Magnetic mineralogy is the study of the

magnetic Magnetism is the class of physical attributes that are mediated by a magnetic field, which refers to the capacity to induce attractive and repulsive phenomena in other entities. Electric currents and the magnetic moments of elementary particle ...

properties of

mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...

s. The contribution of a mineral to the total magnetism of a rock depends strongly on the type of magnetic order or disorder. Magnetically disordered minerals (

diamagnet Diamagnetic materials are repelled by a magnetic field; an applied magnetic field creates an induced magnetic field in them in the opposite direction, causing a repulsive force. In contrast, paramagnetic and ferromagnetic materials are attract ...

s and

paramagnet Paramagnetism is a form of magnetism whereby some materials are weakly attracted by an externally applied magnetic field, and form internal, induced magnetic fields in the direction of the applied magnetic field. In contrast with this behavior, ...

s) contribute a weak magnetism and have no

remanence Remanence or remanent magnetization or residual magnetism is the magnetization left behind in a ferromagnetic material (such as iron) after an external magnetic field is removed. Colloquially, when a magnet is "magnetized", it has remanence. The ...

. The more important minerals for

rock magnetism Rock magnetism is the study of the magnetic properties of rocks, sediments and soils. The field arose out of the need in paleomagnetism to understand how rocks record the Earth's magnetic field. This remanence is carried by minerals, particularly ...

are the minerals that can be magnetically ordered, at least at some temperatures. These are the

ferromagnets Ferromagnetism is a property of certain materials (such as iron) which results in a large observed magnetic permeability, and in many cases a large magnetic coercivity allowing the material to form a permanent magnet. Ferromagnetic materials ...

, ferrimagnets and certain kinds of

antiferromagnets In materials that exhibit antiferromagnetism, the magnetic moments of atoms or molecules, usually related to the spins of electrons, align in a regular pattern with neighboring spins (on different sublattices) pointing in opposite directions. ...

. These minerals have a much stronger response to the field and can have a remanence.

Weakly magnetic minerals

Non-iron-bearing minerals

Most minerals with no iron content are diamagnetic. Some such minerals may have a significant positive

magnetic susceptibility In electromagnetism, the magnetic susceptibility (Latin: , "receptive"; denoted ) is a measure of how much a material will become magnetized in an applied magnetic field. It is the ratio of magnetization (magnetic moment per unit volume) to the ap ...

, for example serpentine, but this is because the minerals have inclusions containing strongly magnetic minerals such as

magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With the ...

. The susceptibility of such minerals is negative and small (Table 1).

Iron-bearing paramagnetic minerals

Biotite big aggregate - Ochtendung, Eifel, Germany

Most iron-bearing

carbonates A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate g ...

and

silicates In chemistry, a silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name is al ...

are paramagnetic at all temperatures. Some

sulfides Sulfide (British English also sulphide) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to chemical compounds la ...

are paramagnetic, but some are strongly magnetic (see below). In addition, many of the strongly magnetic minerals discussed below are paramagnetic above a critical temperature (the

Curie temperature In physics and materials science, the Curie temperature (''T''C), or Curie point, is the temperature above which certain materials lose their permanent magnetic properties, which can (in most cases) be replaced by induced magnetism. The Cur ...

Néel temperature In physics and materials science, the Curie temperature (''T''C), or Curie point, is the temperature above which certain materials lose their permanent magnetic properties, which can (in most cases) be replaced by induced magnetism. The Cur ...

). In Table 2 are given susceptibilities for some iron-bearing minerals. The susceptibilities are positive and an order of magnitude or more larger than diamagnetic susceptibilities.

Strongly magnetic minerals

Iron-titanium oxides

Many of the most important magnetic minerals on Earth are oxides of

iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...

and

titanium Titanium is a chemical element with the symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in ...

. Their compositions are conveniently represented on a

ternary plot A ternary plot, ternary graph, triangle plot, simplex plot, Gibbs triangle or de Finetti diagram is a barycentric plot on three variables which sum to a constant. It graphically depicts the ratios of the three variables as positions in an equi ...

with axes corresponding to the proportions of , , and . Important regions on the diagram include the ''titanomagnetites'', which form a line of compositions for between 0 and 1. At the end is

, while the composition is

ulvöspinel Ulvöspinel or ulvite is an iron titanium oxide mineral with formula: iron, Fe2titanium, Tioxygen, O4 or TiFe2+2O4. It forms brown to black metallic Cubic (crystal system), isometric crystals with a Mohs hardness of 5.5 to 6. It belongs to the sp ...

. The titanomagnetites have an inverse spinel crystal structure and at high temperatures are a

solid solution A solid solution, a term popularly used for metals, is a homogenous mixture of two different kinds of atoms in solid state and have a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The word ...

series. Crystals formed from titanomagnetites by cation-deficient oxidation are called ''titanomaghemites'', an important example of which is

maghemite Maghemite (Fe2O3, γ-Fe2O3) is a member of the family of iron oxides. It has the same spinel ferrite structure as magnetite and is also ferrimagnetic. It is sometimes spelled as "maghaemite". ''Maghemite'' can be considered as an Fe(II)-deficie ...

. Another series, the ''titanohematites'', have

hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...

and

ilmenite Ilmenite is a titanium-iron oxide mineral with the idealized formula . It is a weakly magnetic black or steel-gray solid. Ilmenite is the most important ore of titanium and the main source of titanium dioxide, which is used in paints, printing ...

as their end members, and so are also called ''hemoilmenites''. The crystal structure of hematite is

trigonal In crystallography, the hexagonal crystal family is one of the six crystal families, which includes two crystal systems (hexagonal and trigonal) and two lattice systems (hexagonal and rhombohedral). While commonly confused, the trigonal crysta ...

hexagonal In geometry, a hexagon (from Greek , , meaning "six", and , , meaning "corner, angle") is a six-sided polygon. The total of the internal angles of any simple (non-self-intersecting) hexagon is 720°. Regular hexagon A '' regular hexagon'' has ...

. It has the same composition as

; to distinguish between them, their chemical formulae are generally given as γ for hematite and α for maghemite.

Iron sulfides

The other important class of strongly magnetic minerals is the

iron sulfide Iron sulfide or Iron sulphide can refer to range of chemical compounds composed of iron and sulfur. Minerals By increasing order of stability: * Iron(II) sulfide, FeS * Greigite, Fe3S4 (cubic) * Pyrrhotite, Fe1−xS (where x = 0 to 0.2) (monocli ...

s, particularly

greigite Greigite is an iron sulfide mineral with the chemical formula . It is the sulfur equivalent of the iron oxide magnetite (Fe3O4). It was first described in 1964 for an occurrence in San Bernardino County, California, and named after the mineralogis ...

and

pyrrhotite Pyrrhotite is an iron sulfide mineral with the formula Fe(1-x)S (x = 0 to 0.2). It is a nonstoichiometric variant of FeS, the mineral known as troilite. Pyrrhotite is also called magnetic pyrite, because the color is similar to pyrite and it is ...

Iron alloys

Extraterrestrial environments being low in oxygen, minerals tend to have very little . The primary magnetic phase on the

Moon The Moon is Earth's only natural satellite. It is the fifth largest satellite in the Solar System and the largest and most massive relative to its parent planet, with a diameter about one-quarter that of Earth (comparable to the width of ...

is ferrite, the body-centered cubic (bcc) phase of iron. As the proportion of iron decreases, the crystal structure changes from bcc to face centered cubic (fcc). Nickel iron mixtures tend to exsolve into a mixture of iron-rich

kamacite Kamacite is an alloy of iron and nickel, which is found on Earth only in meteorites. According to the International Mineralogical Association (IMA) it is considered a proper nickel-rich variety of the mineral native iron. The proportion iron:ni ...

and iron-poor

taenite Taenite is a mineral found naturally on Earth mostly in iron meteorites. It is an alloy of iron and nickel, with a chemical formula of and nickel proportions of 20% up to 65%. The name is derived from the Greek ταινία for "band, ribbon" ...

References

{{Reflist Geomagnetism Mineralogy