for the Prohibition of Chemical Weapons (OPCW), this can be any chemical compound intended as a ...
.
*
Cleaning agent
Cleaning agents or hard-surface cleaners are substances (usually liquids, powders, sprays, or granules) used to remove dirt, including dust, stains, bad smells, and clutter on surfaces. Purposes of cleaning agents include health, beauty, removin ...
: In the Indian subcontinent, it has been used to clean marble. As a good absorbent, it removes dust, dirt, impurities and stains from the surface and replenishes the shine of the marble. It has been used numerous times to clean the
Taj Mahal
The Taj Mahal (; ) is an Islamic ivory-white marble mausoleum on the right bank of the river Yamuna in the Indian city of Agra. It was commissioned in 1631 by the Mughal emperor Shah Jahan () to house the tomb of his favourite wife, Mu ...
,
India
India, officially the Republic of India (Hindi: ), is a country in South Asia. It is the seventh-largest country by area, the second-most populous country, and the most populous democracy in the world. Bounded by the Indian Ocean on the so ...
.
*
Litter box
A litter box, also known as a sandbox, cat box, litter tray, cat pan, potty, pot or litter pan, is an indoor feces and urine collection box for cats, as well as Domestic rabbit, rabbits, ferrets, miniature pigs, small dogs, and other pets that ...
: Since the late 1940s, fuller's earth has been used in commercial
cat litter
A litter box, also known as a sandbox, cat box, litter tray, cat pan, potty, pot or litter pan, is an indoor feces and urine collection box for cats, as well as rabbits, ferrets, miniature pigs, small dogs, and other pets that instinctively or ...
.
*
Cosmetology
Cosmetology (from Ancient Greek, Greek , ''kosmētikos'', "beautifying"; and , ''wiktionary:-logia, -logia'') is the study and application of beauty treatment. Branches of specialty include hairstyle, hairstyling, skin care, cosmetics, manicures/p ...
and
dermatology
Dermatology is the branch of medicine dealing with the skin.''Random House Webster's Unabridged Dictionary.'' Random House, Inc. 2001. Page 537. . It is a speciality with both medical and surgical aspects. A dermatologist is a specialist medical ...
: The same properties that make fuller's earth effective at removing oils, dirt, and impurities from wool are also effective on human hair and skin.
*
Film industry
The film industry or motion picture industry comprises the technological and commercial institutions of filmmaking, i.e., film production companies, film studios, cinematography, animation, film production, screenwriting, pre-production, post ...
: Fuller's earth has been used extensively for many years in motion pictures for a variety of applications. In the area of
special effect
Special effects (often abbreviated as SFX, F/X or simply FX) are illusions or visual tricks used in the theatre, film, television, video game, amusement park and simulator industries to simulate the imagined events in a story or virtual wor ...
s, it is used in
pyrotechnics
Pyrotechnics is the science and craft of creating such things as fireworks, safety matches, oxygen candles, explosive bolts and other fasteners, parts of automotive airbags, as well as gas-pressure blasting in mining, quarrying, and demolition. ...
explosions and dust clouds, because it spreads farther and higher than most natural soils, resulting in a blast that looks larger, and is safer than naturally occurring soil should the blast spray hit actors. It was used in the tornado sequence in ''
The Wizard of Oz'' as the artificial twister ploughed its way toward the farmhouse. Fuller's earth is also widely used by the
make-up
Cosmetics are constituted mixtures of chemical compounds derived from either natural sources, or synthetically created ones. Cosmetics have various purposes. Those designed for personal care and skin care can be used to cleanse or protect ...
,
props
A prop, formally known as (theatrical) property, is an object used on stage or screen by actors during a performance or screen production. In practical terms, a prop is considered to be anything movable or portable on a stage or a set, distinc ...
,
wardrobe
A wardrobe or armoire or almirah is a standing closet used for storing clothes. The earliest wardrobe was a chest, and it was not until some degree of luxury was attained in regal palaces and the castles of powerful nobles that separate accomm ...
, and
set dresser A set dresser in drama (theater, film etc.) prepares the set with props and furniture to give it correct appearance and make sure each item is in correct position for each performance.
In film
Set dressers arrange objects on a film set before rolli ...
departments, because it is considered a "clean" dirt, safer to use around people, and it cleans up easily. However, health concerns in this regard have been debated.
[Pickut, Walt (16 July 2015]
Fuller's Earth Health Effects
livestrong.com Fuller's earth is available in small quantities by make-up suppliers for use in making the face and body appear dirty. It is used by props technicians to make furniture look dusty. Wardrobe dressers use a small, loose-mesh cloth bag filled with fuller's earth to apply it to clothing to make it appear dusty. Set dressers use fuller's earth to change paved streets into dirt roads, to create dust trailing from a moving vehicle over a dirt road, or to indicate a vehicle trail over untravelled ground.
See also
*
Diatomaceous earth
Diatomaceous earth (), diatomite (), or kieselgur/kieselguhr is a naturally occurring, soft, siliceous sedimentary rock that can be crumbled into a fine white to off-white powder. It has a particle size ranging from more than 3 μm to le ...
*
Kaolinite
Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral ...
*
Medicinal clay
The use of medicinal clay in folk medicine goes back to prehistoric times. Indigenous peoples around the world still use clay widely, which is related to geophagy. The first recorded use of medicinal clay goes back to ancient Mesopotamia.
A wi ...
*
Sepiolite
Sepiolite, also known in English by the German name meerschaum ( , ; ; meaning "sea foam"), is a soft white clay mineral, often used to make tobacco pipes (known as meerschaum pipes). A complex magnesium silicate, a typical chemical formula for ...
References
Further reading
* Brady, G.S., Clauser, H.R., & Vaccari, J.A. (2002). ''Materials handbook.'' (15th ed.) New York: McGraw-Hill.
''References on Fuller's Earth.''United States Geological Survey
The United States Geological Survey (USGS), formerly simply known as the Geological Survey, is a scientific agency of the United States government. The scientists of the USGS study the landscape of the United States, its natural resources, ...
Kumar P. Multani mitti: Is it more than a placebo?- J Pak Ass Dermatol.2018;29(3):345-348.
*
External links
Fullers Earthhistorical marker in
Attapulgus, Georgia
Attapulgus is a city in Decatur County, Georgia, Decatur County, Georgia (U.S. state), Georgia, United States. As of the 2020 United States Census, 2020 census, the city had a population of 454.
The town's name is an Indian word meaning "Dogwood"; ...
{{DEFAULTSORT:Fuller's Earth
Minerals
Types of soil
Medicinal clay
Dry cleaning
Industrial minerals