Naturally occurring
manganese
Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy use ...
(
25Mn) is composed of one stable
isotope
Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers (mass numb ...
,
55Mn. 25
radioisotope
A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess nuclear energy, making it unstable. This excess energy can be used in one of three ways: emitted from the nucleus as gamma radiation; transferr ...
s have been characterized, with the most stable being
53Mn with a
half-life
Half-life (symbol ) is the time required for a quantity (of substance) to reduce to half of its initial value. The term is commonly used in nuclear physics to describe how quickly unstable atoms undergo radioactive decay or how long stable at ...
of 3.7 million years,
54Mn with a half-life of 312.3 days, and
52Mn with a half-life of 5.591 days. All of the remaining
radioactive
Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consi ...
isotopes have half-lives that are less than 3 hours and the majority of these have half-lives that are less than a minute, but only
45Mn has an unknown half-life. The least stable is
44Mn with a half-life shorter than 105 nanoseconds. This element also has 3
meta state
A nuclear isomer is a metastable state of an atomic nucleus, in which one or more nucleons (protons or neutrons) occupy higher energy levels than in the ground state of the same nucleus. "Metastable" describes nuclei whose excited states have ...
s.
Manganese is part of the
iron
Iron () is a chemical element with Symbol (chemistry), symbol Fe (from la, Wikt:ferrum, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 element, group 8 of the periodic table. It is, Abundanc ...
group of elements, which are thought to be synthesized in large
stars shortly before
supernova explosions.
53Mn decays to
53 Cr with a
half-life
Half-life (symbol ) is the time required for a quantity (of substance) to reduce to half of its initial value. The term is commonly used in nuclear physics to describe how quickly unstable atoms undergo radioactive decay or how long stable at ...
of 3.7 million years. Because of its relatively short half-life,
53Mn occurs only in tiny amounts due to the action of
cosmic rays
Cosmic rays are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the Solar System in our ow ...
on
iron
Iron () is a chemical element with Symbol (chemistry), symbol Fe (from la, Wikt:ferrum, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 element, group 8 of the periodic table. It is, Abundanc ...
in rocks.
Manganese isotopic contents are typically combined with
chromium isotopic contents and have found application in
isotope geology
Isotope geochemistry is an aspect of geology based upon the study of natural variations in the relative abundances of isotopes of various elements. Variations in isotopic abundance are measured by isotope ratio mass spectrometry, and can reveal ...
and
radiometric dating
Radiometric dating, radioactive dating or radioisotope dating is a technique which is used to date materials such as rocks or carbon, in which trace radioactive impurities were selectively incorporated when they were formed. The method compares ...
. Mn−Cr isotopic ratios reinforce the evidence from
26Al and
107 Pd for the early history of the
Solar System
The Solar System Capitalization of the name varies. The International Astronomical Union, the authoritative body regarding astronomical nomenclature, specifies capitalizing the names of all individual astronomical objects but uses mixed "Solar ...
. Variations in
53Cr/
52Cr and Mn/Cr ratios from several
meteorites indicate an initial
53Mn/
55Mn ratio that suggests Mn−Cr isotopic systematics must result from in-situ decay of
53Mn in differentiated planetary bodies. Hence
53Mn provides additional evidence for
nucleosynthetic
Nucleosynthesis is the process that creates new atomic nuclei from pre-existing nucleons (protons and neutrons) and nuclei. According to current theories, the first nuclei were formed a few minutes after the Big Bang, through nuclear reactions in ...
processes immediately before coalescence of the
Solar System
The Solar System Capitalization of the name varies. The International Astronomical Union, the authoritative body regarding astronomical nomenclature, specifies capitalizing the names of all individual astronomical objects but uses mixed "Solar ...
.
The isotopes of manganese range in
atomic weight
Relative atomic mass (symbol: ''A''; sometimes abbreviated RAM or r.a.m.), also known by the deprecated synonym atomic weight, is a dimensionless physical quantity defined as the ratio of the average mass of atoms of a chemical element in a giv ...
from 44
u (
44Mn) to 69 u (
69Mn). The primary
decay mode before the most abundant stable isotope,
55Mn, is
electron capture
Electron capture (K-electron capture, also K-capture, or L-electron capture, L-capture) is a process in which the proton-rich nucleus of an electrically neutral atom absorbs an inner atomic electron, usually from the K or L electron shells. Thi ...
and the primary mode after is
beta decay
In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which a beta particle (fast energetic electron or positron) is emitted from an atomic nucleus, transforming the original nuclide to an isobar of that nuclide. For ...
.
List of isotopes
, -
,
44Mn
, style="text-align:right" , 25
, style="text-align:right" , 19
, 44.00687(54)#
, <105 ns
,
p
,
43Cr
, (2−)#
,
,
, -
,
45Mn
, style="text-align:right" , 25
, style="text-align:right" , 20
, 44.99451(32)#
, unknown
, p
,
44Cr
, (7/2−)#
,
,
, -
, rowspan=4,
46Mn
, rowspan=4 style="text-align:right" , 25
, rowspan=4 style="text-align:right" , 21
, rowspan=4, 45.98672(12)#
, rowspan=4, 37(3) ms
,
β+ (78%)
,
46Cr
, rowspan=4, (4+)
, rowspan=4,
, rowspan=4,
, -
, β
+, p (22%)
,
45V
, -
, β
+,
α (<1%)
,
42Ti
, -
, β
+, 2p (<1%)
,
44Ti
, -
, style="text-indent:1em" ,
46mMn
, colspan="3" style="text-indent:2em" , 150(100)# keV
, 1# ms
, β
+
,
46Cr
, 1-#
,
,
, -
, rowspan=2,
47Mn
, rowspan=2 style="text-align:right" , 25
, rowspan=2 style="text-align:right" , 22
, rowspan=2, 46.97610(17)#
, rowspan=2, 100(50) ms
, β
+ (96.6%)
,
47Cr
, rowspan=2, 5/2−#
, rowspan=2,
, rowspan=2,
, -
, β
+, p (3.4%)
,
46V
, -
, rowspan=3,
48Mn
, rowspan=3 style="text-align:right" , 25
, rowspan=3 style="text-align:right" , 23
, rowspan=3, 47.96852(12)
, rowspan=3, 158.1(22) ms
, β
+ (99.71%)
,
48Cr
, rowspan=3, 4+
, rowspan=3,
, rowspan=3,
, -
, β
+, p (.027%)
,
47V
, -
, β
+, α (6×10
−4%)
,
44Ti
, -
,
49Mn
, style="text-align:right" , 25
, style="text-align:right" , 24
, 48.959618(26)
, 382(7) ms
, β
+
,
49Cr
, 5/2−
,
,
, -
,
50Mn
, style="text-align:right" , 25
, style="text-align:right" , 25
, 49.9542382(11)
, 283.29(8) ms
, β
+
,
50Cr
, 0+
,
,
, -
, style="text-indent:1em" ,
50mMn
, colspan="3" style="text-indent:2em" , 229(7) keV
, 1.75(3) min
, β
+
,
50Cr
, 5+
,
,
, -
,
51Mn
, style="text-align:right" , 25
, style="text-align:right" , 26
, 50.9482108(11)
, 46.2(1) min
, β
+
,
51Cr
, 5/2−
,
,
, -
,
52Mn
, style="text-align:right" , 25
, style="text-align:right" , 27
, 51.9455655(21)
, 5.591(3) d
, β
+
,
52Cr
, 6+
,
,
, -
, rowspan=2 style="text-indent:1em" ,
52mMn
, rowspan=2 colspan="3" style="text-indent:2em" , 377.749(5) keV
, rowspan=2, 21.1(2) min
, β
+ (98.25%)
,
52Cr
, rowspan=2, 2+
, rowspan=2,
, rowspan=2,
, -
,
IT (1.75%)
,
52Mn
, -
,
53Mn
, style="text-align:right" , 25
, style="text-align:right" , 28
, 52.9412901(9)
, 3.7(4)×10
6 y
,
EC
,
53Cr
, 7/2−
,
trace
Trace may refer to:
Arts and entertainment Music
* ''Trace'' (Son Volt album), 1995
* ''Trace'' (Died Pretty album), 1993
* Trace (band), a Dutch progressive rock band
* ''The Trace'' (album)
Other uses in arts and entertainment
* ''Trace'' ...
,
, -
, rowspan=3,
54Mn
, rowspan=3 style="text-align:right" , 25
, rowspan=3 style="text-align:right" , 29
, rowspan=3, 53.9403589(14)
, rowspan=3, 312.03(3) d
, EC 99.99%
,
54Cr
, rowspan=3, 3+
, rowspan=3,
, rowspan=3,
, -
, β
− (2.9×10
−4%)
,
54Fe
, -
, β
+ (5.76×10
−7%)
,
54Cr
, -
,
55Mn
, style="text-align:right" , 25
, style="text-align:right" , 30
, 54.9380451(7)
, colspan=3 align=center, Stable
, 5/2−
, 1.0000
,
, -
,
56Mn
, style="text-align:right" , 25
, style="text-align:right" , 31
, 55.9389049(7)
, 2.5789(1) h
, β
−
,
56Fe
, 3+
,
,
, -
,
57Mn
, style="text-align:right" , 25
, style="text-align:right" , 32
, 56.9382854(20)
, 85.4(18) s
, β
−
,
57Fe
, 5/2−
,
,
, -
,
58Mn
, style="text-align:right" , 25
, style="text-align:right" , 33
, 57.93998(3)
, 3.0(1) s
, β
−
,
58Fe
, 1+
,
,
, -
, rowspan=2 style="text-indent:1em" ,
58mMn
, rowspan=2 colspan="3" style="text-indent:2em" , 71.78(5) keV
, rowspan=2, 65.2(5) s
, β
− (>99.9%)
,
58Fe
, rowspan=2, (4)+
, rowspan=2,
, rowspan=2,
, -
, IT (<.1%)
,
58Mn
, -
,
59Mn
, style="text-align:right" , 25
, style="text-align:right" , 34
, 58.94044(3)
, 4.59(5) s
, β
−
,
59Fe
, (5/2)−
,
,
, -
,
60Mn
, style="text-align:right" , 25
, style="text-align:right" , 35
, 59.94291(9)
, 51(6) s
, β
−
,
60Fe
, 0+
,
,
, -
, rowspan=2 style="text-indent:1em" ,
60mMn
, rowspan=2 colspan="3" style="text-indent:2em" , 271.90(10) keV
, rowspan=2, 1.77(2) s
, β
− (88.5%)
,
60Fe
, rowspan=2, 3+
, rowspan=2,
, rowspan=2,
, -
, IT (11.5%)
,
60Mn
, -
,
61Mn
, style="text-align:right" , 25
, style="text-align:right" , 36
, 60.94465(24)
, 0.67(4) s
, β
−
,
61Fe
, (5/2)−
,
,
, -
, rowspan=2,
62Mn
, rowspan=2 style="text-align:right" , 25
, rowspan=2 style="text-align:right" , 37
, rowspan=2, 61.94843(24)
, rowspan=2, 671(5) ms
, β
− (>99.9%)
,
62Fe
, rowspan=2, (3+)
, rowspan=2,
, rowspan=2,
, -
, β
−,
n (<.1%)
,
61Fe
, -
, style="text-indent:1em" ,
62mMn
, colspan="3" style="text-indent:2em" , 0(150)# keV
, 92(13) ms
,
,
, (1+)
,
,
, -
,
63Mn
, style="text-align:right" , 25
, style="text-align:right" , 38
, 62.95024(28)
, 275(4) ms
, β
−
,
63Fe
, 5/2−#
,
,
, -
, rowspan=2,
64Mn
, rowspan=2 style="text-align:right" , 25
, rowspan=2 style="text-align:right" , 39
, rowspan=2, 63.95425(29)
, rowspan=2, 88.8(25) ms
, β
− (>99.9%)
,
64Fe
, rowspan=2, (1+)
, rowspan=2,
, rowspan=2,
, -
, β
−, n (<.1%)
,
63Fe
, -
, style="text-indent:1em" ,
64mMn
, colspan="3" style="text-indent:2em" , 135(3) keV
, >100 µs
,
,
,
,
,
, -
, rowspan=2,
65Mn
, rowspan=2 style="text-align:right" , 25
, rowspan=2 style="text-align:right" , 40
, rowspan=2, 64.95634(58)
, rowspan=2, 92(1) ms
, β
− (>99.9%)
,
65Fe
, rowspan=2, 5/2−#
, rowspan=2,
, rowspan=2,
, -
, β
−, n (<.1%)
,
64Fe
, -
, rowspan=2,
66Mn
, rowspan=2 style="text-align:right" , 25
, rowspan=2 style="text-align:right" , 41
, rowspan=2, 65.96108(43)#
, rowspan=2, 64.4(18) ms
, β
− (>99.9%)
,
66Fe
, rowspan=2,
, rowspan=2,
, rowspan=2,
, -
, β
−, n (<.1%)
,
65Fe
, -
,
67Mn
, style="text-align:right" , 25
, style="text-align:right" , 42
, 66.96414(54)#
, 45(3) ms
, β
−
,
67Fe
, 5/2−#
,
,
, -
,
68Mn
, style="text-align:right" , 25
, style="text-align:right" , 43
, 67.96930(64)#
, 28(4) ms
,
,
,
,
,
, -
,
69Mn
, style="text-align:right" , 25
, style="text-align:right" , 44
, 68.97284(86)#
, 14(4) ms
,
,
, 5/2−#
,
,
References
* Isotope masses from:
**
* Isotopic compositions and standard atomic masses from:
**
**
* Half-life, spin, and isomer data selected from the following sources.
**
**
**
{{Navbox element isotopes
Manganese
Manganese
Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy use ...