Liquid Fuel
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Liquid fuels are combustible or energy-generating molecules that can be harnessed to create
mechanical energy In Outline of physical science, physical sciences, mechanical energy is the sum of potential energy and kinetic energy. The principle of conservation of mechanical energy states that if an isolated system is subject only to conservative forces, t ...
, usually producing
kinetic energy In physics, the kinetic energy of an object is the energy that it possesses due to its motion. It is defined as the work needed to accelerate a body of a given mass from rest to its stated velocity. Having gained this energy during its accele ...
; they also must take the shape of their container. It is the fumes of liquid fuels that are flammable instead of the fluid. Most liquid fuels in widespread use are derived from
fossil fuels A fossil fuel is a hydrocarbon-containing material formed naturally in the Earth's crust from the remains of dead plants and animals that is extracted and burned as a fuel. The main fossil fuels are coal, oil, and natural gas. Fossil fuels ...
; however, there are several types, such as
hydrogen fuel Hydrogen fuel refers to hydrogen which is burned as fuel with oxygen. It is zero-carbon, provided that it is created in a process that does not involve carbon. It can be used in fuel cells or internal combustion engines (see HICEV). Regarding hydr ...
(for automotive uses), ethanol, and
biodiesel Biodiesel is a form of diesel fuel derived from plants or animals and consisting of long-chain fatty acid esters. It is typically made by chemically reacting lipids such as animal fat (tallow), soybean oil, or some other vegetable oil with ...
, which are also categorized as a liquid fuel. Many liquid fuels play a primary role in transportation and the economy. Liquid fuels are contrasted with
solid fuel Solid fuel refers to various forms of solid material that can be burnt to release energy, providing heat and light through the process of combustion. Solid fuels can be contrasted with liquid fuels and gaseous fuels. Common examples of solid fuels ...
s and
gaseous fuel Fuel gas is any one of a number of fuels that under ordinary conditions are gaseous. Most fuel gases are composed of hydrocarbons (such as methane or propane), hydrogen, carbon monoxide, or mixtures thereof. Such gases are sources energy that ...
s.


General properties

Some common properties of liquid fuels are that they are easy to transport, and can be handled with relative ease. Physical properties of liquid fuels vary by temperature, though not as greatly as for gaseous fuels. Some of these properties are:
flash point The flash point of a material is the "lowest liquid temperature at which, under certain standardized conditions, a liquid gives off vapours in a quantity such as to be capable of forming an ignitable vapour/air mixture". (EN 60079-10-1) The fl ...
, the lowest temperature at which a flammable concentration of vapor is produced;
fire point The fire point of a fuel is the lowest temperature at which the vapour of that fuel will continue to burn for at least five seconds after ignition by an open flame of standard dimension. At the flash point, a lower temperature, a substance will ig ...
, the temperature at which sustained burning of vapor will occur;
cloud point In liquids, the cloud point is the temperature below which a transparent solution undergoes either a liquid-liquid phase separation to form an emulsion or a liquid-solid phase transition to form either a stable sol or a suspension that settles a p ...
for diesel fuels, the temperature at which dissolved waxy compounds begin to coalesce, and
pour point The pour point of a liquid is the temperature below which the liquid loses its flow characteristics. It is defined as the minimum temperature in which the oil has the ability to pour down from a beaker. In crude oil a high pour point is generally ...
, the temperature below which the fuel is too thick to pour freely. These properties affect the safety and handling of the fuel.


Petroleum fuels

Most liquid fuels used currently are produced from petroleum. The most notable of these is
gasoline Gasoline (; ) or petrol (; ) (see ) is a transparent, petroleum-derived flammable liquid that is used primarily as a fuel in most spark-ignited internal combustion engines (also known as petrol engines). It consists mostly of organic co ...
. Scientists generally accept that petroleum formed from the fossilized remains of dead plants and animals by exposure to heat and pressure in the Earth's crust.


Gasoline

Gasoline is the most widely used liquid fuel. Gasoline, as it is known in United States and Canada, or petrol virtually everywhere else, is made of
hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ex ...
molecules A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and bioche ...
(compounds that contain hydrogen and carbon only) forming
aliphatic compound In organic chemistry, hydrocarbons ( compounds composed solely of carbon and hydrogen) are divided into two classes: aromatic compounds and aliphatic compounds (; G. ''aleiphar'', fat, oil). Aliphatic compounds can be saturated, like hexane, or ...
s, or chains of carbons with hydrogen atoms attached. However, many
aromatic compound Aromatic compounds, also known as "mono- and polycyclic aromatic hydrocarbons", are organic compounds containing one or more aromatic rings. The parent member of aromatic compounds is benzene. The word "aromatic" originates from the past grouping ...
s (carbon chains forming rings) such as
benzene Benzene is an organic chemical compound with the molecular formula C6H6. The benzene molecule is composed of six carbon atoms joined in a planar ring with one hydrogen atom attached to each. Because it contains only carbon and hydrogen atoms, ...
are found naturally in gasoline and cause the health risks associated with prolonged exposure to the fuel. Production of gasoline is achieved by
distillation Distillation, or classical distillation, is the process of separation process, separating the components or substances from a liquid mixture by using selective boiling and condensation, usually inside an apparatus known as a still. Dry distilla ...
of
crude oil Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crude ...
. The desirable liquid is separated from the crude oil in
refineries A refinery is a production facility composed of a group of chemical engineering unit processes and unit operations refining certain materials or converting raw material into products of value. Types of refineries Different types of refineries ar ...
. Crude oil is extracted from the ground in several processes, the most commonly seen may be beam pumps. To create gasoline,
petroleum Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crud ...
must first be removed from crude oil. Liquid gasoline itself is not actually burned, but its fumes ignite, causing the remaining liquid to
evaporate Evaporation is a type of vaporization that occurs on the surface of a liquid as it changes into the gas phase. High concentration of the evaporating substance in the surrounding gas significantly slows down evaporation, such as when humidi ...
and then burn. Gasoline is extremely volatile and easily combusts, making any leakage potentially extremely dangerous. Gasoline sold in most countries carries a published
octane rating An octane rating, or octane number, is a standard measure of a fuel's ability to withstand compression in an internal combustion engine without detonating. The higher the octane number, the more compression the fuel can withstand before detonating ...
. The octane number is an
empirical Empirical evidence for a proposition is evidence, i.e. what supports or counters this proposition, that is constituted by or accessible to sense experience or experimental procedure. Empirical evidence is of central importance to the sciences and ...
measure of the resistance of gasoline to combusting prematurely, known as knocking. The higher the octane rating, the more resistant the fuel is to autoignition under high pressures, which allows for a higher
compression ratio The compression ratio is the ratio between the volume of the cylinder and combustion chamber in an internal combustion engine at their maximum and minimum values. A fundamental specification for such engines, it is measured two ways: the stati ...
. Engines with a higher compression ratio, commonly used in race cars and high-performance regular-production automobiles, can produce more power; however, such engines require a higher octane fuel. Increasing the octane rating has, in the past, been achieved by adding 'anti-knock' additives such as lead-tetra-ethyl. Because of the environmental impact of lead additives, the octane rating is increased today by refining out the impurities that cause knocking.


Diesel

Conventional diesel is similar to gasoline in that it is a mixture of aliphatic hydrocarbons extracted from petroleum. Diesel may cost more or less than gasoline, but generally costs less to produce because the extraction processes used are simpler. Some countries (particularly Canada, India and Italy) also have lower tax rates on diesel fuels. After distillation, the diesel fraction is normally processed to reduce the amount of
sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
in the fuel. Sulfur causes corrosion in vehicles,
acid rain Acid rain is rain or any other form of precipitation that is unusually acidic, meaning that it has elevated levels of hydrogen ions (low pH). Most water, including drinking water, has a neutral pH that exists between 6.5 and 8.5, but acid ...
and higher emissions of soot from the tail pipe (exhaust pipe). Historically, in Europe lower sulfur levels than in the United States were legally required. However, recent US legislation reduced the maximum sulfur content of diesel from 3,000 ppm to 500 ppm in 2007, and 15 ppm by 2010. Similar changes are also underway in Canada, Australia, New Zealand and several Asian countries. See also
Ultra-low-sulfur diesel Ultra-low-sulfur diesel (ULSD) is diesel fuel with substantially lowered sulfur content. Since 2006, almost all of the petroleum-based diesel fuel available in Europe and North America has been of a ULSD type. The move to lower sulfur content allo ...
. A
diesel engine The diesel engine, named after Rudolf Diesel, is an internal combustion engine in which ignition of the fuel is caused by the elevated temperature of the air in the cylinder due to mechanical compression; thus, the diesel engine is a so-call ...
is a type of
internal combustion engine An internal combustion engine (ICE or IC engine) is a heat engine in which the combustion of a fuel occurs with an oxidizer (usually air) in a combustion chamber that is an integral part of the working fluid flow circuit. In an internal combus ...
which ignites fuel by injecting it into a combustion chamber previously compressed with air (which in turn raises the temperature) as opposed to using an outside ignition source, such as a spark plug.


Kerosene

Kerosene is used in
kerosene lamp A kerosene lamp (also known as a paraffin lamp in some countries) is a type of lighting device that uses kerosene as a fuel. Kerosene lamps have a wick or mantle as light source, protected by a glass chimney or globe; lamps may be used on a t ...
s and as a fuel for cooking, heating, and small engines. It displaced
whale oil Whale oil is oil obtained from the blubber of whales. Whale oil from the bowhead whale was sometimes known as train oil, which comes from the Dutch word ''traan'' ("tears, tear" or "drop"). Sperm oil, a special kind of oil obtained from the ...
for lighting use.
Jet fuel Jet fuel or aviation turbine fuel (ATF, also abbreviated avtur) is a type of aviation fuel designed for use in aircraft powered by gas-turbine engines. It is colorless to straw-colored in appearance. The most commonly used fuels for commercial a ...
for jet engines is made in several grades ( Avtur,
Jet A Jet fuel or aviation turbine fuel (ATF, also abbreviated avtur) is a type of aviation fuel designed for use in aircraft powered by gas-turbine engines. It is colorless to straw-colored in appearance. The most commonly used fuels for commercial a ...
,
Jet A-1 Jet fuel or aviation turbine fuel (ATF, also abbreviated avtur) is a type of aviation fuel designed for use in aircraft powered by gas-turbine engines. It is colorless to straw-colored in appearance. The most commonly used fuels for commercial av ...
,
Jet B Jet fuel or aviation turbine fuel (ATF, also abbreviated avtur) is a type of aviation fuel designed for use in aircraft powered by gas-turbine engines. It is colorless to straw-colored in appearance. The most commonly used fuels for commercial av ...
, JP-4,
JP-5 Jet fuel or aviation turbine fuel (ATF, also abbreviated avtur) is a type of aviation fuel designed for use in aircraft powered by gas-turbine engines. It is colorless to straw-colored in appearance. The most commonly used fuels for commercial av ...
,
JP-7 Turbine Fuel Low Volatility JP-7, commonly known as JP-7 (referred to as Jet Propellant 7 prior to MIL-DTL-38219) is a specialized type of jet fuel developed in 1955 for the United States Air Force (USAF) for use in its supersonic military aircr ...
or
JP-8 JP-8, or JP8 (for "Jet Propellant 8") is a jet fuel, specified and used widely by the US military. It is specified by MIL-DTL-83133 and British Defence Standard 91-87, and similar to commercial aviation's Jet A-1, but with the addition of corrosio ...
) that are kerosene-type mixtures. One form of the fuel known as RP-1 is burned with liquid oxygen as rocket fuel. These fuel grade kerosenes meet specifications for smoke points and freeze points. In the mid-20th century, kerosene or "TVO" (Tractor Vaporising Oil) was used as a cheap fuel for tractors. The engine would start on gasoline, then switch over to kerosene once the engine warmed up. A "heat valve" on the manifold would route the exhaust gases around the intake pipe, heating the kerosene to the point where it can be ignited by an
electric spark An electric spark is an abrupt electrical discharge that occurs when a sufficiently high electric field creates an ionized, electrically conductive channel through a normally-insulating medium, often air or other gases or gas mixtures. Michael F ...
. Kerosene is sometimes used as an additive in diesel fuel to prevent gelling or waxing in cold temperatures. However, this is not advisable in some recent vehicle diesel engines, as doing so may interfere with the engine's emissions regulation equipment.


Liquefied petroleum gas (LPG)

LP gas is a mixture of
propane Propane () is a three-carbon alkane with the molecular formula . It is a gas at standard temperature and pressure, but compressible to a transportable liquid. A by-product of natural gas processing and petroleum refining, it is commonly used a ...
and
butane Butane () or ''n''-butane is an alkane with the formula C4H10. Butane is a gas at room temperature and atmospheric pressure. Butane is a highly flammable, colorless, easily liquefied gas that quickly vaporizes at room temperature. The name but ...
, both of which are easily compressible gases under standard atmospheric conditions. It offers many of the advantages of compressed natural gas (CNG), but does not burn as cleanly, is denser than air and is much more easily compressed. Commonly used for cooking and space heating, LP gas and compressed propane are seeing increased use in motorized vehicles; propane is the third most commonly used motor fuel globally.


Carbon dioxide formation from petroleum fuels.

Petroleum fuels, when burnt, release carbon dioxide that is harmful to world climate. The amount of carbon dioxide released when one liter of fuel is combusted can be estimated: As a good approximation the chemical formula of e.g. diesel is . Note that diesel is a mixture of different molecules. As carbon has a molar mass of 12 g/mol and hydrogen (atomic!) has a molar mass of about 1 g/mol, so the fraction by weight of carbon in diesel is roughly 12/14. The reaction of diesel combustion is given by: 2 + 3n 2n + 2n Carbon dioxide has a molar mass of 44g/mol as it consists of 2 atoms of oxygen (16 g/mol) and 1 atom of carbon (12 g/mol). So 12 g of carbon yield 44 g of Carbon dioxide. Diesel has a density of 0.838 kg per liter. Putting everything together the mass of carbon dioxide that is produced by burning 1 liter of diesel can be calculated as: 0.838 kg/L \cdot \cdot = 2.63 kg/L The number of 2.63 kg of carbon dioxide from 1 liter of Diesel is close to the values found in the literature. For gasoline, with a density of 0.75 kg/L and a ratio of carbon to hydrogen atoms of about 6 to 14, the estimated value of carbon emission if 1 liter of gasoline is burnt gives: 0.75 kg/L \cdot \cdot = 2.3 kg/L


Non-petroleum fossil fuels

When petroleum is not easily available, chemical processes such as the
Fischer–Tropsch process The Fischer–Tropsch process is a collection of chemical reactions that converts a mixture of carbon monoxide and hydrogen, known as syngas, into liquid hydrocarbons. These reactions occur in the presence of metal catalysts, typically at temperat ...
can be used to produce liquid fuels from
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when dea ...
or
natural gas Natural gas (also called fossil gas or simply gas) is a naturally occurring mixture of gaseous hydrocarbons consisting primarily of methane in addition to various smaller amounts of other higher alkanes. Low levels of trace gases like carbo ...
. Synthetic fuels from coal were strategically important during World War II for the German military. Today synthetic fuels produced from natural gas are manufactured, to take advantage of the higher value of liquid fuels in transportation.


Natural gas

Natural gas Natural gas (also called fossil gas or simply gas) is a naturally occurring mixture of gaseous hydrocarbons consisting primarily of methane in addition to various smaller amounts of other higher alkanes. Low levels of trace gases like carbo ...
, composed chiefly of
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Eart ...
, can be compressed to a liquid and used as a substitute for other traditional liquid fuels. Its combustion is very clean compared to other
hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ex ...
fuels, but the fuel's low boiling point requires the fuel to be kept at high pressures to keep it in the liquid state. Though it has a much lower flash point than fuels such as gasoline, it is in many ways safer due to its higher
autoignition temperature The autoignition temperature or kindling point of a substance is the lowest temperature in which it spontaneously ignites in a normal atmosphere without an external source of ignition, such as a flame or spark. This temperature is required to su ...
and its low density, which causes it to dissipate when released in air.


Biodiesel

Biodiesel is similar to diesel but has differences akin to those between petrol and ethanol. For instance, biodiesel has a higher
cetane Hexadecane (also called cetane) is an alkane hydrocarbon with the chemical formula C16H34. Hexadecane consists of a chain of 16 carbon atoms, with three hydrogen atoms bonded to the two end carbon atoms, and two hydrogens bonded to each of the 14 ...
rating (45-60 compared to 45-50 for crude-oil-derived diesel) and it acts as a cleaning agent to get rid of dirt and deposits. It has been argued that it only becomes economically feasible above oil prices of $80 (£40 or €60 as of late February, 2007) per barrel. This does, however, depend on locality, economic situation, government stance on biodiesel and a host of other factors- and it has been proven to be viable at much lower costs in some countries. Also, it yields about 10% less energy than ordinary diesel. Analogous to the use of higher compression ratios used for engines burning higher octane alcohols and petrol in spark-ignition engines, taking advantage of biodiesel's high cetane rating can potentially overcome the energy deficit compared to ordinary Number 2 diesel.


Alcohols

Generally, the term alcohol refers to ethanol, the first
organic chemical In chemistry, organic compounds are generally any chemical compounds that contain carbon-hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The st ...
produced by humans, but any alcohol can be burned as a fuel.
Ethanol Ethanol (abbr. EtOH; also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound. It is an Alcohol (chemistry), alcohol with the chemical formula . Its formula can be also written as or (an ethyl ...
and
methanol Methanol (also called methyl alcohol and wood spirit, amongst other names) is an organic chemical and the simplest aliphatic alcohol, with the formula C H3 O H (a methyl group linked to a hydroxyl group, often abbreviated as MeOH). It is a ...
are the most common, being sufficiently inexpensive to be useful.


Methanol

Methanol is the lightest and simplest
alcohol Alcohol most commonly refers to: * Alcohol (chemistry), an organic compound in which a hydroxyl group is bound to a carbon atom * Alcohol (drug), an intoxicant found in alcoholic drinks Alcohol may also refer to: Chemicals * Ethanol, one of sev ...
, produced from the
natural gas Natural gas (also called fossil gas or simply gas) is a naturally occurring mixture of gaseous hydrocarbons consisting primarily of methane in addition to various smaller amounts of other higher alkanes. Low levels of trace gases like carbo ...
component
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Eart ...
. Its application is limited primarily due to its toxicity (similar to gasoline), but also due to its high
corrosivity Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engin ...
and miscibility with water. Small amounts are used in some types of gasoline to increase the
octane rating An octane rating, or octane number, is a standard measure of a fuel's ability to withstand compression in an internal combustion engine without detonating. The higher the octane number, the more compression the fuel can withstand before detonating ...
. Methanol-based fuels are used in some race cars and model aeroplanes. Methanol is also called ''methyl alcohol'' or ''wood alcohol'', the latter because it was formerly produced from the
distillation Distillation, or classical distillation, is the process of separation process, separating the components or substances from a liquid mixture by using selective boiling and condensation, usually inside an apparatus known as a still. Dry distilla ...
of wood. It is also known by the name ''methyl hydrate''.


Ethanol

Ethanol, also known as grain alcohol or ethyl alcohol, is commonly found in
alcoholic beverage An alcoholic beverage (also called an alcoholic drink, adult beverage, or a drink) is a drink that contains ethanol, a type of alcohol that acts as a drug and is produced by fermentation of grains, fruits, or other sources of sugar. The c ...
s. However, it may also be used as a fuel, most often in combination with gasoline. For the most part, it is used in a 9:1 ratio of gasoline to ethanol to reduce the negative environmental effects of gasoline. There is increasing interest in the use of a blend of 85% fuel ethanol blended with 15% gasoline. This fuel blend called E85 has a higher fuel octane than most premium types of gasoline. When used in a modern
Flexible fuel vehicle A flexible-fuel vehicle (FFV) or dual-fuel vehicle (colloquially called a flex-fuel vehicle) is an alternative fuel vehicle with an internal combustion engine designed to run on more than one fuel, usually gasoline blended with either ethanol o ...
, it delivers more performance to the gasoline it replaces at the expense of higher fuel consumption due to ethanol's lesser specific energy content. Ethanol for use in gasoline and industrial purposes may be considered a fossil fuel because it is often synthesized from the petroleum product
ethylene Ethylene (IUPAC name: ethene) is a hydrocarbon which has the formula or . It is a colourless, flammable gas with a faint "sweet and musky" odour when pure. It is the simplest alkene (a hydrocarbon with carbon-carbon double bonds). Ethylene i ...
, which is cheaper than production from
fermentation Fermentation is a metabolic process that produces chemical changes in organic substrates through the action of enzymes. In biochemistry, it is narrowly defined as the extraction of energy from carbohydrates in the absence of oxygen. In food ...
of
grains A grain is a small, hard, dry fruit (caryopsis) – with or without an attached hull layer – harvested for human or animal consumption. A grain crop is a grain-producing plant. The two main types of commercial grain crops are cereals and legumes ...
or
sugarcane Sugarcane or sugar cane is a species of (often hybrid) tall, Perennial plant, perennial grass (in the genus ''Saccharum'', tribe Andropogoneae) that is used for sugar Sugar industry, production. The plants are 2–6 m (6–20 ft) tall with ...
.


Butanol

Butanol is an
alcohol Alcohol most commonly refers to: * Alcohol (chemistry), an organic compound in which a hydroxyl group is bound to a carbon atom * Alcohol (drug), an intoxicant found in alcoholic drinks Alcohol may also refer to: Chemicals * Ethanol, one of sev ...
which can be used as a fuel in most gasoline internal combustion engines without engine modification. It is typically a product of the fermentation of
biomass Biomass is plant-based material used as a fuel for heat or electricity production. It can be in the form of wood, wood residues, energy crops, agricultural residues, and waste from industry, farms, and households. Some people use the terms bi ...
by the
bacterium Bacteria (; singular: bacterium) are ubiquitous, mostly free-living organisms often consisting of one biological cell. They constitute a large domain of prokaryotic microorganisms. Typically a few micrometres in length, bacteria were among ...
''Clostridium acetobutylicum'' (also known as the Weizmann organism). This process was first delineated by
Chaim Weizmann Chaim Azriel Weizmann ( he, חיים עזריאל ויצמן ', russian: Хаим Евзорович Вейцман, ''Khaim Evzorovich Veytsman''; 27 November 1874 – 9 November 1952) was a Russian-born biochemist, Zionist leader and Israel ...
in 1916 for the production of
acetone Acetone (2-propanone or dimethyl ketone), is an organic compound with the formula . It is the simplest and smallest ketone (). It is a colorless, highly volatile and flammable liquid with a characteristic pungent odour. Acetone is miscib ...
from
starch Starch or amylum is a polymeric carbohydrate consisting of numerous glucose units joined by glycosidic bonds. This polysaccharide is produced by most green plants for energy storage. Worldwide, it is the most common carbohydrate in human diets ...
for making
cordite Cordite is a family of smokeless propellants developed and produced in the United Kingdom since 1889 to replace black powder as a military propellant. Like modern gunpowder, cordite is classified as a low explosive because of its slow burni ...
, a smokeless gunpowder. The advantages of butanol are its high octane rating (over 100) and high energy content, only about 10% lower than gasoline, and subsequently about 50% more energy-dense than ethanol, 100% more so than methanol. Butanol's only major disadvantages are its high flashpoint (35 °C or 95 °F), toxicity (note that toxicity levels exist but are not precisely confirmed), and the fact that the fermentation process for renewable butanol emits a foul odour. The Weizmann organism can only tolerate butanol levels up to 2% or so, compared to 14% for ethanol and yeast. Making butanol from oil produces no such odour, but the limited supply and environmental impact of oil usage defeat the purpose of alternative fuels. The cost of butanol is about $1.25–$1.32 per kilogram ($0.57-$0.58 per pound or $4 approx. per US gallon). Butanol is much more expensive than ethanol (approximately $0.40 per litre or 1.50 per gallon) and methanol. On June 20, 2006, DuPont and BP announced that they were converting an existing ethanol plant to produce 9 million gallons (34 000 cubic meters) of butanol per year from sugar beets. DuPont stated a goal of being competitive with oil at $30–$40 per barrel ($0.19-$0.25 per liter) without subsidies, so the price gap with ethanol is narrowing.


Hydrogen

Liquefied hydrogen is the
liquid state A liquid is a nearly incompressible fluid that conforms to the shape of its container but retains a (nearly) constant volume independent of pressure. As such, it is one of the four fundamental states of matter (the others being solid, gas, an ...
of the element
hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, an ...
. It is a common liquid
rocket fuel Rocket propellant is the reaction mass of a rocket. This reaction mass is ejected at the highest achievable velocity from a rocket engine to produce thrust. The energy required can either come from the propellants themselves, as with a chemical ...
for
rocket A rocket (from it, rocchetto, , bobbin/spool) is a vehicle that uses jet propulsion to accelerate without using the surrounding air. A rocket engine produces thrust by reaction to exhaust expelled at high speed. Rocket engines work entirely fr ...
applications and can be used as a fuel in an
internal combustion engine An internal combustion engine (ICE or IC engine) is a heat engine in which the combustion of a fuel occurs with an oxidizer (usually air) in a combustion chamber that is an integral part of the working fluid flow circuit. In an internal combus ...
or
fuel cell A fuel cell is an electrochemical cell that converts the chemical energy of a fuel (often hydrogen) and an oxidizing agent (often oxygen) into electricity through a pair of redox reactions. Fuel cells are different from most batteries in requ ...
. Various concept
hydrogen vehicle A hydrogen vehicle is a vehicle that uses hydrogen fuel for motive power. Hydrogen vehicles include hydrogen-fueled space rockets, as well as ships and aircraft. Power is generated by converting the chemical energy of hydrogen to mechanical energ ...
s have been lower volumetric energy, the hydrogen volumes needed for combustion are large. Hydrogen was liquefied for the first time by
James Dewar Sir James Dewar (20 September 1842 – 27 March 1923) was a British chemist and physicist. He is best known for his invention of the vacuum flask, which he used in conjunction with research into the liquefaction of gases. He also studied a ...
in 1898.


Ammonia

Ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous was ...
(NH3) has been used as a fuel before at times when gasoline is unavailable (e.g. for buses in Belgium during WWII). It has a volumetric energy density of 17 Megajoules per liter (compared to 10 for hydrogen, 18 for methanol, 21 for dimethyl ether and 34 for gasoline). It must be compressed or cooled to be a liquid fuel, although it does not require
cryogenic In physics, cryogenics is the production and behaviour of materials at very low temperatures. The 13th IIR International Congress of Refrigeration (held in Washington DC in 1971) endorsed a universal definition of “cryogenics” and “cr ...
cooling as hydrogen does to be liquefied.


References


External links

* {{Authority control
Liquid fuels Liquid fuels are combustible or energy-generating molecules that can be harnessed to create mechanical energy, usually producing kinetic energy; they also must take the shape of their container. It is the fumes of liquid fuels that are flammable ...