Melanterite is a mineral form of hydrous

iron(II) sulfate Iron(II) sulfate (British English: iron(II) sulphate) or ferrous sulfate denotes a range of salts with the formula Fe SO4·''x''H2O. These compounds exist most commonly as the heptahydrate (''x'' = 7) but several values for x are know ...

: FeSO₄·7H₂O. It is the iron analogue of the copper sulfate

chalcanthite Chalcanthite (, ) is a richly colored blue-green water-soluble sulfate mineral . It is commonly found in the late-stage oxidation zones of copper deposits. Due to its ready solubility, chalcanthite is more common in arid regions. Chalcanthite i ...

. It alters to

siderotil Siderotil is an iron(II) sulfate hydrate mineral with formula: FeSO4·5H2O which forms by the dehydration of melanterite. Copper commonly occurs substituting for iron in the structure. It typically occurs as fibrous or powdery encrustations, but m ...

by loss of water. It is a secondary

sulfate mineral The sulfate minerals are a class of minerals that include the sulfate ion () within their structure. The sulfate minerals occur commonly in primary evaporite depositional environments, as gangue minerals in hydrothermal veins and as secondary mine ...

which forms from the

oxidation Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a d ...

of primary

sulfide mineral The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the ...

s such as

pyrite The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Iron, FeSulfur, S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic Luster (mineralogy), lust ...

and

marcasite The mineral marcasite, sometimes called “white iron pyrite”, is iron sulfide (FeS2) with orthorhombic crystal structure. It is physically and crystallographically distinct from pyrite, which is iron sulfide with cubic crystal structure. Both ...

in the near-surface environment. It often occurs as a ''post mine'' encrustation on old

underground mine Mining is the extraction of valuable minerals or other geological materials from the Earth, usually from an ore body, lode, vein, seam, reef, or placer deposit. The exploitation of these deposits for raw material is based on the economic via ...

surfaces. It also occurs in

coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when dea ...

and

lignite Lignite, often referred to as brown coal, is a soft, brown, combustible, sedimentary rock formed from naturally compressed peat. It has a carbon content around 25–35%, and is considered the lowest rank of coal due to its relatively low heat ...

seams exposed to humid air and as a rare sublimate phase around

volcanic A volcano is a rupture in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface. On Earth, volcanoes are most often found where tectonic plates a ...

fumarole A fumarole (or fumerole) is a vent in the surface of the Earth or other rocky planet from which hot volcanic gases and vapors are emitted, without any accompanying liquids or solids. Fumaroles are characteristic of the late stages of volcani ...

s. Associated minerals include pisanite,

epsomite Epsomite, Epsom salt, or magnesium sulfate heptahydrate, is a hydrous magnesium sulfate mineral with formula MgSO4·7H2O. Epsomite crystallizes in the orthorhombic system as rarely found acicular or fibrous crystals, the normal form is as massi ...

pickeringite Pickeringite is a magnesium aluminium sulfate mineral with formula MgAl2(SO4)4·22(H2O). It forms a series with halotrichite. It forms as an alteration product of pyrite in aluminium rich rocks and in coal seams. It also occurs in pyrite rich hyd ...

halotrichite Halotrichite, also known as ''feather alum'', is a highly hydrated sulfate of aluminium and iron. Its chemical formula is FeAl2(SO4)4·22H2O. It forms fibrous monoclinic crystals. The crystals are water-soluble. It is formed by the weathering and ...

and other sulfate minerals. It was first described in 1850.

Gallery

File:Melanterite crystal structure.png, Crystal structure of melanterite File:Cuprian Melanterite - Parys Mountain Mines, Amlwch, Isle of Anglesey, Wales, UK.jpg, Cuprian Melanterite

References

Sulfate minerals Iron(II) minerals Monoclinic minerals Minerals in space group 14 {{sulfate-mineral-stub