Lithium bis(trifluoromethanesulfonyl)imide, often simply referred to as LiTFSI, is a
hydrophilic
A hydrophile is a molecule or other molecular entity that is attracted to water molecules and tends to be dissolved by water.Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon'' Oxford: Clarendon Press.
In contrast, hydrophobes are ...
salt with the chemical formula LiC
2F
6NO
4S
2. It is commonly used as Li-ion source in
electrolytes
An electrolyte is a medium containing ions that is electrically conducting through the movement of those ions, but not conducting electrons. This includes most soluble salts, acids, and bases dissolved in a polar solvent, such as water. Upon di ...
for Li-ion batteries as a safer alternative to commonly used
lithium hexafluorophosphate
Lithium hexafluorophosphate is an inorganic compound with the formula Li PF6. It is a white crystalline powder.
Production
LiPF6 is manufactured by reacting phosphorus pentachloride with hydrogen fluoride and lithium fluoride
:PCl5 + LiF + ...
. It is made up of one Li cation and a
bistriflimide anion.
Because of its very high solubility in water (> 21
m), LiTFSI has been used as lithium salt in water-in-salt electrolytes for
aqueous lithium-ion batteries.
References
Lithium salts
Lithium-ion batteries
Organolithium compounds
Trifluoromethyl compounds
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