Mooihoekite is a

copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...

iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...

sulfide mineral The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the ...

with

chemical formula In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, ...

of Cu₉Fe₉S₁₆. The mineral was discovered in 1972 and received its name from its discovery area, the Mooihoek mine in

Transvaal Transvaal is a historical geographic term associated with land north of (''i.e.'', beyond) the Vaal River in South Africa. A number of states and administrative divisions have carried the name Transvaal. * South African Republic (1856–1902; af, ...

South Africa South Africa, officially the Republic of South Africa (RSA), is the southernmost country in Africa. It is bounded to the south by of coastline that stretch along the South Atlantic and Indian Oceans; to the north by the neighbouring countri ...

Crystal structure and optical properties

Mooihoekite crystallizes in the

tetragonal In crystallography, the tetragonal crystal system is one of the 7 crystal systems. Tetragonal crystal lattices result from stretching a cubic lattice along one of its lattice vectors, so that the cube becomes a rectangular prism with a square ...

crystal system In crystallography, a crystal system is a set of point groups (a group of geometric symmetries with at least one fixed point). A lattice system is a set of Bravais lattices. Space groups are classified into crystal systems according to their po ...

. It has a short optical c-axis that is perpendicular to two longer a-axes of equal length. For Mooihoekite, the c-axis is a 4-fold rotoinversion axis. Mooihoekite is an opaque mineral which shows weak anisotropism in polished section under reflected light microscopy. It goes slightly extinct every 90°.

Occurrence

It is found in massive sulfide from pipe-shaped

dunite Dunite (), also known as olivinite (not to be confused with the mineral olivenite), is an intrusive igneous rock of ultramafic composition and with phaneritic (coarse-grained) texture. The mineral assemblage is greater than 90% olivine, with mi ...

pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic com ...

in the

norite Norite is a mafic intrusive igneous rock composed largely of the calcium-rich plagioclase labradorite, orthopyroxene, and olivine. The name ''norite'' is derived from ''Norge'', the Norwegian name for Norway. Norite also known as orthopyroxen ...

zone of the

Bushveld igneous complex The Bushveld Igneous Complex (BIC) is the largest layered igneous intrusion within the Earth's crust. It has been tilted and eroded forming the outcrops around what appears to be the edge of a great geological basin: the Transvaal Basin. It is ...

. It has also been found in

troctolite Troctolite (from Greek τρώκτης 'trout' and λίθος 'stone') is a mafic intrusive rock type. It consists essentially of major but variable amounts of olivine and calcic plagioclase along with minor pyroxene. It is an olivine-rich anorth ...

from the basal Duluth gabbro in

Minnesota Minnesota () is a state in the upper midwestern region of the United States. It is the 12th largest U.S. state in area and the 22nd most populous, with over 5.75 million residents. Minnesota is home to western prairies, now given over to ...

, US; in the Talnakh area,

Norilsk Norilsk ( rus, Нори́льск, p=nɐˈrʲilʲsk, ''Norílʹsk'') is a closed city in Krasnoyarsk Krai, Russia, located south of the western Taymyr Peninsula, around 90 km east of the Yenisey River and 1,500 km north of Krasnoyarsk. Norilsk i ...

region, western

Siberia Siberia ( ; rus, Сибирь, r=Sibir', p=sʲɪˈbʲirʲ, a=Ru-Сибирь.ogg) is an extensive geographical region, constituting all of North Asia, from the Ural Mountains in the west to the Pacific Ocean in the east. It has been a part of ...

; at

Krzemianka Krzemianka is a village in the administrative district of Gmina Jeleniewo, within Suwałki County, Podlaskie Voivodeship, in north-eastern Poland. It lies approximately west of Jeleniewo, north of Suwałki, and north of the regional capital Bia ...

Poland Poland, officially the Republic of Poland, is a country in Central Europe. It is divided into 16 administrative provinces called voivodeships, covering an area of . Poland has a population of over 38 million and is the fifth-most populous ...

; in the

Malanjkhand Malanjkhand also referred to as MCP (acronym for Malanjkhand Copper Project) is an open-pit copper mine in India, located near the town of Malanjkhand, northeast of Balaghat in Madhya Pradesh, at an altitude of 576 MRL. It falls in the tehsil ...

copper-molybdenum deposit,

Madhya Pradesh Madhya Pradesh (, ; meaning 'central province') is a state in central India. Its capital is Bhopal, and the largest city is Indore, with Jabalpur, Ujjain, Gwalior, Sagar, and Rewa being the other major cities. Madhya Pradesh is the seco ...

India India, officially the Republic of India (Hindi: ), is a country in South Asia. It is the seventh-largest country by area, the second-most populous country, and the most populous democracy in the world. Bounded by the Indian Ocean on the so ...

; and the

Stillwater igneous complex The Stillwater igneous complex is a large layered mafic intrusion (LMI) located in southern Montana in Stillwater, Sweet Grass and Park Counties. The complex is exposed across 30 miles (48 km) of the north flank of the Beartooth Mount ...

Montana Montana () is a state in the Mountain West division of the Western United States. It is bordered by Idaho to the west, North Dakota and South Dakota to the east, Wyoming to the south, and the Canadian provinces of Alberta, British Columbi ...

, US. Mooihoekite occurs in association with haycockite,

magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With the ...

troilite Troilite is a rare iron sulfide mineral with the simple formula of FeS. It is the iron-rich endmember of the pyrrhotite group. Pyrrhotite has the formula Fe(1-x)S (x = 0 to 0.2) which is iron deficient. As troilite lacks the iron deficiency whic ...

, cuprian

pentlandite Pentlandite is an iron–nickel sulfide with the chemical formula . Pentlandite has a narrow variation range in Ni:Fe but it is usually described as having a Ni:Fe of 1:1. It also contains minor cobalt, usually at low levels as a fraction of wei ...

mackinawite Mackinawite is an iron nickel sulfide mineral with the chemical formula (where x = 0 to 0.11). The mineral crystallizes in the tetragonal crystal system and has been described as a distorted, close packed, cubic array of S atoms with some of the ...

sphalerite Sphalerite (sometimes spelled sphaelerite) is a sulfide mineral with the chemical formula . It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in Sedimentary exhalative deposits, sedimen ...

, and moncheite in the Mooihoek mine and with haycockite,

native copper Native copper is an uncombined form of copper that occurs as a natural mineral. Copper is one of the few metallic elements to occur in native form, although it most commonly occurs in oxidized states and mixed with other elements. Native coppe ...

, troilite, pentlandite,

cubanite Cubanite is a copper iron sulfide mineral that commonly occurs as a minor alteration mineral in magmatic sulfide deposits. It has the chemical formula CuFe2S3 and when found, it has a bronze to brass-yellow appearance. On the Mohs hardness scale, ...

and magnetite in the Duluth complex.

Uses

Mooihoekite is a rare mineral that is mostly used for research purposes. It has similar properties to

chalcopyrite Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mo ...

CuFeS₂, making it helpful in the study of ore deposits and the study of the central portion of the Cu-Fe-S phase system. Mooihoekite, chalcopyrite,

talnakhite Talnakhite is a mineral of chalcopyrite group with formula: Cu9(Fe, Ni)8S16. It was named after the Talnakh ore deposit, near Norilsk in Western Siberia, Russia where it was discovered as reported in 1963 by I. Budko and E. Kulagov. It was offici ...

, and haycockite all play key roles in the study of

ore genesis Various theories of ore genesis explain how the various types of mineral deposits form within Earth's crust. Ore-genesis theories vary depending on the mineral or commodity examined. Ore-genesis theories generally involve three components: sour ...

and

beneficiation In the mining industry or extractive metallurgy, beneficiation is any process that improves (benefits) the economic value of the ore by removing the gangue minerals, which results in a higher grade product (ore concentrate) and a waste stream (tail ...

References

{{Reflist Copper minerals Iron minerals Sulfide minerals Tetragonal minerals Minerals in space group 111 Minerals described in 1972