Manganokhomyakovite is a very rare mineral of the

eudialyte group Eudialyte group is a group of complex trigonal zircono- and, more rarely, titanosilicate minerals with general formula (1)N(2)N(3)N(4)N(5)sub>3 (1a)M(1b)sub>3M(2)3M(4)Z3 i24O72'4X2, where N(1) and N(2) and N(3) and N(5) = Na+ and more rarely H3 ...

,Mindat, Manganokhomyakovite, http://www.mindat.org/min-7137.html with the chemical formula .Johnsen, O., Gault., R.A., Grice, J.D., and Ercit, T.S., 1999: Khomyakovite and manganokhomyakovite, two new members of the eudialyte group from Mont Saint-Hilaire, Quebec, Canada. The Canadian Mineralogist 37, 893–899 This formula is in extended form (based on the original one), to show the presence of cyclic silicate groups and domination of silicon at the M4 site, basing on the nomenclature of the eudialyte group. Some niobium substitutes for tungsten in khomyakovite. As suggested by its name, manganokhomyakovite is a manganese-analogue of

khomyakovite Khomyakovite is an exceedingly rare mineral of the eudialyte group, with formula .Mindat, Khomyakovite, http://www.mindat.org/min-7137.htmlJohnsen, O., Gault, R.A., Grice, J.D., and Ercit, T.S., 1999: Khomyakovite and manganokhomyakovite, two new ...

, the latter being more rare. The two minerals are the only group representatives, beside taseqite, with species-defining

strontium Strontium is the chemical element with the symbol Sr and atomic number 38. An alkaline earth metal, strontium is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is ex ...

, although many other members display strontium diadochy. Manganokhomyakovite is the third eudialyte-group mineral with essential tungsten (after johnsenite-(Ce) and

Occurrence and association

Manganokhomyakovite,

, johnsenite-(Ce) and

oneillite Oneillite is a rare mineral of the eudialyte group with the chemical formula .Mindat, Oneillite, http://www.mindat.org/min-11029.htmlJohnsen, O., Grice, J.D., and Gault, R.A., 1999. Oneillite: a new Ca-deficient and ''REE''-rich member of the eud ...

are four eudialyte-group minerals discovered in alkaline rocks of Mont Saint-Hilaire, Quebec, Canada. Association of manganokhomyakovite is rich and includes: aegirine, albite, analcime, annite, kupletskite, microcline, natrolite,

sodalite Sodalite ( ) is a tectosilicate mineral with the formula , with royal blue varieties widely used as an wikt:ornamental, ornamental gemstone. Although massive sodalite samples are opaque, crystals are usually transparent to translucent. Sodalite i ...

, titanite,

wöhlerite Wöhlerite, also known as wöehlerite is a member of the amphibole supergroup, and the wöhlerite subgroup within it. It was named after German chemist Friedrich Wöhler. It was first described by Scheerer in 1843, but the crystal structure was l ...

, zircon, cerussite,

galena Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver. Galena is one of the most abundant and widely distributed sulfide minerals. It cryst ...

, molybdenite, pyrite, pyrrhotite, and

sphalerite Sphalerite (sometimes spelled sphaelerite) is a sulfide mineral with the chemical formula . It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in Sedimentary exhalative deposits, sedimen ...

Notes on chemistry

Impurities in manganokhomyakovite include

niobium Niobium is a chemical element with chemical symbol Nb (formerly columbium, Cb) and atomic number 41. It is a light grey, crystalline, and ductile transition metal. Pure niobium has a Mohs hardness rating similar to pure titanium, and it has sim ...

and iron, with traces of rare earth elements, hafnium, titanium, tantalum, and aluminium.

References

Cyclosilicates Sodium minerals Strontium minerals Calcium minerals Manganese minerals Zirconium minerals Tungsten minerals Trigonal minerals Minerals in space group 160 {{silicate-mineral-stub