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A liquid-propellant rocket or liquid rocket utilizes a
rocket engine A rocket engine uses stored rocket propellants as the reaction mass for forming a high-speed propulsive Jet (fluid), jet of fluid, usually high-temperature gas. Rocket engines are reaction engines, producing thrust by ejecting mass rearward, i ...
that uses liquid propellants. Liquids are desirable because they have a reasonably high density and high specific impulse (''I''sp). This allows the volume of the propellant tanks to be relatively low. It is also possible to use lightweight centrifugal turbopumps to pump the rocket propellant from the tanks into the combustion chamber, which means that the propellants can be kept under low pressure. This permits the use of low-mass propellant tanks that do not need to resist the high pressures needed to store significant amounts of gasses, resulting in a low mass ratio for the rocket. An inert gas stored in a tank at a high pressure is sometimes used instead of pumps in simpler small engines to force the propellants into the combustion chamber. These engines may have a higher mass ratio, but are usually more reliable, and are therefore used widely in satellites for orbit maintenance. Liquid rockets can be monopropellant rockets using a single type of propellant, or bipropellant rockets using two types of propellant. Tripropellant rockets using three types of propellant are rare. Some designs are throttleable for variable thrust operation and some may be restarted after a previous in-space shutdown. Liquid propellants are also used in hybrid rockets, with some of the advantages of a solid rocket.


History


Russia / Soviet Union

The idea of a liquid rocket as understood in the modern context first appeared in 1903 in the book ''Exploration of the Universe with Rocket-Propelled Vehicles'', by the Russian school teacher Konstantin Tsiolkovsky.The magnitude of his contribution to astronautics is astounding, including the Tsiolkovsky rocket equation, multi staged rockets and using liquid oxygen and liquid hydrogen in liquid propellant rockets. Tsiolkovsky influenced later rocket scientists throughout Europe, like Wernher von Braun. Soviet search teams at Peenemünde found a German translation of a book by Tsiolkovsky of which "almost every page...was embellished by von Braun's comments and notes." Leading Soviet rocket-engine designer Valentin Glushko and rocket designer Sergey Korolev studied Tsiolkovsky's works as youths, and both sought to turn Tsiolkovsky's theories into reality. From 1929 to 1930 in
Leningrad Saint Petersburg ( rus, links=no, Санкт-Петербург, a=Ru-Sankt Peterburg Leningrad Petrograd Piter.ogg, r=Sankt-Peterburg, p=ˈsankt pʲɪtʲɪrˈburk), formerly known as Petrograd (1914–1924) and later Leningrad (1924–1991), i ...
Glushko pursued rocket research at the Gas Dynamics Laboratory (GDL), where a new research section was set up for the study of liquid-propellant and electric rocket engines. This resulted in the creation of ORM (from "Experimental Rocket Motor" in Russian) engines to . A total of 100 bench tests of liquid-propellant rockets were conducted using various types of fuel, both low and high-boiling and thrust up to 300 kg was achieved. During this period in
Moscow Moscow ( , US chiefly ; rus, links=no, Москва, r=Moskva, p=mɐskˈva, a=Москва.ogg) is the capital and largest city of Russia. The city stands on the Moskva River in Central Russia, with a population estimated at 13.0 million ...
Fredrich Tsander, a scientist and inventor was designing and building liquid rocket engines which ran on compressed air and gasoline. Tsander used it to investigate high-energy fuels including powdered metals mixed with gasoline. In September 1931 Tsander formed the Moscow based ' Group for the Study of Reactive Motion', better known by its Russian acronym “GIRD”. In May 1932, Sergey Korolev replaced Tsander as the head of GIRD. Mikhail Tikhonravov launched the first Soviet liquid propelled rocket, fueled by liquid oxygen and jellied gasoline, the GIRD-9, took place on 17 August 1933, which reached an altitude of . In January 1933 Tsander began development of the GIRD-X rocket. This design burned liquid oxygen and gasoline and was one of the first engines to be regeneratively cooled by the liquid oxygen, which flowed around the inner wall of the combustion chamber before entering it. Problems with burn-through during testing prompted a switch from gasoline to less energetic alcohol. The final missile, long by in diameter, had a mass of , and it was anticipated that it could carry a payload to an altitude of . The GIRD X rocket was launched on 25 November 1933 and flew to a height of 80 meters. In 1933 GDL and GIRD merged and became the Reactive Scientific Research Institute (RNII). At RNII Gushko continued the development of liquid propellant rocket engines ОРМ-53 to ОРМ-102, with powering the RP-318 rocket-powered aircraft. In 1938 Leonid Dushkin replaced Glushko and continued development of the ORM engines, including the engine for the rocket powered interceptor, the Bereznyak-Isayev BI-1. At RNII Tikhonravov worked on developing oxygen/alcohol liquid-propellant rocket engines. Ultimately liquid propellant rocket engines were given a low priority during the late 1930s at RNII, however the research was productive and very important for later achievements of the Soviet rocket program.


France

Pedro Paulet wrote a letter to ''El Comercio'' in
Lima Lima ( ; ), originally founded as Ciudad de Los Reyes (City of The Kings) is the capital and the largest city of Peru. It is located in the valleys of the Chillón, Rímac and Lurín Rivers, in the desert zone of the central coastal part of t ...
in 1927, claiming he had experimented with a liquid rocket engine while he was a student in Paris three decades earlier. Historians of early rocketry experiments, among them Max Valier, Willy Ley, and John D. Clark, have given differing amounts of credence to Paulet's report. Valier applauded Paulet's liquid-propelled rocket design in the Verein für Raumschiffahrt publication ''Die Rakete'', saying the engine had "amazing power" and that his plans were necessary for future rocket development. Wernher von Braun would later describe Paulet as "the pioneer of the liquid fuel propulsion motor" and stated that "Paulet helped man reach the Moon". Paulet was approached by
Nazi Germany Nazi Germany (lit. "National Socialist State"), ' (lit. "Nazi State") for short; also ' (lit. "National Socialist Germany") (officially known as the German Reich from 1933 until 1943, and the Greater German Reich from 1943 to 1945) was ...
to help develop rocket technology, though he refused to assist and never shared the formula for his propellant.


United States

The first ''flight'' of a liquid-propellant rocket took place on March 16, 1926 at
Auburn, Massachusetts Auburn is a town in Worcester County, Massachusetts, United States. The population was 16,889 at the 2020 census. History The Auburn area was first settled in 1714 as of today outer parts of Worcester, Sutton, Leicester and Oxford, Massachus ...
, when American professor Dr. Robert H. Goddard launched a vehicle using liquid oxygen and gasoline as propellants. The rocket, which was dubbed "Nell", rose just 41 feet during a 2.5-second flight that ended in a cabbage field, but it was an important demonstration that rockets utilizing liquid propulsion were possible. Goddard proposed liquid propellants about fifteen years earlier and began to seriously experiment with them in 1921. The German-Romanian Hermann Oberth published a book in 1922 suggesting the use of liquid propellants.


Germany

In Germany, engineers and scientists became enthralled with liquid propulsion, building and testing them in the late 1920s within Opel RAK, the world's first rocket program, in Rüsselsheim. According to Max Valier's account, Opel RAK rocket designer, Friedrich Wilhelm Sander launched two liquid-fuel rockets at Opel Rennbahn in Rüsselsheim on April 10 and April 12, 1929. These Opel RAK rockets have been the first European, and after Goddard the world's second, liquid-fuel rockets in history. In his book “Raketenfahrt” Valier describes the size of the rockets as of 21 cm in diameter and with a length of 74 cm, weighing 7 kg empty and 16 kg with fuel. The maximum thrust was 45 to 50 kp, with a total burning time of 132 seconds. These properties indicate a gas pressure pumping. The main purpose of these tests was to develop the liquid rocket-propulsion system for a Gebrüder-Müller-Griessheim aircraft under construction for a planned flight across the English channel. Also spaceflight historian
Frank H. Winter Frank H. Winter (born 1942) is an American historian and writer. He is the retired Curator of Rocketry of the National Air and Space Museum (NASM) of the Smithsonian Institution of Washington, D.C. Winter is also an internationally recognized hist ...
, curator at National Air and Space Museum in Washington, DC, confirms the Opel group was working, in addition to their solid-fuel rockets used for land-speed records and the world's first manned rocket-plane flights with the
Opel RAK.1 The Opel RAK.1 (also known as the Opel RAK.3) was the world's first purpose-built rocket-powered aircraft. It was designed and built by Julius Hatry under commission from Fritz von Opel, who flew it on September 30, 1929 in front of a large crowd ...
, on liquid-fuel rockets. By May 1929, the engine produced a thrust of 200 kg (440 lb.) "for longer than fifteen minutes and in July 1929, the Opel RAK collaborators were able to attain powered phases of more than thirty minutes for thrusts of 300 kg (660-lb.) at Opel's works in Rüsselsheim," again according to Max Valier's account. The Great Depression brought an end to the Opel RAK activities. After working for the German military in the early 1930s, Sander was arrested by Gestapo in 1935, when private rocket-engineering became forbidden in Germany. He was convicted of treason to 5 years in prison and forced to sell his company, he died in 1938. Max Valier's (via Arthur Rudolph and Heylandt), who died while experimenting in 1930, and Friedrich Sander's work on liquid-fuel rockets was confiscated by the German military, the Heereswaffenamt and integrated into the activities under General Walter Dornberger in the early and mid-1930s in a field near Berlin. Max Valier was a co-founder of an amateur research group, the VfR, working on liquid rockets in the early 1930s, and many of whose members eventually became important rocket technology pioneers, including Wernher von Braun. Von Braun served as head of the army research station that designed the V-2 rocket weapon for the Nazis. By the late 1930s, use of rocket propulsion for manned flight began to be seriously experimented with, as Germany's Heinkel He 176 made the first manned rocket-powered flight using a liquid rocket engine, designed by German aeronautics engineer Hellmuth Walter on June 20, 1939. The only production rocket-powered combat aircraft ever to see military service, the Me 163 ''Komet'' in 1944-45, also used a Walter-designed liquid rocket engine, the Walter HWK 109-509, which produced up to 1,700 kgf (16.7 kN) thrust at full power.


Post World War II

After World War II the American government and military finally seriously considered liquid-propellant rockets as weapons and began to fund work on them. The Soviet Union did likewise, and thus began the Space Race. In 2010s 3D printed engines started being used for spaceflight. Examples of such engines include SuperDraco used in launch escape system of the SpaceX Dragon 2 and also engines used for first or second stages in launch vehicles from
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, Orbex, Relativity Space, Skyrora, or Launcher.


Types

Liquid rockets have been built as monopropellant rockets using a single type of propellant, bipropellant rockets using two types of propellant, or more exotic tripropellant rockets using three types of propellant. Bipropellant liquid rockets generally use a liquid
fuel A fuel is any material that can be made to react with other substances so that it releases energy as thermal energy or to be used for work. The concept was originally applied solely to those materials capable of releasing chemical energy bu ...
, such as liquid hydrogen or a hydrocarbon fuel such as RP-1, and a liquid oxidizer, such as liquid oxygen. The engine may be a cryogenic rocket engine, where the fuel and oxidizer, such as hydrogen and oxygen, are gases which have been liquefied at very low temperatures. Liquid-propellant rockets can be throttled (thrust varied) in realtime, and have control of mixture ratio (ratio at which oxidizer and fuel are mixed); they can also be shut down, and, with a suitable ignition system or self-igniting propellant, restarted. Hybrid rockets apply a liquid or gaseous oxidizer to a solid fuel.


Principle of operation

All liquid rocket engines have tankage and pipes to store and transfer propellant, an injector system, a combustion chamber which is very typically cylindrical, and one (sometimes two or more) rocket nozzles. Liquid systems enable higher specific impulse than solids and hybrid rocket motors and can provide very high tankage efficiency. Unlike gases, a typical liquid propellant has a density similar to water, approximately 0.7–1.4g/cm³ (except liquid hydrogen which has a much lower density), while requiring only relatively modest pressure to prevent vaporization. This combination of density and low pressure permits very lightweight tankage; approximately 1% of the contents for dense propellants and around 10% for liquid hydrogen (due to its low density and the mass of the required insulation). For injection into the combustion chamber, the propellant pressure at the injectors needs to be greater than the chamber pressure; this can be achieved with a pump. Suitable pumps usually use centrifugal turbopumps due to their high power and light weight, although
reciprocating pump A reciprocating pump is a class of positive-displacement pumps that includes the piston pump, plunger pump, and diaphragm pump. Well maintained, reciprocating pumps can last for decades. Unmaintained, however, they can succumb to wear and tear. It i ...
s have been employed in the past. Turbopumps are usually extremely lightweight and can give excellent performance; with an on-Earth weight well under 1% of the thrust. Indeed, overall
rocket engine A rocket engine uses stored rocket propellants as the reaction mass for forming a high-speed propulsive Jet (fluid), jet of fluid, usually high-temperature gas. Rocket engines are reaction engines, producing thrust by ejecting mass rearward, i ...
thrust to weight ratio Thrust-to-weight ratio is a dimensionless ratio of thrust to weight of a rocket, jet engine, propeller engine, or a vehicle propelled by such an engine that is an indicator of the performance of the engine or vehicle. The instantaneous thrust-to-w ...
s including a turbopump have been as high as 155:1 with the SpaceX Merlin 1D rocket engine and up to 180:1 with the vacuum version Alternatively, instead of pumps, a heavy tank of a high-pressure inert gas such as helium can be used, and the pump forgone; but the delta-v that the stage can achieve is often much lower due to the extra mass of the tankage, reducing performance; but for high altitude or vacuum use the tankage mass can be acceptable. The major components of a rocket engine are therefore the combustion chamber (thrust chamber), pyrotechnic igniter, propellant feed system, valves, regulators, the propellant tanks, and the rocket engine nozzle. In terms of feeding propellants to the combustion chamber, liquid-propellant engines are either pressure-fed or pump-fed, and pump-fed engines work in either a gas-generator cycle, a staged-combustion cycle, or an expander cycle. A liquid rocket engine can be tested prior to use, whereas for a solid rocket motor a rigorous quality management must be applied during manufacturing to ensure high reliability. A Liquid rocket engine can also usually be reused for several flights, as in the Space Shuttle and Falcon 9 series rockets, although reuse of solid rocket motors was also effectively demonstrated during the shuttle program. Use of liquid propellants can be associated with a number of issues: * Because the propellant is a very large proportion of the mass of the vehicle, the center of mass shifts significantly rearward as the propellant is used; one will typically lose control of the vehicle if its center mass gets too close to the center of drag/pressure. * When operated within an atmosphere, pressurization of the typically very thin-walled propellant tanks must guarantee positive gauge pressure at all times to avoid catastrophic collapse of the tank. * Liquid propellants are subject to '' slosh'', which has frequently led to loss of control of the vehicle. This can be controlled with slosh baffles in the tanks as well as judicious control laws in the guidance system. * They can suffer from pogo oscillation where the rocket suffers from uncommanded cycles of acceleration. * Liquid propellants often need ullage motors in zero-gravity or during staging to avoid sucking gas into engines at start up. They are also subject to vortexing within the tank, particularly towards the end of the burn, which can also result in gas being sucked into the engine or pump. * Liquid propellants can leak, especially
hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic ...
, possibly leading to the formation of an explosive mixture. * Turbopumps to pump liquid propellants are complex to design, and can suffer serious failure modes, such as overspeeding if they run dry or shedding fragments at high speed if metal particles from the manufacturing process enter the pump. * Cryogenic propellants, such as liquid oxygen, freeze atmospheric water vapor into ice. This can damage or block seals and valves and can cause leaks and other failures. Avoiding this problem often requires lengthy ''chilldown'' procedures which attempt to remove as much of the vapor from the system as possible. Ice can also form on the outside of the tank, and later fall and damage the vehicle. External foam insulation can cause issues as shown by the Space Shuttle Columbia disaster. Non-cryogenic propellants do not cause such problems. * Non-storable liquid rockets require considerable preparation immediately before launch. This makes them less practical than solid rockets for most weapon systems.


Propellants

Thousands of combinations of fuels and oxidizers have been tried over the years. Some of the more common and practical ones are:


Cryogenic

* Liquid oxygen ( LOX, O2) and liquid
hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic ...
( LH, H2) – Space Shuttle main engines,
Ariane 5 Ariane 5 is a European heavy-lift space launch vehicle developed and operated by Arianespace for the European Space Agency (ESA). It is launched from the Centre Spatial Guyanais (CSG) in French Guiana. It has been used to deliver payloads in ...
main stage and the Ariane 5 ECA second stage, the BE-3 of Blue Origin's New Shepard, the first and second stage of the Delta IV, the upper stages of the Ares I,
Saturn V Saturn V is a retired American super heavy-lift launch vehicle developed by NASA under the Apollo program for human exploration of the Moon. The rocket was human-rated, with three stages, and powered with liquid fuel. It was flown from 1 ...
's second and third stages, Saturn IB, and
Saturn I The Saturn I was a rocket designed as the United States' first medium lift launch vehicle for up to low Earth orbit payloads.Terminology has changed since the 1960s; back then, 20,000 pounds was considered "heavy lift". The rocket's first s ...
as well as Centaur rocket stage, the first stage and second stage of the H-II, H-IIA, H-IIB, and the upper stage of the GSLV Mk-II and GSLV Mk-III. The main advantages of this mixture are a clean burn (water vapor is the only combustion product) and high performance. * Liquid oxygen (LOX) and liquid methane (CH4,
liquefied natural gas Liquefied natural gas (LNG) is natural gas (predominantly methane, CH4, with some mixture of ethane, C2H6) that has been cooled down to liquid form for ease and safety of non-pressurized storage or transport. It takes up about 1/600th the v ...
, LNG) – the in-development Raptor (SpaceX) and
BE-4 The Blue Engine 4 or BE-4 is an oxygen-rich liquefied-methane-fueled staged-combustion rocket engine under development by Blue Origin. The BE-4 is being developed with private and public funding. The engine has been designed to produce of thr ...
(Blue Origin) engines. (See also Propulsion Cryogenics & Advanced Development project of NASA, and Project Morpheus.) One of the most efficient mixtures,
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as we ...
and
hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic ...
, suffers from the extremely low temperatures required for storing liquid hydrogen (around ) and very low fuel density (, compared to RP-1 at ), necessitating large tanks that must also be lightweight and insulating. Lightweight foam insulation on the Space Shuttle external tank led to the 's destruction, as a piece broke loose, damaged its wing and caused it to break up on atmospheric reentry. Liquid methane/LNG has several advantages over LH. Its performance (max. specific impulse) is lower than that of LH but higher than that of RP1 (kerosene) and solid propellants, and its higher density, similarly to other hydrocarbon fuels, provides higher thrust to volume ratios than LH, although its density is not as high as that of RP1. This makes it specially attractive for
reusable launch system A reusable launch vehicle have parts that can be recovered and reflown, while carrying payloads from the surface to outer space. Rocket stages are the most common launch vehicle parts aimed for reuse. Smaller parts such as rocket engines and ...
s because higher density allows for smaller motors, propellant tanks and associated systems. LNG also burns with less or no soot (less or no coking) than RP1, which eases reusability when compared with it, and LNG and RP1 burn cooler than LH so LNG and RP1 do not deform the interior structures of the engine as much. This means that engines that burn LNG can be reused more than those that burn RP1 or LH. Unlike engines that burn LH, both RP1 and LNG engines can be designed with a shared shaft with a single turbine and two turbopumps, one each for LOX and LNG/RP1. In space, LNG does not need heaters to keep it liquid, unlike RP1. LNG is less expensive, being readily available in large quantities. It can be stored for more prolonged periods of time, and is less explosive than LH.


Semi-cryogenic

* Liquid oxygen (LOX) and RP-1 (kerosene) –
Saturn V Saturn V is a retired American super heavy-lift launch vehicle developed by NASA under the Apollo program for human exploration of the Moon. The rocket was human-rated, with three stages, and powered with liquid fuel. It was flown from 1 ...
's first stage, Zenit rocket, R-7-derived vehicles including Soyuz, Delta,
Saturn I The Saturn I was a rocket designed as the United States' first medium lift launch vehicle for up to low Earth orbit payloads.Terminology has changed since the 1960s; back then, 20,000 pounds was considered "heavy lift". The rocket's first s ...
, and Saturn IB first stages, Titan I and Atlas rockets, Falcon 1 and Falcon 9 * Liquid oxygen (LOX) and alcohol (
ethanol Ethanol (abbr. EtOH; also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound. It is an alcohol with the chemical formula . Its formula can be also written as or (an ethyl group linked to a