List Of Refrigerants
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This is a list of refrigerants, sorted by their
ASHRAE The American Society of Heating, Refrigerating and Air-Conditioning Engineers (ASHRAE ) is an American professional association seeking to advance heating, ventilation, air conditioning and refrigeration The term refrigeration refers to the ...
-designated numbers, commonly known as R numbers. Many modern refrigerants are man-made
halogenated In chemistry, halogenation is a chemical reaction that entails the introduction of one or more halogens into a compound. Halide-containing compounds are pervasive, making this type of transformation important, e.g. in the production of polyme ...
gases, especially fluorinated gases and chlorinated gases, that are frequently referred to as
Freon Freon ( ) is a registered trademark of the Chemours Company and generic descriptor for a number of halocarbon products. They are stable, nonflammable, low toxicity gases or liquids which have generally been used as refrigerants and as aerosol prope ...
(a registered trademark of
Chemours Chemours (, ) is an American chemical company that was founded in July 2015 as a spin-off from DuPont. It has its corporate headquarters in Wilmington, Delaware, United States. History In October 2013, DuPont announced that it was planning to ...
). The R number of a chemical refrigerant is assigned systematically according to molecular structure. First ASHRAE digit is the number of carbon atoms minus 1 (C-1); the second digit is the number of hydrogen atoms plus 1 (H+1); the third digit is the number of fluorine atoms; any remaining spaces are chlorine atoms. Eg.: R-22 aka R-022, which is chlorodifluoromethane. C=1 i.e. 1-1=0; H=1 i.e. 1+1=2; F=2 i.e 2; 1 remaining space 1=Cl. A "B" number means that one of the chlorine atoms is replaced by bromine (Br). This formula does not work with zeotropic or azeotropic blends. The table is sortable by each of the following refrigerant properties (scroll right or reduce magnification to view more properties): * Type/prefix (see
legends A legend is a historical narrative, a symbolic representation of folk belief. Legend(s) or The Legend(s) may also refer to: Narrative * Urban legend, a widely repeated story of dubious truth * A fictitious identity used in espionage Books, co ...
) * ASHRAE number * IUPAC chemical name *
molecular formula In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, ...
*
CAS registry number A CAS Registry Number (also referred to as CAS RN or informally CAS Number) is a unique identification number assigned by the Chemical Abstracts Service (CAS), US to every chemical substance described in the open scientific literature. It inclu ...
/ blend name *
Atmospheric lifetime A greenhouse gas (GHG or GhG) is a gas that Absorption (electromagnetic radiation), absorbs and Emission (electromagnetic radiation), emits radiant energy within the thermal infrared range, causing the greenhouse effect. The primary greenhouse ...
in years * Semi-empirical
ozone depletion potential The ozone depletion potential (ODP) of a chemical compound is the relative amount of degradation to the ozone layer it can cause, with trichlorofluoromethane (R-11 or CFC-11) being fixed at an ODP of 1.0. Chlorodifluoromethane (R-22), for exampl ...
* Net
global warming potential Global warming potential (GWP) is the heat absorbed by any greenhouse gas in the atmosphere, as a multiple of the heat that would be absorbed by the same mass of carbon dioxide (). GWP is 1 for . For other gases it depends on the gas and the time ...
over a 100-year time horizon *
Occupational exposure limit An occupational exposure limit is an upper limit on the acceptable concentration of a hazardous substance in workplace air for a particular material or class of materials. It is typically set by competent national authorities and enforced by legi ...
/
permissible exposure limit The permissible exposure limit (PEL or OSHA PEL) is a legal limit in the United States for exposure of an employee to a chemical substance or physical agent such as high level noise. Permissible exposure limits are established by the Occupational ...
in parts per million (volume per volume) over a time-weighted average (TWA) concentration for a normal eight-hour work day and a 40-hour work week * ASHRAE 34 safety group in toxicity & flammability (in air @ 60 °C, 101.3 kPa) classing (see
legends A legend is a historical narrative, a symbolic representation of folk belief. Legend(s) or The Legend(s) may also refer to: Narrative * Urban legend, a widely repeated story of dubious truth * A fictitious identity used in espionage Books, co ...
) * Refrigerant concentration limit /
immediately dangerous to life or health The term immediately dangerous to life or health (IDLH) is defined by the US National Institute for Occupational Safety and Health (NIOSH) as exposure to airborne contaminants that is "likely to cause death or immediate or delayed permanent advers ...
in parts per million (volume per volume) and grams per cubic meter *
Molecular mass The molecular mass (''m'') is the mass of a given molecule: it is measured in daltons (Da or u). Different molecules of the same compound may have different molecular masses because they contain different isotopes of an element. The related quanti ...
in
atomic mass unit The dalton or unified atomic mass unit (symbols: Da or u) is a non-SI unit of mass widely used in physics and chemistry. It is defined as of the mass of an unbound neutral atom of carbon-12 in its nuclear and electronic ground state and at ...
s * Normal boiling point (or bubble & dew points for the zeotrope(400)-series), or normal boiling point and azeotropic temperature for the azeotrope(500)-series) at 101,325 Pa (1 atmosphere) in degrees Celsius * Critical temperature in degrees Celsius * Absolute
critical pressure In thermodynamics, a critical point (or critical state) is the end point of a phase equilibrium curve. The most prominent example is the liquid–vapor critical point, the end point of the pressure–temperature curve that designates conditions ...
in kilopascals Since over 100,000 refrigerant blends are possible, this list should only have notable refrigerants and refrigerant blends.


List


Type and flammability

Compounds used as refrigerants may be described using either the appropriate prefix above or with the prefixes "R-" or "Refrigerant." Thus, CFC-12 may also be written as R-12 or Refrigerant 12.
An alkene, olefin, or olefine is an
unsaturated compound In chemistry, a saturated compound is a chemical compound (or ion) that resists the addition reactions, such as hydrogenation, oxidative addition, and binding of a Lewis base. The term is used in many contexts and for many classes of chemical c ...
containing at least one carbon-carbon double bond. ; Educated Estimates


See also

* Haloalkane


References


Notes

{{reflist, 30em, group=note *
Refrigerants A refrigerant is a working fluid used in the refrigeration cycle of air conditioning systems and heat pumps where in most cases they undergo a repeated phase transition from a liquid to a gas and back again. Refrigerants are heavily regulated d ...
Chemical compounds