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Lechatelierite is
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
glass,
amorphous In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid, glassy solid) is a solid that lacks the long-range order that is characteristic of a crystal. Etymology The term comes from the Greek ''a'' ("wi ...
SiO2, non-crystalline
mineraloid A mineraloid is a naturally occurring mineral-like substance that does not demonstrate crystallinity. Mineraloids possess chemical compositions that vary beyond the generally accepted ranges for specific minerals. For example, obsidian is an amor ...
.


Structure

Lechatelierite is a
mineraloid A mineraloid is a naturally occurring mineral-like substance that does not demonstrate crystallinity. Mineraloids possess chemical compositions that vary beyond the generally accepted ranges for specific minerals. For example, obsidian is an amor ...
as it does not have a
crystal structure In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystal, crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric pat ...
. Although not a true mineral, it is often classified in the
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
mineral group.


Formation

One common way in which lechatelierite forms naturally is by very high temperature melting of
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
sand during a
lightning Lightning is a naturally occurring electrostatic discharge during which two electric charge, electrically charged regions, both in the atmosphere or with one on the land, ground, temporarily neutralize themselves, causing the instantaneous ...
strike. The result is an irregular, branching, often foamy hollow tube of silica glass called a
fulgurite Fulgurites (), commonly known as "fossilized lightning", are natural tubes, clumps, or masses of sintered, vitrified, and/or fused soil, sand, rock, organic debris and other sediments that sometimes form when lightning discharges into ground. ...
.Lechatelierite on Mindat.org
/ref> Not all fulgurites are lechatelierite; the original sand must be nearly pure silica. Lechatelierite also forms as the result of high pressure
shock metamorphism Shock metamorphism or impact metamorphism describes the effects of shock-wave related deformation and heating during impact events. The formation of similar features during explosive volcanism is generally discounted due to the lack of metamorp ...
during
meteorite A meteorite is a solid piece of debris from an object, such as a comet, asteroid, or meteoroid, that originates in outer space and survives its passage through the atmosphere to reach the surface of a planet or Natural satellite, moon. When the ...
impact crater An impact crater is a circular depression in the surface of a solid astronomical object formed by the hypervelocity impact of a smaller object. In contrast to volcanic craters, which result from explosion or internal collapse, impact craters ...
ing and is a common component of a type of glassy
ejecta Ejecta (from the Latin: "things thrown out", singular ejectum) are particles ejected from an area. In volcanology, in particular, the term refers to particles including pyroclastic materials (tephra) that came out of a volcanic explosion and magma ...
called
tektite Tektites (from grc, τηκτός , meaning 'molten') are gravel-sized bodies composed of black, green, brown or grey natural glass formed from terrestrial debris ejected during meteorite impacts. The term was coined by Austrian geologist Franz ...
s. Most tektites are blobs of impure glassy material, but tektites from the
Sahara Desert , photo = Sahara real color.jpg , photo_caption = The Sahara taken by Apollo 17 astronauts, 1972 , map = , map_image = , location = , country = , country1 = , ...
in
Libya Libya (; ar, ليبيا, Lībiyā), officially the State of Libya ( ar, دولة ليبيا, Dawlat Lībiyā), is a country in the Maghreb region in North Africa. It is bordered by the Mediterranean Sea to the north, Egypt to Egypt–Libya bo ...
and
Egypt Egypt ( ar, مصر , ), officially the Arab Republic of Egypt, is a transcontinental country spanning the northeast corner of Africa and southwest corner of Asia via a land bridge formed by the Sinai Peninsula. It is bordered by the Mediter ...
, known as ''
Libyan desert glass Libyan Desert glass or Great Sand Sea glass is an impactite, made mostly of lechatelierite, found in areas in the eastern Sahara, in the deserts of eastern Libya and western Egypt. Fragments of desert glass can be found over areas of tens of s ...
'', are composed of almost pure silica that is almost pure lechatelierite. High pressure experiments have shown that shock pressures of 85
GPa Grading in education is the process of applying standardized measurements for varying levels of achievements in a course. Grades can be assigned as letters (usually A through F), as a range (for example, 1 to 6), as a percentage, or as a numbe ...
are needed to produce lechatelierite in quartz grains embedded in
granite Granite () is a coarse-grained (phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies undergro ...
. Lechatelierite was formed during the impact of a
meteorite A meteorite is a solid piece of debris from an object, such as a comet, asteroid, or meteoroid, that originates in outer space and survives its passage through the atmosphere to reach the surface of a planet or Natural satellite, moon. When the ...
into a layer of
Coconino Sandstone Coconino Sandstone is a geologic formation named after its exposure in Coconino County, Arizona. This formation spreads across the Colorado Plateau province of the United States, including northern Arizona, northwest Colorado, Nevada, and Utah. ...
at
Meteor Crater Meteor Crater, or Barringer Crater, is a meteorite impact crater about east of Flagstaff and west of Winslow in the desert of northern Arizona, United States. The site had several earlier names, and fragments of the meteorite are official ...
in
Arizona Arizona ( ; nv, Hoozdo Hahoodzo ; ood, Alĭ ṣonak ) is a state in the Southwestern United States. It is the 6th largest and the 14th most populous of the 50 states. Its capital and largest city is Phoenix. Arizona is part of the Fou ...
. During the rapid pressure reduction following the impact, steam expanded the newly formed lechatelierite. The shattered and expanded glass has a density less than that of water. Lechatelierite may also form artificially, a unique example being the ''
trinitite Trinitite, also known as atomsite or Alamogordo glass, is the glassy residue left on the desert floor after the plutonium-based Trinity nuclear bomb test on July 16, 1945, near Alamogordo, New Mexico. The glass is primarily composed of arkosic sa ...
'' produced by melting of quartz sand at the first nuclear bomb explosion at Trinity Flats,
White Sands, New Mexico White Sands is a census-designated place (CDP) in Doña Ana County, New Mexico, United States. It consists of the main residential area on the White Sands Missile Range. As of the 2010 census the population of the CDP was 1,651. It is part of t ...
.Lechatelierite on Webmineral
/ref>


References

Impact event minerals Glass in nature {{mineral-stub