A molecular beam is produced by allowing a gas at higher

pressure Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and e ...

to expand through a small

orifice An orifice is any opening, mouth, hole or vent, as in a pipe, a plate, or a body * Body orifice, any opening in the body of a human or animal *Orifice plate, a restriction used to measure flow or to control pressure or flow, sometimes given specia ...

into a chamber at lower pressure to form a beam of particles (

atom Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas, and ...

free radical A daughter category of ''Ageing'', this category deals only with the biological aspects of ageing. Ageing Ailments of unknown cause Biogerontology Biological processes Causes of death Cellular processes Gerontology Life extension Metabo ...

molecule A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and bioch ...

s or

ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...

s) moving at approximately equal

velocities Velocity is the directional speed of an object in motion as an indication of its rate of change in position as observed from a particular frame of reference and as measured by a particular standard of time (e.g. northbound). Velocity is a ...

, with very few

collision In physics, a collision is any event in which two or more bodies exert forces on each other in a relatively short time. Although the most common use of the word ''collision'' refers to incidents in which two or more objects collide with great fo ...

s between the particles. Molecular beams are useful for fabricating

thin film A thin film is a layer of material ranging from fractions of a nanometer (monolayer) to several micrometers in thickness. The controlled synthesis of materials as thin films (a process referred to as deposition) is a fundamental step in many ap ...

s in

molecular beam epitaxy Molecular-beam epitaxy (MBE) is an epitaxy method for thin-film deposition of single crystals. MBE is widely used in the manufacture of semiconductor devices, including transistors, and it is considered one of the fundamental tools for the devel ...

and artificial structures such as

quantum well A quantum well is a potential well with only discrete energy values. The classic model used to demonstrate a quantum well is to confine particles, which were initially free to move in three dimensions, to two dimensions, by forcing them to occupy ...

quantum wire In mesoscopic physics, a quantum wire is an electrically conducting wire in which quantum effects influence the transport properties. Usually such effects appear in the dimension of nanometers, so they are also referred to as nanowires. Quantum e ...

s, and

quantum dot Quantum dots (QDs) are semiconductor particles a few nanometres in size, having light, optical and electronics, electronic properties that differ from those of larger particles as a result of quantum mechanics. They are a central topic in nanote ...

s. Molecular beams have also been applied as

crossed molecular beam Crossed molecular beam experiments are chemical experiments where two beams of atoms or molecules are collided together to study the dynamics of the chemical reaction, and can detect individual reactive collisions. Technique In a crossed molec ...

s. The molecules in the molecular beam can be manipulated by

electrical field An electric field (sometimes E-field) is the physical field that surrounds electrically charged particles and exerts force on all other charged particles in the field, either attracting or repelling them. It also refers to the physical field fo ...

s and

magnetic field A magnetic field is a vector field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular to its own velocity and to ...

s. Molecules can be decelerated in a Stark decelerator or in a

Zeeman slower A Zeeman slower is a scientific apparatus that is commonly used in atomic physics to slow and cool a beam of hot atoms to speeds of several meters per second and temperatures below a kelvin. The Gas-phase atoms used in atomic physics are often ...

History

The first to study molecular beams were H. Kallmann and F. Reiche who in 1921 were interested in dipole moments and the deflection of beams of polar molecules in an inhomogeneous electric field. Their work inspired indirectly the

Stern–Gerlach experiment The Stern–Gerlach experiment demonstrated that the spatial orientation of angular momentum is quantized. Thus an atomic-scale system was shown to have intrinsically quantum properties. In the original experiment, silver atoms were sent throug ...

(1922) that used not molecular beams but atomic beams. The first to report on the relationship between dipole moments and

deflection Deflection or deflexion may refer to: Board games * Deflection (chess), a tactic that forces an opposing chess piece to leave a square * Khet (game), formerly ''Deflexion'', an Egyptian-themed chess-like game using lasers Mechanics * Deflection ...

in a molecular beam (using binary salts such as

KCl Potassium chloride (KCl, or potassium salt) is a metal halide Salt (chemistry), salt composed of potassium and chlorine. It is odorless and has a white or colorless vitreous lustre, vitreous crystal appearance. The solid dissolves readily in wa ...

) was Erwin Wrede in 1927. In 1939

Isidor Rabi Isidor Isaac Rabi (; born Israel Isaac Rabi, July 29, 1898 – January 11, 1988) was an American physicist who won the Nobel Prize in Physics in 1944 for his discovery of nuclear magnetic resonance, which is used in magnetic resonance im ...

invented a molecular beam

magnetic resonance Magnetic resonance is a process by which a physical excitation (resonance) is set up via magnetism. This process was used to develop magnetic resonance imaging and Nuclear magnetic resonance spectroscopy technology. It is also being used to ...

method in which two magnets placed one after the other create an inhomogeneous magnetic field. The method was used to measure the

magnetic moment In electromagnetism, the magnetic moment is the magnetic strength and orientation of a magnet or other object that produces a magnetic field. Examples of objects that have magnetic moments include loops of electric current (such as electromagnets ...

of several lithium isotopes with molecular beams of LiCl,

LiF Lithium fluoride is an inorganic compound with the chemical formula LiF. It is a colorless solid, that transitions to white with decreasing crystal size. Although odorless, lithium fluoride has a bitter-saline taste. Its structure is analogous to ...

and

dilithium Dilithium, Li2, is a strongly electrophilic, diatomic molecule comprising two lithium atoms covalently bonded together. Li2 is known in the gas phase. It has a bond order of 1, an internuclear separation of 267.3 pm and a bond energy o ...

. This method is a predecessor of

NMR Nuclear magnetic resonance (NMR) is a physical phenomenon in which nuclei in a strong constant magnetic field are perturbed by a weak oscillating magnetic field (in the near field) and respond by producing an electromagnetic signal with ...

. The invention of the

maser A maser (, an acronym for microwave amplification by stimulated emission of radiation) is a device that produces coherent electromagnetic waves through amplification by stimulated emission. The first maser was built by Charles H. Townes, Ja ...

in 1957 by James P. Gordon,

Herbert J. Zeiger Herbert J. Zeiger (b. 16 March 1925 in the Bronx, New York City, United States; d. 14 January 2011) was an American physicist and co-developer of the first maser. Zeiger graduated from the City College of New York with a bachelor's degree in 1944 ...

and

Charles H. Townes Charles Hard Townes (July 28, 1915 – January 27, 2015) was an American physicist. Townes worked on the theory and application of the maser, for which he obtained the fundamental patent, and other work in quantum electronics associated wi ...

was made possible by a molecular beam of

ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous was ...

and a special electrostatic quadrupole focuser.

References

{{Authority control Quantum electronics Chemical physics

History

See also

References