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Lars Fredrik Nilson (27 May 1840 – 14 May 1899) was a Swedish
chemist A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a scientist trained in the study of chemistry. Chemists study the composition of matter and its properties. Chemists carefully describe th ...
, professor at
Uppsala University Uppsala University ( sv, Uppsala universitet) is a public research university in Uppsala, Sweden. Founded in 1477, it is the oldest university in Sweden and the Nordic countries still in operation. The university rose to significance during ...
, and later Director of the Agricultural Chemical Experiment Station at the
Royal Swedish Academy of Agriculture and Forestry The Royal Swedish Academy of Agriculture and Forestry ( sv, Kungliga Skogs- och Lantbruksakademien), formerly the Royal Swedish Academy of Agriculture (''Kungl. Lantbruksakademien''), founded in 1813 at the initiative of Crown Prince Charles, is o ...
in Stockholm. He discovered the element
scandium Scandium is a chemical element with the symbol Sc and atomic number 21. It is a silvery-white metallic d-block element. Historically, it has been classified as a rare-earth element, together with yttrium and the Lanthanides. It was discovered in ...
in 1879, by separating out
scandium(III) oxide Scandium(III) oxide or scandia is a inorganic compound with formula Sc2 O3. It is one of several oxides of rare earth elements with a high melting point. It is used in the preparation of other scandium compounds as well as in high-temperature sys ...
, also known as scandia. In addition to his work on the
analytic chemistry Analytical chemistry studies and uses instruments and methods to separate, identify, and quantify matter. In practice, separation, identification or quantification may constitute the entire analysis or be combined with another method. Separati ...
of elements and rare earths, he made substantial contributions to Swedish agriculture, including methods of fertilization and the introduction of
sugar beets Sugar is the generic name for sweet-tasting, soluble carbohydrates, many of which are used in food. Simple sugars, also called monosaccharides, include glucose, fructose, and galactose. Compound sugars, also called disaccharides or double ...
as a crop.


Education

Nilson was born in Skönberga parish in Östergötland, Sweden. Later his family moved to the island of Gotland, where his father, Nikolaus, owned Rosendal farm in Follingbo. In later life, Lars Fredrik Nilson retained a small holding on Gotland, which he visited yearly. After graduating from Wisby high school on Gotland, Lars Fredrik Nilson enrolled at
Uppsala University Uppsala University ( sv, Uppsala universitet) is a public research university in Uppsala, Sweden. Founded in 1477, it is the oldest university in Sweden and the Nordic countries still in operation. The university rose to significance during ...
in 1859. There he studied the natural sciences including zoology and biology. His work in mineralogy drew the attention of the chemistry professor at Uppsala, Lars Fredrik Svanberg, a former student of Jöns Jakob Berzelius. To obtain a Doctorate of Philosophy in Sweden, the candidate was expected to pass a series of examinations in all areas of study, including languages, history, and philosophy as well as their main area of study, within a fixed period of time. In 1865, just before Nilson could complete his final examination, his father became severely ill. Nilson returned home to Gotland, where he took over management of the farm, working in the fields as needed. When his father recovered some months later, the harvest and fall planting had been successfully completed, and Nilson had installed the first engine threshing machine to be used in Gotland. Nilson's own health had greatly benefited from his work on the farm: the young man who had arrived home in poor health had become much stronger. He was able to return to Uppsala and pass the next season's examinations, becoming a doctor of chemistry in 1866.


Career

In 1866, Nilson became an associate professor of chemistry at Uppsala, with the responsibilities of chief assistant and demonstrator of chemistry at Svanberg's laboratory. He was a calm and patient teacher, relying more on demonstrations than on lectures. He insisted that after the work of the day was completed, it was to be left behind, and not discussed during leisure. His earliest papers focused on sulfides,
arsenical Arsenicals are chemical compounds that contain arsenic. In a military context, the term arsenical refer to toxic arsenic compounds that are used as chemical warfare agents. This include blister agents, blood agents and vomiting agents. Examples Bl ...
sulfosalt minerals Sulfosalt minerals are sulfide minerals with the general formula , where *A represents a metal such as copper, lead, silver, iron, and rarely mercury, zinc, vanadium *B usually represents semi-metal such as arsenic, antimony, bismuth, and rare ...
, and
selenous acid Selenous acid (or selenious acid) is the chemical compound with the formula . Structurally, it is more accurately described by . It is the principal oxoacid of selenium; the other being selenic acid. Formation and properties Selenous acid is an ...
, extending the work of Berzelius.


Elements

In 1874 Nilson became professor of general and agricultural chemistry at Uppsala. From then on he could devote more time to research. He began working on rare earths such as
euxenite Euxenite, or euxenite-(Y) (the official mineralogical name), is a brownish black mineral with a metallic luster. Chemistry It contains calcium, niobium, tantalum, cerium, titanium, yttrium, and typically uranium and thorium, with some other met ...
and gadolinite, using methods of successive fractionation introduced by
Nils Johan Berlin Nils Johan Berlin (Nils Johannes Berlin) (18 February 1812 – 27 December 1891) was a Swedish chemist and physician, who held various professorships at the University of Lund from 1843 to 1864. Berlin was the first chemist who took the initiati ...
. One of his goals was to better understand the relationship of the newly discovered elements to the proposed
periodic system The periodic table, also known as the periodic table of the (chemical) elements, is a rows and columns arrangement of the chemical elements. It is widely used in chemistry, physics, and other sciences, and is generally seen as an icon o ...
. In 1879 Nilson separated out the oxide
scandia Scandza was described as a "great island" by Gothic-Byzantine historian Jordanes in his work ''Getica''. The island was located in the Arctic regions of the sea that surrounded the world. The location is usually identified with Scandinavia. Jor ...
. By doing so he discovered a new element,
scandium Scandium is a chemical element with the symbol Sc and atomic number 21. It is a silvery-white metallic d-block element. Historically, it has been classified as a rare-earth element, together with yttrium and the Lanthanides. It was discovered in ...
, which he named for Scandinavia. The discovery was of particular importance because the existence of an element with such properties, "ekaboron", had been predicted by Mendeleev, based on his organization of the
periodic system The periodic table, also known as the periodic table of the (chemical) elements, is a rows and columns arrangement of the chemical elements. It is widely used in chemistry, physics, and other sciences, and is generally seen as an icon o ...
. Nilson's spectral analysis indicated a previously unreported pattern of lines. Per Theodor Cleve demonstrated the equivalence of Nilson's scandium and Mendeleev's hypothetical ekaboron. Nilson and Sven Otto Pettersson were the first to isolate titanium metal in a relatively pure form, extracting a 95% pure sample in 1887.
Jöns Jacob Berzelius Baron Jöns Jacob Berzelius (; by himself and his contemporaries named only Jacob Berzelius, 20 August 1779 – 7 August 1848) was a Swedish chemist. Berzelius is considered, along with Robert Boyle, John Dalton, and Antoine Lavoisier, to be on ...
had extracted titanium metal in 1825, but only in a very impure form. In 1910 Matthew Hunter was finally able to produce 99.9% pure titanium metal, through his new
Hunter process The Hunter process was the first industrial process to produce pure ductile metallic titanium. It was invented in 1910 by Matthew A. Hunter, a chemist born in New Zealand who worked in the United States. The process involves reducing titanium tet ...
. Nilson also studied the gas density of metals which made it possible to determine the valence of various metals.


Agriculture

Nilson held the chair of analytical chemistry at Uppsala from 1878 until 1883, when he became professor of chemistry of the
Royal Swedish Academy of Agriculture and Forestry The Royal Swedish Academy of Agriculture and Forestry ( sv, Kungliga Skogs- och Lantbruksakademien), formerly the Royal Swedish Academy of Agriculture (''Kungl. Lantbruksakademien''), founded in 1813 at the initiative of Crown Prince Charles, is o ...
in Stockholm. As an agricultural chemist and Director of the Agricultural Chemical Experiment Station, he published nearly sixty papers on topics such as soils and manures. As a result of his inquiries many of the swamps of Gothland were drained and put under cultivation. The
sugar beet A sugar beet is a plant whose root contains a high concentration of sucrose and which is grown commercially for sugar production. In plant breeding, it is known as the Altissima cultivar group of the common beet (''Beta vulgaris''). Together w ...
was introduced and became a major crop, as chalky moors were treated with potash fertilizers. He also conducted studies on cow's milk and various plants for cattle
fodder Fodder (), also called provender (), is any agricultural foodstuff used specifically to feed domesticated livestock, such as cattle, rabbits, sheep, horses, chickens and pigs. "Fodder" refers particularly to food given to the animals (includin ...
. Nilson was elected a foreign member of the Chemical Society of Great Britain on February 2, 1888. Nilson was a member of several other academies as well. He received several awards, including the Order of the Polar Star.


References


Further reading

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English excerpt
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{{DEFAULTSORT:Nilson, Nils Fredrik Swedish chemists Uppsala University alumni 1840 births 1899 deaths Discoverers of chemical elements 19th-century Swedish scientists 19th-century chemists Scandium Order of the Polar Star Rare earth scientists Members of the Royal Society of Sciences in Uppsala