Minium is the naturally occurring form of

lead tetroxide Lead(II,IV) oxide, also called red lead or minium, is the inorganic compound with the formula Pb3O4. A bright red or orange solid, it is used as pigment, in the manufacture of batteries, and rustproof primer paints. It is an example of a mixed ...

, Pb²⁺₂Pb⁴⁺O₄ also known as red lead. Minium is a light-to-vivid red and may have brown-to-yellow tints. It typically occurs in scaly-to-earthy masses. It crystallizes in the

tetragonal In crystallography, the tetragonal crystal system is one of the 7 crystal systems. Tetragonal crystal lattices result from stretching a cubic lattice along one of its lattice vectors, so that the cube becomes a rectangular prism with a square ...

crystal system In crystallography, a crystal system is a set of point groups (a group of geometric symmetries with at least one fixed point). A lattice system is a set of Bravais lattices. Space groups are classified into crystal systems according to their po ...

. Minium is rare and occurs in lead-mineral deposits that have been subjected to severe

oxidizing Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a d ...

conditions. It also occurs as a result of mine fires. It is associated with

cerussite Cerussite (also known as lead carbonate or white lead ore) is a mineral consisting of lead carbonate (PbCO3), and is an important ore of lead. The name is from the Latin ''cerussa'', white lead. ''Cerussa nativa'' was mentioned by Conrad Gessner ...

galena Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver. Galena is one of the most abundant and widely distributed sulfide minerals. It cryst ...

litharge Litharge (from Greek lithargyros, lithos (stone) + argyros (silver) ''λιθάργυρος'') is one of the natural mineral forms of lead(II) oxide, PbO. Litharge is a secondary mineral which forms from the oxidation of galena ores. It forms as coa ...

massicot Massicot is lead (II) oxide mineral with an orthorhombic lattice structure. Lead(II) oxide (formula: PbO) can occur in one of two lattice formats, orthorhombic and tetragonal. The tetragonal form is called litharge. PbO can be changed from massi ...

mimetite Mimetite is a lead arsenate chloride mineral (Pb5(AsO4)3Cl) which forms as a secondary mineral in lead deposits, usually by the oxidation of galena and arsenopyrite. The name derives from the Greek Μιμητής ''mimetes'', meaning "imitator" a ...

, native

lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cu ...

, and

wulfenite Wulfenite is a lead molybdate mineral with the formula Pb Mo O4. It can be most often found as thin tabular crystals with a bright orange-red to yellow-orange color, sometimes brown, although the color can be highly variable. In its yellow form ...

. It occurs in relatively small amounts throughout the world: Langhecke,

Hesse Hesse (, , ) or Hessia (, ; german: Hessen ), officially the State of Hessen (german: links=no, Land Hessen), is a States of Germany, state in Germany. Its capital city is Wiesbaden, and the largest urban area is Frankfurt. Two other major histor ...

;

Badenweiler Badenweiler (High Alemannic: ''Badewiler'') is a health resort and spa in the Breisgau-Hochschwarzwald district of Baden-Württemberg, Germany, historically in the Markgräflerland. It is 28 kilometers by road and rail from Basel, 10 kilometer ...

Baden-Württemberg Baden-Württemberg (; ), commonly shortened to BW or BaWü, is a German state () in Southwest Germany, east of the Rhine, which forms the southern part of Germany's western border with France. With more than 11.07 million inhabitants across a ...

;

Bleialf Bleialf is a municipality in the district of Bitburg-Prüm, in Rhineland-Palatinate, western Germany. Geography Bleialf lies in the North Eifel Nature Park North is one of the four compass points or cardinal directions. It is the opposi ...

Eifel The Eifel (; lb, Äifel, ) is a low mountain range in western Germany and eastern Belgium. It occupies parts of southwestern North Rhine-Westphalia, northwestern Rhineland-Palatinate and the southern area of the German-speaking Community of ...

district; Horhausen (),

Rhineland-Palatinate Rhineland-Palatinate ( , ; german: link=no, Rheinland-Pfalz ; lb, Rheinland-Pfalz ; pfl, Rhoilond-Palz) is a western state of Germany. It covers and has about 4.05 million residents. It is the ninth largest and sixth most populous of the ...

Germany Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated betwe ...

. It occurs at

Mies Mies may refer to: People * Ludwig Mies van der Rohe (1886–1969), architect *Maria Mies (born 1931), German feminist * Richard W. Mies (born 1944), U.S. Navy admiral and fourth commander in chief of the United States Strategic Command *Mies Boi ...

Slovenia Slovenia ( ; sl, Slovenija ), officially the Republic of Slovenia (Slovene: , abbr.: ''RS''), is a country in Central Europe. It is bordered by Italy to the west, Austria to the north, Hungary to the northeast, Croatia to the southeast, an ...

;

Leadhills Leadhills, originally settled for the accommodation of miners, is a village in South Lanarkshire, Scotland, WSW of Elvanfoot. The population in 1901 was 835. It was originally known as Waterhead. It is the second highest village in Scotland, ...

Lanarkshire Lanarkshire, also called the County of Lanark ( gd, Siorrachd Lannraig; sco, Lanrikshire), is a historic county, lieutenancy area and registration county in the central Lowlands of Scotland. Lanarkshire is the most populous county in Scotlan ...

Scotland Scotland (, ) is a country that is part of the United Kingdom. Covering the northern third of the island of Great Britain, mainland Scotland has a border with England to the southeast and is otherwise surrounded by the Atlantic Ocean to the ...

; Castelberg

St. Avold Saint-Avold (; ; Lorraine Franconian: ''Sänt Avuur'') is a commune in the Moselle department in Grand Est in north-eastern France. It is situated twenty-eight miles (45 km) east of Metz, France and seventeen miles (27 km) southwest ...

Moselle The Moselle ( , ; german: Mosel ; lb, Musel ) is a river that rises in the Vosges mountains and flows through north-eastern France and Luxembourg to western Germany. It is a bank (geography), left bank tributary of the Rhine, which it jo ...

France France (), officially the French Republic ( ), is a country primarily located in Western Europe. It also comprises of Overseas France, overseas regions and territories in the Americas and the Atlantic Ocean, Atlantic, Pacific Ocean, Pac ...

; from Langban, Varmland,

Sweden Sweden, formally the Kingdom of Sweden,The United Nations Group of Experts on Geographical Names states that the country's formal name is the Kingdom of SwedenUNGEGN World Geographical Names, Sweden./ref> is a Nordic country located on ...

;

Sarrabus Sarrabus-Gerrei is a sub-region of south-eastern Sardinia, Italy. Sarrabus Traditionally Sarrabus, probably from the Roman-time city of Sarcopos, occupies the area of the communes of Castiadas, Muravera, San Vito and Villaputzu, corresponding to ...

Sardinia Sardinia ( ; it, Sardegna, label=Italian, Corsican and Tabarchino ; sc, Sardigna , sdc, Sardhigna; french: Sardaigne; sdn, Saldigna; ca, Sardenya, label=Algherese and Catalan) is the second-largest island in the Mediterranean Sea, after ...

Italy Italy ( it, Italia ), officially the Italian Republic, ) or the Republic of Italy, is a country in Southern Europe. It is located in the middle of the Mediterranean Sea, and its territory largely coincides with the homonymous geographical re ...

; near

Anarak Anarak ( fa, انارک, also Romanized as Anārak) is a city and capital of Anarak District, in Nain County, Isfahan Province, Iran. At the 2006 census, its population was 1,285, in 462 families. It is situated at an altitude of . Anarak is lo ...

Iran Iran, officially the Islamic Republic of Iran, and also called Persia, is a country located in Western Asia. It is bordered by Iraq and Turkey to the west, by Azerbaijan and Armenia to the northwest, by the Caspian Sea and Turkmeni ...

; and

Tsumeb , nickname = , settlement_type = City , motto = ''Glück Auf'' (German language, German for ''Good luck'') , image_skyline = Welcome to tsumeb.jpg , imagesize = , image_caption ...

Namibia Namibia (, ), officially the Republic of Namibia, is a country in Southern Africa. Its western border is the Atlantic Ocean. It shares land borders with Zambia and Angola to the north, Botswana to the east and South Africa to the south and ea ...

. In the US, mines include the Jay Gould mine,

Alturas County, Idaho Alturas County was a county in Idaho Territory and later the state of Idaho from 1864 to 1895. It covered an area larger than the states of Maryland, New Jersey, and Delaware combined. Most present-day southern Idaho counties were created at least ...

; the

Leadville The City of Leadville is a statutory city that is the county seat, the most populous community, and the only incorporated municipality in Lake County, Colorado, United States. The city population was 2,602 at the 2010 census and an estimated ...

district,

Lake County, Colorado ''Lake County'' is a county located in the U.S. state of Colorado. As of the 2020 census, the population was 7,436. The county seat and the only municipality in the county is Leadville. The highest natural point in Colorado and the entire Rock ...

; and in the Tonopah-Belmont mine,

Maricopa County, Arizona Maricopa County is in the south-central part of the U.S. state of Arizona. As of the 2020 census, the population was 4,420,568, making it the state's most populous county, and the fourth-most populous in the United States. It contains about 6 ...

. It also occurs in Eschuchapa and

Guerrero Guerrero is one of the 32 states that comprise the 32 Federal Entities of Mexico. It is divided in 81 municipalities and its capital city is Chilpancingo and its largest city is Acapulcocopied from article, GuerreroAs of 2020, Guerrero the pop ...

Mexico Mexico (Spanish: México), officially the United Mexican States, is a country in the southern portion of North America. It is bordered to the north by the United States; to the south and west by the Pacific Ocean; to the southeast by Guatema ...

. Good specimens were produced by a mine fire at the Broken Hill mine in

New South Wales ) , nickname = , image_map = New South Wales in Australia.svg , map_caption = Location of New South Wales in AustraliaCoordinates: , subdivision_type = Country , subdivision_name = Australia , established_title = Before federation , es ...

Australia Australia, officially the Commonwealth of Australia, is a Sovereign state, sovereign country comprising the mainland of the Australia (continent), Australian continent, the island of Tasmania, and numerous List of islands of Australia, sma ...

. Minium has been identified as one of the pigments at

Angkor Wat Angkor Wat (; km, អង្គរវត្ត, "City/Capital of Temples") is a temple complex in Cambodia and is the largest religious monument in the world, on a site measuring . Originally constructed as a Hinduism, Hindu temple dedicated ...

in Cambodia. Uchida, Archaeometry 54:549-64 2012 Minium was named for the Iberian river known to the imperial Romans as ''Minius'', now known as the Spanish Miño and the Portuguese Minho. The name was originally applied to certain forms of

cinnabar Cinnabar (), or cinnabarite (), from the grc, κιννάβαρι (), is the bright scarlet to brick-red form of Mercury sulfide, mercury(II) sulfide (HgS). It is the most common source ore for refining mercury (element), elemental mercury and ...

that had been coated with the minium oxide; however, once the ''red lead'' contaminant was determined to be chemically distinct from cinnabar crystals, the name, ''minium'', was applied. For properties and uses of minium see

References

{{Commons category, Minium Lead minerals Pigments Inorganic pigments Tetragonal minerals Minerals in space group 135