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Artificial leather, also called synthetic leather, is a material intended to substitute for
leather Leather is a strong, flexible and durable material obtained from the tanning, or chemical treatment, of animal skins and hides to prevent decay. The most common leathers come from cattle, sheep, goats, equine animals, buffalo, pigs and hogs, ...
in upholstery, clothing, footwear, and other uses where a leather-like finish is desired but the actual material is cost prohibitive or unsuitable. Artificial leather is known under many names, including ''leatherette'', ''imitation leather'', ''faux leather'', ''
vegan Veganism is the practice of abstaining from the use of animal product—particularly in diet—and an associated philosophy that rejects the commodity status of animals. An individual who follows the diet or philosophy is known as a vegan. Di ...
leather'', ''PU leather'', and ''pleather''.


Manufacture

Many different methods for the manufacture of imitation leathers have been developed. A current method is to use an embossed
release paper A release liner or ''release paper'' is a paper or plastic-based film sheet (usually applied during the manufacturing process) used to prevent a sticky surface from prematurely adhering. It is coated on one or both sides with a release agent, whi ...
known as ''casting paper'' as a form for the surface finish, often mimicking the texture of top-grain leather. This embossed release paper holds the final texture in negative. For the manufacture, the release paper is coated with several layers of
plastic Plastics are a wide range of synthetic or semi-synthetic materials that use polymers as a main ingredient. Their plasticity makes it possible for plastics to be moulded, extruded or pressed into solid objects of various shapes. This adaptab ...
e.g. pvc or
polyurethane Polyurethane (; often abbreviated PUR and PU) refers to a class of polymers composed of organic chemistry, organic units joined by carbamate (urethane) links. In contrast to other common polymers such as polyethylene and polystyrene, polyurethan ...
, possibly including a surface finish, a colour layer, a foam layer, an adhesive, a fabric layer, a reverse finish. Depending on the specific process, these layers may be wet or partially cured at the time of integration. The artificial leather is cured, then the release paper is removed and possibly reused. A fermentation method of making
collagen Collagen () is the main structural protein in the extracellular matrix found in the body's various connective tissues. As the main component of connective tissue, it is the most abundant protein in mammals, making up from 25% to 35% of the whole ...
, the main chemical in real leather, is under development.


Historical methods

One of the earliest artificial leathers was Presstoff. Invented in 19th century Germany, it was made of specially layered and treated paper pulp. It gained its widest use in Germany during the
Second World War World War II or the Second World War, often abbreviated as WWII or WW2, was a world war that lasted from 1939 to 1945. It involved the vast majority of the world's countries—including all of the great powers—forming two opposin ...
in place of leather, which under wartime conditions was rationed. Presstoff could be used in almost every application normally filled by leather, excepting items like footwear that were repeatedly subjected to flex wear or moisture. Under these conditions, Presstoff tends to delaminate and lose cohesion. Another early example was
Rexine Rexine is the registered trademark of an artificial leather leathercloth fabric produced in the United Kingdom by Rexine Ltd of Hyde, near Manchester, England. It was made of cloth surfaced with a mixture of cellulose nitrate (a low explosive also u ...
, a leathercloth fabric produced in the United Kingdom by Rexine Ltd of Hyde, near Manchester. It was made of cloth surfaced with a mixture of
nitrocellulose Nitrocellulose (also known as cellulose nitrate, flash paper, flash cotton, guncotton, pyroxylin and flash string, depending on form) is a highly flammable compound formed by nitrating cellulose through exposure to a mixture of nitric acid and ...
,
camphor Camphor () is a waxy, colorless solid with a strong aroma. It is classified as a terpenoid and a cyclic ketone. It is found in the wood of the camphor laurel ('' Cinnamomum camphora''), a large evergreen tree found in East Asia; and in the k ...
oil, alcohol, and pigment, embossed to look like leather. It was used as a
bookbinding Bookbinding is the process of physically assembling a book of codex format from an ordered stack of ''signatures'', sheets of paper folded together into sections that are bound, along one edge, with a thick needle and strong thread. Cheaper, b ...
material and upholstery covering, especially for the interiors of motor vehicles and the interiors of railway carriages produced by British manufacturers beginning in the 1920s, its cost being around a quarter that of leather. Poromerics are made from a plastic coating (usually a
polyurethane Polyurethane (; often abbreviated PUR and PU) refers to a class of polymers composed of organic chemistry, organic units joined by carbamate (urethane) links. In contrast to other common polymers such as polyethylene and polystyrene, polyurethan ...
) on a fibrous base layer (typically a
polyester Polyester is a category of polymers that contain the ester functional group in every repeat unit of their main chain. As a specific material, it most commonly refers to a type called polyethylene terephthalate (PET). Polyesters include natural ...
). The term poromeric was coined by
DuPont DuPont de Nemours, Inc., commonly shortened to DuPont, is an American multinational chemical company first formed in 1802 by French-American chemist and industrialist Éleuthère Irénée du Pont de Nemours. The company played a major role in ...
as a derivative of the terms ''porous'' and ''polymeric''. The first poromeric material was DuPont's Corfam, introduced in 1963 at the Chicago Shoe Show. Corfam was the centerpiece of the DuPont pavilion at the
1964 New York World's Fair The 1964–1965 New York World's Fair was a world's fair that held over 140 pavilions and 110 restaurants, representing 80 nations (hosted by 37), 24 US states, and over 45 corporations with the goal and the final result of building exhibits or ...
in New York City. After spending millions of dollars marketing the product to shoe manufacturers, DuPont withdrew Corfam from the market in 1971 and sold the rights to a company in
Poland Poland, officially the Republic of Poland, is a country in Central Europe. It is divided into 16 administrative provinces called voivodeships, covering an area of . Poland has a population of over 38 million and is the fifth-most populous ...
. Leatherette is also made by covering a fabric base with a plastic. The fabric can be made of natural or synthetic fiber which is then covered with a soft polyvinyl chloride (PVC) layer. Leatherette is used in
bookbinding Bookbinding is the process of physically assembling a book of codex format from an ordered stack of ''signatures'', sheets of paper folded together into sections that are bound, along one edge, with a thick needle and strong thread. Cheaper, b ...
and was common on the casings of 20th century cameras. Cork leather is a natural-fiber alternative made from the bark of
cork oak ''Quercus suber'', commonly called the cork oak, is a medium-sized, evergreen oak tree in the section ''Quercus'' sect. ''Cerris''. It is the primary source of cork for wine bottle stoppers and other uses, such as cork flooring and as the cores ...
trees that has been compressed, similar to Presstoff.


Environmental effect

The production of the PVC used in the production of many artificial leathers requires a
plasticizer A plasticizer ( UK: plasticiser) is a substance that is added to a material to make it softer and more flexible, to increase its plasticity, to decrease its viscosity, and/or to decrease friction during its handling in manufacture. Plasticiz ...
called a
phthalate Phthalates (, ), or phthalate esters, are esters of phthalic acid. They are mainly used as plasticizers, i.e., substances added to plastics to increase their flexibility, transparency, durability, and longevity. They are used primarily to soften ...
to make it flexible and soft. PVC requires petroleum and large amounts of energy thus making it reliant on fossil fuels. During the production process carcinogenic byproducts,
dioxin Dioxin may refer to: * 1,2-Dioxin or 1,4-Dioxin, two unsaturated heterocyclic 6-membered rings where two carbon atoms have been replaced by oxygen atoms, giving the molecular formula C4H4O2 *Dibenzo-1,4-dioxin, the parent compound also known as ...
s, are produced which are toxic to humans and animals. Dioxins remain in the environment long after PVC is manufactured. When PVC ends up in a landfill it does not decompose like genuine leather and can release dangerous chemicals into the water and soil. Polyurethane is currently more popular for use than PVC. The production of some artificial leathers requires plastic, with others only requiring plant-based materials; the inclusion of artificial materials in the production of artificial leathers notably raises sustainability issues. However, some reports state that the manufacture of artificial leather is still more sustainable than that of real leather, with the Environmental Profit & Loss, a sustainability report developed in 2018 by Kering, stating that the impact of vegan-leather production can be up to a third lower than real leather.


Uses

Artificial leathers are often used in clothing fabrics, furniture upholstery, water craft upholstery, and automotive interiors. Depending on the construction, the artificial leather may be porous and breathable, or may be impermeable and waterproof. Porous artificial leather with a non-woven microfibre backing is a popular choice for clothing, and is comfortable to wear. One of its primary advantages, especially in cars, is that it requires little maintenance in comparison to leather, and does not crack or fade easily, though the surface of some artificial leathers may rub and wear off with time.


Brand names

* Alcantara *
Clarino is a brand name for artificial leather manufactured by Kuraray Co., Ltd. of Japan. It is commonly used in gloves, footwear, handbags, and law enforcement duty gear. Versions are made that simulate suede and top-grain leather. Being a man-mad ...
: manufactured by Kuraray Co., Ltd. of Japan. *
Fabrikoid Fabrikoid, patented in October 1915, is a brand of artificial leather manufactured by DuPont. Material Fabrikoid consists of cotton cloth coated with pyroxylin (a less nitrated nitrocellulose, dissolved in castor oil, alcohol, benzene and amyl ac ...
: A
DuPont DuPont de Nemours, Inc., commonly shortened to DuPont, is an American multinational chemical company first formed in 1802 by French-American chemist and industrialist Éleuthère Irénée du Pont de Nemours. The company played a major role in ...
brand, cotton cloth coated with
nitrocellulose Nitrocellulose (also known as cellulose nitrate, flash paper, flash cotton, guncotton, pyroxylin and flash string, depending on form) is a highly flammable compound formed by nitrating cellulose through exposure to a mixture of nitric acid and ...
*
Kirza Kirza (russian: кирза) is a type of artificial leather based on the multi-layer textile fabric, modified by membrane-like substances, produced mainly in the Soviet Union. The surface of kirza imitates pig leather. The material is mainly use ...
: A Russian form developed in the 1930s consisting of cotton fabric, latex, and rosin * MB-Tex: Used in many
Mercedes-Benz Mercedes-Benz (), commonly referred to as Mercedes and sometimes as Benz, is a German luxury and commercial vehicle automotive brand established in 1926. Mercedes-Benz AG (a Mercedes-Benz Group subsidiary established in 2019) is headquartere ...
base trims * MuSkin: Made from a shelf fungus (''
Phellinus ellipsoideus ''Phellinus ellipsoideus'' (formerly ''Fomitiporia ellipsoidea'') is a species of polypore fungus in the family Hymenochaetaceae, a specimen of which produced the largest fungal fruit body ever recorded. Found in China, the fruit bodies produc ...
'') that is treated to become water resistant *
Naugahyde Naugahyde is an American brand of artificial leather. Naugahyde is a composite knit fabric backing and expanded polyvinyl chloride (PVC) coating. It was developed by Byron A. Hunter, senior chemist at the United States Rubber Company, and is no ...
: An American brand introduced by
Uniroyal The company formerly known as the United States Rubber Company, now Uniroyal, is an American manufacturer of tires and other synthetic rubber-related products, as well as variety of items for military use, such as ammunition, explosives, chemical ...
*
Piñatex Piñatex () is a non-biodegradable leather alternative made from cellulose fibres extracted from pineapple leaves, PLA (polylactic acid), and petroleum-based resin. Piñatex was developed by Dr Carmen Hijosa and first presented at the PhD grad ...
: Made from
pineapple The pineapple (''Ananas comosus'') is a tropical plant with an edible fruit; it is the most economically significant plant in the family Bromeliaceae. The pineapple is indigenous to South America, where it has been cultivated for many centuri ...
leaves *
Rexine Rexine is the registered trademark of an artificial leather leathercloth fabric produced in the United Kingdom by Rexine Ltd of Hyde, near Manchester, England. It was made of cloth surfaced with a mixture of cellulose nitrate (a low explosive also u ...
: A British brand * Skai: Made by the German company Konrad Hornschuch AG, its name has become a genericized trademark in Germany and surrounding countries


See also

*
Bicast leather Bicast leather (also spelled as bi-cast leather or bycast leather) is a material made with a split leather backing covered with an embossed layer of polyurethane or vinyl. Bicast leather was originally made for the apparel industry for glossy sh ...
– a form of genuine leather coated with a plastic finish *
Bonded leather Bonded leather, also called reconstituted leather, composition leather or blended leather, is a term used for a manufactured upholstery material which contains animal hide. It is made as a layered structure of a fiber or paper backer covered with ...
– a material made by blending scrap leather fibers with a plastic binder *
Microfiber Microfiber (or microfibre) is synthetic fiber finer than one denier or decitex/thread, having a diameter of less than ten micrometers. A strand of silk is about one denier and about a fifth of the diameter of a human hair. The most common ty ...
– a material made with synthetic fibers thinner than natural silk; can be used for making synthetic suedes, like
Ultrasuede Ultrasuede is the trade name for a synthetic ultra-microfiber fabric invented in 1970 by Dr. Miyoshi Okamoto, a scientist working for Toray Industries. In Japan, it is sold under the brand name Ecsaine. It is often described as an artificial s ...
* Mycelium-based materials -
Mycelium Mycelium (plural mycelia) is a root-like structure of a fungus consisting of a mass of branching, thread-like hyphae. Fungal colonies composed of mycelium are found in and on soil and many other substrate (biology), substrates. A typical single ...
, the fungal equivalent of roots in plants, has been identified as an ecologically friendly substitute to a litany of materials throughout different industries.


References


Further reading

* ''Faux Real: Genuine Leather and 200 Years of Inspired Fakes'', by Robert Kanigel. Joseph Henry Press, 2007.


External links

* {{Authority control Sustainability Nonwoven fabrics Synthetic materials Leather Textiles Fashion design