Mendozite is a

sulfate The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ar ...

mineral, one of the

alum An alum () is a type of chemical compound, usually a hydrated double salt, double sulfate salt (chemistry), salt of aluminium with the general chemical formula, formula , where is a valence (chemistry), monovalent cation such as potassium or a ...

series, with formula NaAl(SO₄)₂·11H₂O. It is a hydrated form of sodium aluminium sulfate (soda alum). It was discovered in western

Argentina Argentina (), officially the Argentine Republic ( es, link=no, República Argentina), is a country in the southern half of South America. Argentina covers an area of , making it the second-largest country in South America after Brazil, th ...

in 1868, probably near

San Juan San Juan, Spanish for Saint John, may refer to: Places Argentina * San Juan Province, Argentina * San Juan, Argentina, the capital of that province * San Juan, Salta, a village in Iruya, Salta Province * San Juan (Buenos Aires Underground), ...

. The exact location has been lost, but was described as "San Juan, near Mendoza", and it is the latter city that give the mineral its name. It occurs in

evaporites An evaporite () is a water-soluble sedimentary mineral deposit that results from concentration and crystallization by evaporation from an aqueous solution. There are two types of evaporite deposits: marine, which can also be described as ocean ...

, presumably from the

oxidation Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a d ...

sulfide mineral The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the ...

s in the presence of

clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay par ...

s. It is very soluble in water, and so can only be found in dry regions: however, in can still

effloresce In chemistry, efflorescence (which means "to flower out" in French) is the migration of a salt to the surface of a porous material, where it forms a coating. The essential process involves the dissolving of an internally held salt in water, or ...

(lose water of crystallisation) in extremely arid climates, altering to

tamarugite Tamarugite (sodium, Naaluminium, Al(sulfur, Soxygen, O4)2·6hydrogen, H2O) is a colorless monoclinic sulfate mineral. Deposits containing tamarugite are geographically dispersed with occurrences of the mineral on all seven continents (Antarctica ...

(the hexahydrate).

References

Bibliography

*Palache, P.; Berman H.; Frondel, C. (1960). "''Dana's System of Mineralogy, Volume II: Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. (Seventh Edition)"'' John Wiley and Sons, Inc., New York, pp. 469-471. Sodium minerals Aluminium minerals Sulfate minerals Monoclinic minerals Minerals in space group 15 {{sulfate-mineral-stub