M687 155 Mm Projectile
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The M687 was an American
155 mm 155 mm (6.1 in) is a common, NATO-standard, artillery caliber. It is defined in AOP-29 part 1 with reference to STANAG 4425. It is commonly used in field guns, howitzers, and gun-howitzers. Land warfare The caliber originated in France after ...
binary Binary may refer to: Science and technology Mathematics * Binary number, a representation of numbers using only two digits (0 and 1) * Binary function, a function that takes two arguments * Binary operation, a mathematical operation that t ...
sarin Sarin (NATO designation GB G-series, "B"">Nerve_agent#G-series.html" ;"title="hort for Nerve agent#G-series">G-series, "B" is an extremely toxic synthetic organophosphorus compound.chemical
artillery shell A shell, in a military context, is a projectile whose payload contains an explosive, incendiary, or other chemical filling. Originally it was called a bombshell, but "shell" has come to be unambiguous in a military context. Modern usage ...
. The design was standardized in 1976 and production began on December 16, 1987 at
Pine Bluff Arsenal The Pine Bluff Arsenal is a United States Army installation in Jefferson County, Arkansas, about eight miles northwest of Pine Bluff and thirty miles southeast of Little Rock. Pine Bluff Arsenal is one of nine Army installations in the United ...
, Pine Bluff, Arkansas. Production was halted three years later, following the
1990 Chemical Weapons Accord On June 1, 1990, Presidents George H. W. Bush and Mikhail Gorbachev signed the bilateral U.S.–Soviet Chemical Weapons Accord; officially known as the "Agreement on Destruction and Non-production of Chemical Weapons and on Measures to Facilita ...
between the United States and the
USSR The Soviet Union,. officially the Union of Soviet Socialist Republics. (USSR),. was a transcontinental country that spanned much of Eurasia from 1922 to 1991. A flagship communist state, it was nominally a federal union of fifteen nationa ...
, and the dismantling of existing stocks began in November 1997 at
Hawthorne Army Depot Hawthorne Army Depot (HWAD) is a U.S. Army Joint Munitions Command ammunition storage depot located near the town of Hawthorne in western Nevada in the United States. It is directly south of Walker Lake. The depot covers or 226 sq. mi. and ha ...
, Nevada. America's remaining stocks were stored at the
Deseret Chemical Depot The Deseret Chemical Depot () was a U.S. Army chemical weapon storage area located in Utah, 60 miles (100 km) southwest of Salt Lake City. It is related to the Tooele Chemical Agent Disposal Facility. History The area was used to store chemi ...
, Utah, and the
Umatilla Chemical Depot The Umatilla Chemical Depot, (UMCD) based in Umatilla, Oregon, was a U.S. Army installation in the United States that stored chemical weapons. The chemical weapons originally stored at the depot consisted of various live munitions and storage con ...
( Umatilla County, Oregon). The shell contained two canisters separated by a rupture disk. The compartments were filled with two liquid precursor chemicals for
sarin Sarin (NATO designation GB G-series, "B"">Nerve_agent#G-series.html" ;"title="hort for Nerve agent#G-series">G-series, "B" is an extremely toxic synthetic organophosphorus compound.methylphosphonyl difluoride Methylphosphonyl difluoride (DF), also known as EA-1251 or difluoro, is a chemical weapon precursor. Its chemical formula is CH3POF2. It is a List of Schedule 1 substances (CWC), Schedule 1 substance under the Chemical Weapons Convention. It is ...
(denominated DF) and a mixture of
isopropyl alcohol Isopropyl alcohol (IUPAC name propan-2-ol and also called isopropanol or 2-propanol) is a colorless, flammable organic compound with a pungent alcoholic odor. As an isopropyl group linked to a hydroxyl group (chemical formula ) it is the simple ...
and
isopropyl amine Isopropylamine (monoisopropyl amine, MIPA, 2-Propylamine) is an organic compound, an amine. It is a hygroscopic colorless liquid with ammonia-like odor. It is miscible with water and flammable. It is a valuable intermediate in chemical industry. ...
(denominated OPA) is in a second canister. The isopropyl amine binds the
hydrogen fluoride Hydrogen fluoride (fluorane) is an inorganic compound with the chemical formula . This colorless gas or liquid is the principal industrial source of fluorine, often as an aqueous solution called hydrofluoric acid. It is an important feedstock i ...
generated during the chemical reaction. When the shell was fired the force of the acceleration would cause the disk between them to breach and the spinning of the projectile facilitated mixing. The two precursor chemicals would react in flight to produce sarin and when the shell reached its target the sarin would be released. The shells were meant to be stored and transported with only the OPA compartment loaded; the
fuze In military munitions, a fuze (sometimes fuse) is the part of the device that initiates function. In some applications, such as torpedoes, a fuze may be identified by function as the exploder. The relative complexity of even the earliest fuze d ...
and the DF compartment would be inserted shortly before firing. The M687 was never used in combat and, under the
Chemical Weapons Convention The Chemical Weapons Convention (CWC), officially the Convention on the Prohibition of the Development, Production, Stockpiling and Use of Chemical Weapons and on their Destruction, is an arms control treaty administered by the Organisation for ...
, the U.S. destroyed the shells and the precursor chemical DF as part of its agreement to eliminate all chemical weapons. More than 258,000 of the shells were shipped to
Hawthorne Army Depot Hawthorne Army Depot (HWAD) is a U.S. Army Joint Munitions Command ammunition storage depot located near the town of Hawthorne in western Nevada in the United States. It is directly south of Walker Lake. The depot covers or 226 sq. mi. and ha ...
from their storage at
Deseret Chemical Depot The Deseret Chemical Depot () was a U.S. Army chemical weapon storage area located in Utah, 60 miles (100 km) southwest of Salt Lake City. It is related to the Tooele Chemical Agent Disposal Facility. History The area was used to store chemi ...
, Utah, and the
Umatilla Chemical Depot The Umatilla Chemical Depot, (UMCD) based in Umatilla, Oregon, was a U.S. Army installation in the United States that stored chemical weapons. The chemical weapons originally stored at the depot consisted of various live munitions and storage con ...
, Oregon and were destroyed by July 1999. The last of the U.S.'s stockpile of DF was destroyed on April 6, 2006.


See also

*
Chemical Weapons Convention The Chemical Weapons Convention (CWC), officially the Convention on the Prohibition of the Development, Production, Stockpiling and Use of Chemical Weapons and on their Destruction, is an arms control treaty administered by the Organisation for ...
*
M104 155 mm projectile The M104 155 mm projectile is a chemical artillery shell designed for use by the U.S. Army. It was specifically designed to carry about of sulfur mustard (H) or (HD) blister agent (distilled mustard). As early as the 1960s, the shell was also ...
*
M110 155 mm projectile The M110 155mm Projectile is an artillery shell used by the U.S. Army and U.S. Marine Corps. The M110 was originally designed as a chemical artillery round to deliver blister agents via howitzer as a replacement for the World War I-era 75mm chemi ...
*
M121 155 mm projectile The M121/A1 155mm Projectile was a chemical artillery shell designed for use by the U.S. Army. It was designed to be used with approximately of GB or VX nerve agents. History The U.S. Army standardized the M121 shell in 1954 as an artillery s ...
* M2 4.2-inch mortar *
M55 (rocket) The M55 rocket was a chemical weapon developed by the United States in the 1950s. The United States Army produced both Sarin and VX unitary warheads for the M55. History In 1951 the US Army Chemical Corps and United States Army Ordnance Corps, Ord ...
* United States and weapons of mass destruction


External links


The M687 @ The Federation of American Scientists

The U.S. Army Chemical Materials Agency (CMA) - Binary Chemical Weapons
{{U.S. chemical weapons 155mm artillery shells Chemical weapon delivery systems Chemical weapons of the United States