The term liquid color or liquid color concentrate describes to a system consisting of a liquid binder (carrier),

dyes A dye is a colored substance that chemically bonds to the substrate to which it is being applied. This distinguishes dyes from pigments which do not chemically bind to the material they color. Dye is generally applied in an aqueous solution and ...

pigments A pigment is a colored material that is completely or nearly insoluble in water. In contrast, dyes are typically soluble, at least at some stage in their use. Generally dyes are often organic compounds whereas pigments are often inorganic compou ...

and other additives such as process additives, stabilisers or similar. The liquid colors are mixed into the plastic (raw

polymer A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic a ...

or recyclat) for coloring or changing the properties. In general, there are three groups of liquid colors. * Liquid colors, which are used to color plastic products. * Liquid additive concentrates that provide specific properties in the end products, such as UV stabilization, flame retardancy,

antistatic An antistatic agent is a compound used for treatment of materials or their surfaces in order to reduce or eliminate buildup of static electricity. Static charge may be generated by the triboelectric effect or by a non-contact process using a high ...

or anti-blocking. * Combination liquid colors that contain both colorants and additives.

History and market relevance

So-called liquid colours have been used for colouring plastics since the end of the 1960s / beginning of the 1970s. However, liquid colours are still not used extensively and have a market share of just 7 % in Europe compared to 93 % for

masterbatch Masterbatch (MB) is a solid additive used for coloring (color masterbatch) or imparting other properties (additive masterbatch) to plastics. Masterbatch is a concentrated mixture of pigments and/or additives which is manufactured by encapsulation du ...

colouring. This is different in the US, where the market share of liquid colors is about 40 %. This is mainly due to the inadequate dosing technology in the early days and the associated contamination in the production area. As a result, the liquid colorant gained a bad reputation and is still not very popular with processors, although the dosing systems have been adapted to the requirements of users, especially in the last decade, and clean and easy handling is possible.

Fields of application

It is possible to add liquid colors to a variety of thermoplastic and thermoset processing methods, such as * Film extrusion/ thermoforming sheets * Foam extrusion * Blown films * Profile extrusion *

Injection moulding Injection moulding (U.S. spelling: injection molding) is a manufacturing process for producing parts by injecting molten material into a mould, or mold. Injection moulding can be performed with a host of materials mainly including metals (for ...

Fachagentur Nachwachsende Rohstoffe e.V. (Hrsg.): . März 2016 (www.biokunststoffe-verarbeiten.de). * Injection blow moulding * Sealing compounds * Plastisol hot dipping process The products obtained from the processing methods are used in the following areas, for example: * Packaging industry * Medical Technology *

Automotive Industry The automotive industry comprises a wide range of company, companies and organizations involved in the design, Business development, development, manufacturing, marketing, and selling of motor vehicles. It is one of the world's largest industry ...

* furniture industry * Electronics industry * Toy industry

Manufacture

Depending on the plastic, the choice of the liquid carrier is decisive due to the processing temperatures, compatibility and the later application. In order to prevent migration of the carrier liquid as far as possible, well-tolerated liquid carriers are used which interact with the polymer. The typical components are: *

Fatty acid esters Fatty is a derogatory term for someone who is obese. It may refer also to: People * Mai Fatty, Gambian politician * Roscoe Arbuckle (1887–1933), American actor and comedian * Fatty Briody (1858–1903), American Major League Baseball player * ...

or fatty acid ester ethoxylates *

Plasticisers A plasticizer ( UK: plasticiser) is a substance that is added to a material to make it softer and more flexible, to increase its plasticity, to decrease its viscosity, and/or to decrease friction during its handling in manufacture. Plasticiz ...

* Paraffin, mineral and natural oils * Alkyd oils * Polyisobutylene * Polyhydric alcohols or alcohol ethoxylates * Lubricant * Antistatics Different mixtures of the components are also used. The pigment preparations are produced in batches. For this the formulation components are distributed into a binder previously selected for the respective application and then dispersed. The most optimal breaking up of agglomerates is crucial to ensure a high effectiveness of the colour concentrates and / or functional process additives. Dissolvers, bead mills and roller mills are usually used here. For transparent, thin film applications, particularly well broken down pigments are required. In practice, particle sizes < 5 μm have proven successful for film applications.

Dosing technology

The liquid colours can be dosed in different ways. The simplest possibility is to use a so-called drum. Here the polymer granulate is wetted with the liquid color, homogenized in a mixing device and usually processed further. In large-scale applications, aggregates such as peristaltic pumps, Progressive Cavity Pumps or gear pumps are usually used. Here, the dosing can take place above the hopper or directly into the melt.

Advantages and Disadvantages

Positive effect of color intensity and light scattering of liquid colors

Advantages

Due to batch production, the pigments can be broken down in the liquid carrier medium until they are optimally dispersed. The particles are therefore very finely distributed, which has a positive effect on color intensity and light scattering. Each batch can be controlled in terms of colour, viscosity and particle size distribution and, if necessary, corrected as a whole. If the liquid colorant is added to the main hopper together with the raw polymer, the distribution of the liquid colorant is statistically better than that of masterbatch even before melting. Without additional mixing units, a homogeneous, streak-free coloration can be achieved with highly concentrated liquid color from 0.5 % dosage. Due to the wetting with liquid carrier, the pigments adhere less strongly to the metal components of the processing machines, which results in sometimes significantly reduced color change times. Especially when using hot runner systems, the number of cleaning cycles can be reduced. In addition, it is possible to inject the liquid colorant downstream into the plastic melt with appropriate dosing technology. This means that only part of the production line has to be flushed when changing colors, which saves a considerable amount of material and time. The production of the liquid colours takes place at room temperature. A maximum of 40 °C is achieved by shearing. This means that heat-sensitive pigments such as fluorescent or daylight pigments are not thermally damaged. Defect patterns such as black specks and streaks are reduced and rejects are minimized. Liquid colors do not have to be pre-dried, which reduces energy costs and handling effort and also further reduces the thermal preload. The coloring of bio-based plastics with liquid colors leads to an increase in characteristic values in the notched bar impact test.

Disadvantages

The disadvantages are the high cleaning effort without using suitable dosing equipment. When dosing in the feed zone, very high colouring concentrations are not possible, since above a certain colour dosing level, overlubrication of the plasticizing screw can occur system-related. This means an excessive liquid film on the plasticizing screw, which hinders the uniform conveying of the polymer granulate. The maximum color dosage depends heavily on the polymer used (particle size, surface finish and surface energy), the machine configurations and the pigment load of the liquid color. This can cause problems with very thin-walled parts that must be colored as opaque as possible, or even prevent coloring with liquid color altogether. If the liquid colorants are not sufficiently stabilized, the colorants may settle. This can lead to uncontrolled flocculation, i.e. pigment particles are in direct contact with each other and can only be separated from each other by high shear forces. When suitable additives are used, pigment particles are connected to a network via additive molecules. Thus there is no direct pigment-pigment contact. Such flocculates can be destroyed by low shear forces, such as manual stirring.

References

Dyes Plastics additives {{chemistry-stub