Limiting Oxygen Index
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The limiting oxygen index (LOI) is the minimum concentration of
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as wel ...
, expressed as a percentage, that will support
combustion Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combusti ...
of a
polymer A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic a ...
. It is measured by passing a mixture of oxygen and
nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...
over a burning specimen, and reducing the oxygen level until a critical level is reached. LOI values for different plastics are determined by standardized tests, such as the ISO 4589 and ASTM D2863. The LOI value is also dependent on the surrounding temperature of the sample. The percent of oxygen required for combustion reduces as the surrounding temperature is increased. Plastics and cable material is tested for its LOI value at both ambient temperature and elevated temperature to understand its oxygen requirement under actual fire conditions. Materials with an LOI greater than the atmospheric oxygen concentration are called fire retardant materials.


See also

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Fire-resistance rating A fire-resistance rating typically means the duration for which a passive fire protection system can withstand a standard fire resistance test. This can be quantified simply as a measure of time, or it may entail other criteria, involving eviden ...


References

Passive fire protection {{chemistry-stub