Luminescence (other)
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Luminescence is a
spontaneous emission Spontaneous emission is the process in which a quantum mechanical system (such as a molecule, an atom or a subatomic particle) transits from an excited energy state to a lower energy state (e.g., its ground state) and emits a quantized amount of ...
of
radiation In physics, radiation is the emission or transmission of energy in the form of waves or particles through space or through a material medium. This includes: * ''electromagnetic radiation'', such as radio waves, microwaves, infrared, visi ...
from an electronically or vibrationally excited species not in
thermal equilibrium Two physical systems are in thermal equilibrium if there is no net flow of thermal energy between them when they are connected by a path permeable to heat. Thermal equilibrium obeys the zeroth law of thermodynamics. A system is said to be in ...
with its environment. A luminescent object emits ''cold light'' in contrast to
incandescence Incandescence is the emission of electromagnetic radiation (including visible light) from a hot body as a result of its high temperature. The term derives from the Latin verb ''incandescere,'' to glow white. A common use of incandescence is ...
, where an object only emits light after heating. Generally, the emission of light is due to the movement of electrons between different energy levels within an atom after excitation by external factors. However, the exact mechanism of light emission in vibrationally excited species is unknown. The dials, hands, scales, and signs of aviation and navigational instruments and markings are often coated with luminescent materials in a process known as ''luminising''.


Types

*
Radioluminescence Radioluminescence is the phenomenon by which light is produced in a material by bombardment with ionizing radiation such as alpha particles, beta particles, or gamma rays. Radioluminescence is used as a low level light source for night illumi ...
, a result of bombardment by ionizing radiation *
Electroluminescence Electroluminescence (EL) is an optical phenomenon, optical and electrical phenomenon, in which a material emits light in response to the passage of an electric current or to a strong electric field. This is distinct from black body light emissi ...
, a result of an electric current passed through a substance **
Cathodoluminescence Cathodoluminescence is an optical and electromagnetic phenomenon in which electrons impacting on a luminescent material such as a phosphor, cause the emission of photons which may have wavelengths in the visible spectrum. A familiar example is th ...
, a result of a luminescent material being struck by electrons *
Chemiluminescence Chemiluminescence (also chemoluminescence) is the emission of light (luminescence) as the result of a chemical reaction. There may also be limited emission of heat. Given reactants A and B, with an excited intermediate ◊, : + -> lozenge -> ...
, the emission of light as a result of a
chemical reaction A chemical reaction is a process that leads to the IUPAC nomenclature for organic transformations, chemical transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the pos ...
**
Bioluminescence Bioluminescence is the production and emission of light by living organisms. It is a form of chemiluminescence. Bioluminescence occurs widely in marine vertebrates and invertebrates, as well as in some fungi, microorganisms including some b ...
, a result of biochemical reactions in a living organism **
Electrochemiluminescence Electrochemiluminescence or electrogenerated chemiluminescence (ECL) is a kind of luminescence produced during electrochemical reactions in solutions. In electrogenerated chemiluminescence, electrochemically generated intermediates undergo a highl ...
, a result of an
electrochemical reaction Electrochemistry is the branch of physical chemistry concerned with the relationship between electrical potential difference, as a measurable and quantitative phenomenon, and identifiable chemical change, with the potential difference as an outco ...
**
Lyoluminescence Lyoluminescence refers to the emission of light while dissolving a solid into a liquid solvent. It is a form of chemiluminescence. The most common lyoluminescent effect is seen when solid samples which have been heavily irradiated by ionizing radia ...
, a result of dissolving a solid (usually heavily irradiated) in a liquid solvent **
Candoluminescence Candoluminescence is the light given off by certain materials at elevated temperatures (usually when exposed to a flame) that has an intensity at some wavelengths which can, through chemical action in flames, be higher than the blackbody emission ex ...
, is light emitted by certain materials at elevated temperatures, which differs from the
blackbody A black body or blackbody is an idealized physical body that absorbs all incident electromagnetic radiation, regardless of frequency or angle of incidence. The name "black body" is given because it absorbs all colors of light. A black body ...
emission expected at the temperature in question. *
Mechanoluminescence Mechanoluminescence is light emission resulting from any mechanical action on a solid. It can be produced through ultrasound, or through other means. * Fractoluminescence is caused by stress that results in the formation of fractures. * Piezolumi ...
, a result of a mechanical action on a solid **
Triboluminescence Triboluminescence is a phenomenon in which light is generated when a material is mechanically pulled apart, ripped, scratched, crushed, or rubbed (see tribology). The phenomenon is not fully understood, but appears to be caused by the separation a ...
, generated when bonds in a material are broken when that material is scratched, crushed, or rubbed **
Fractoluminescence Triboluminescence is a phenomenon in which light is generated when a material is mechanically pulled apart, ripped, scratched, crushed, or rubbed (see tribology). The phenomenon is not fully understood, but appears to be caused by the separation a ...
, generated when bonds in certain crystals are broken by fractures **
Piezoluminescence Piezoluminescence is a form of luminescence created by pressure upon certain solids. This phenomenon is characterized by recombination processes involving electrons, holes and impurity ion centres. Some piezoelectric crystals give off a certain amo ...
, produced by the action of pressure on certain solids **
Sonoluminescence Sonoluminescence is the emission of light from imploding bubbles in a liquid when excited by sound. History The sonoluminescence effect was first discovered at the University of Cologne in 1934 as a result of work on sonar. Hermann Frenzel and ...
, a result of imploding bubbles in a liquid when excited by sound *
Crystalloluminescence Crystalloluminescence is the effect of luminescence produced during crystallization. The phenomenon was first reported in the 1800s from the rapid crystallization of potassium sulfate from an aqueous solution An aqueous solution is a solution i ...
, produced during
crystallization Crystallization is the process by which solid forms, where the atoms or molecules are highly organized into a structure known as a crystal. Some ways by which crystals form are precipitating from a solution, freezing, or more rarely deposi ...
*
Thermoluminescence Thermoluminescence is a form of luminescence that is exhibited by certain crystalline materials, such as some minerals, when previously absorbed energy from electromagnetic radiation or other ionizing radiation is re-emitted as light upon he ...
, the re-emission of absorbed energy when a substance is heated ** Cryoluminescence, the emission of light when an object is cooled (an example of this is
wulfenite Wulfenite is a lead molybdate mineral with the formula Pb Mo O4. It can be most often found as thin tabular crystals with a bright orange-red to yellow-orange color, sometimes brown, although the color can be highly variable. In its yellow form ...
) *
Photoluminescence Photoluminescence (abbreviated as PL) is light emission from any form of matter after the absorption of photons (electromagnetic radiation). It is one of many forms of luminescence (light emission) and is initiated by photoexcitation (i.e. photon ...
, a result of the absorption of photons **
Fluorescence Fluorescence is the emission of light by a substance that has absorbed light or other electromagnetic radiation. It is a form of luminescence. In most cases, the emitted light has a longer wavelength, and therefore a lower photon energy, tha ...
, traditionally defined as the emission of light that ends immediately after the source of excitation is removed. As the definition does not fully describe the phenomenon, quantum mechanics is employed where it is defined as there is no change in spin multiplicity from the state of excitation to emission of light. **
Phosphorescence Phosphorescence is a type of photoluminescence related to fluorescence. When exposed to light (radiation) of a shorter wavelength, a phosphorescent substance will glow, absorbing the light and reemitting it at a longer wavelength. Unlike fluo ...
, traditionally defined as persistent emission of light after the end of excitation. As the definition does not fully describe the phenomenon, quantum mechanics is employed where it is defined as there is a change in spin multiplicity from the state of excitation to the emission of light.


Applications

*
Light-emitting diode A light-emitting diode (LED) is a semiconductor device that emits light when current flows through it. Electrons in the semiconductor recombine with electron holes, releasing energy in the form of photons. The color of the light (cor ...
s (LEDs) emit light via electro-luminescence. *
Phosphor A phosphor is a substance that exhibits the phenomenon of luminescence; it emits light when exposed to some type of radiant energy. The term is used both for fluorescent or phosphorescent substances which glow on exposure to ultraviolet or vi ...
s, materials that emit light when irradiated by higher-energy
electromagnetic radiation In physics, electromagnetic radiation (EMR) consists of waves of the electromagnetic field, electromagnetic (EM) field, which propagate through space and carry momentum and electromagnetic radiant energy. It includes radio waves, microwaves, inf ...
or
particle radiation Particle radiation is the radiation of energy by means of fast-moving subatomic particles. Particle radiation is referred to as a particle beam if the particles are all moving in the same direction, similar to a light beam. Due to the wave–par ...
*
Laser A laser is a device that emits light through a process of optical amplification based on the stimulated emission of electromagnetic radiation. The word "laser" is an acronym for "light amplification by stimulated emission of radiation". The fir ...
, and
lamp Lamp, Lamps or LAMP may refer to: Lighting * Oil lamp, using an oil-based fuel source * Kerosene lamp, using kerosene as a fuel * Electric lamp, or light bulb, a replaceable component that produces light from electricity * Light fixture, or ligh ...
industry *
Phosphor thermometry Phosphor thermometry is an optical method for surface temperature measurement. The method exploits luminescence emitted by phosphor material. Phosphors are fine white or pastel-colored inorganic powders which may be stimulated by any of a variety of ...
, measuring temperature using
phosphorescence Phosphorescence is a type of photoluminescence related to fluorescence. When exposed to light (radiation) of a shorter wavelength, a phosphorescent substance will glow, absorbing the light and reemitting it at a longer wavelength. Unlike fluo ...
*
Thermoluminescence dating Thermoluminescence dating (TL) is the determination, by means of measuring the accumulated radiation dose, of the time elapsed since material containing crystalline minerals was either heated (lava, ceramics) or exposed to sunlight (sediments ...
*
Thermoluminescent dosimeter A thermoluminescent dosimeter, or TLD, is a type of radiation dosimeter, consisting of a piece of a thermoluminescent crystalline material inside a radiolucent package. When a thermoluminescent crystal is exposed to ionizing radiation, it abso ...
* Non-disruptive observation of processes within a
cell Cell most often refers to: * Cell (biology), the functional basic unit of life Cell may also refer to: Locations * Monastic cell, a small room, hut, or cave in which a religious recluse lives, alternatively the small precursor of a monastery w ...
. Luminescence occurs in some
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...
s when they are exposed to low-powered sources of
ultraviolet Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nanometer, nm (with a corresponding frequency around 30 Hertz, PHz) to 400 nm (750 Hertz, THz), shorter than that of visible light, but longer than ...
or
infrared Infrared (IR), sometimes called infrared light, is electromagnetic radiation (EMR) with wavelengths longer than those of visible light. It is therefore invisible to the human eye. IR is generally understood to encompass wavelengths from around ...
electromagnetic radiation In physics, electromagnetic radiation (EMR) consists of waves of the electromagnetic field, electromagnetic (EM) field, which propagate through space and carry momentum and electromagnetic radiant energy. It includes radio waves, microwaves, inf ...
(for example, portable UV lamps) at
atmospheric pressure Atmospheric pressure, also known as barometric pressure (after the barometer), is the pressure within the atmosphere of Earth. The standard atmosphere (symbol: atm) is a unit of pressure defined as , which is equivalent to 1013.25 millibars, 7 ...
and atmospheric temperatures. This property of these minerals can be used during the process of mineral identification at rock
outcrop An outcrop or rocky outcrop is a visible exposure of bedrock or ancient superficial deposits on the surface of the Earth. Features Outcrops do not cover the majority of the Earth's land surface because in most places the bedrock or superficial ...
s in the
field Field may refer to: Expanses of open ground * Field (agriculture), an area of land used for agricultural purposes * Airfield, an aerodrome that lacks the infrastructure of an airport * Battlefield * Lawn, an area of mowed grass * Meadow, a grass ...
or in the laboratory.


History

The term ''luminescence'' was first introduced in 1888."Über Fluorescenz und Phosphorescenz, I. Abhandlung"
(On fluorescence and phosphorescence, first paper), ''Annalen der Physik und Chemie'', 34: 446-463. From page 447: "Ich möchte für diese zweite Art der Lichterregung, für die uns eine einheitliche Benennung fehlt, den Namen Luminescenz vorschlagen, und Körper, die in dieser Weise leuchten, luminescirende nennen." or this second type of light excitation, for which we lack a consistent name, I would like to suggest the name of "luminescence", and call "luminescing" [anybodies that glow in this way.">ny">or this second type of light excitation, for which we lack a consistent name, I would like to suggest the name of "luminescence", and call "luminescing" [anybodies that glow in this way./ref>


See also

* List of light sources * Scientific American,
Luminous Paint
(historical aspects), 10-Dec-1881, pp.368 *
High-visibility clothing High-visibility clothing, sometimes shortened to hi vis or hi viz, is any clothing worn that is highly luminescent in its natural matt property or a color that is easily discernible from any background. It is most commonly worn on the torso and ...


References


External links


Fluorophores.org A database of luminescent dyes
{{Authority control Light sources 1880s neologisms