Lars Fredrik Nilson (27 May 1840 – 14 May 1899) was a
Swedish
Swedish or ' may refer to:
Anything from or related to Sweden, a country in Northern Europe. Or, specifically:
* Swedish language, a North Germanic language spoken primarily in Sweden and Finland
** Swedish alphabet, the official alphabet used by ...
chemist
A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a scientist trained in the study of chemistry. Chemists study the composition of matter and its properties. Chemists carefully describe t ...
, professor at
Uppsala University
Uppsala University ( sv, Uppsala universitet) is a public research university in Uppsala, Sweden. Founded in 1477, it is the oldest university in Sweden and the Nordic countries still in operation.
The university rose to significance during ...
, and later Director of the Agricultural Chemical Experiment Station at the
Royal Swedish Academy of Agriculture and Forestry
The Royal Swedish Academy of Agriculture and Forestry ( sv, Kungliga Skogs- och Lantbruksakademien), formerly the Royal Swedish Academy of Agriculture (''Kungl. Lantbruksakademien''), founded in 1813 at the initiative of Crown Prince Charles, is on ...
in
Stockholm.
He discovered the element
scandium
Scandium is a chemical element with the symbol Sc and atomic number 21. It is a silvery-white metallic d-block element. Historically, it has been classified as a rare-earth element, together with yttrium and the Lanthanides. It was discovered in ...
in 1879, by separating out
scandium(III) oxide
Scandium(III) oxide or scandia is a inorganic compound with formula Sc2 O3. It is one of several oxides of rare earth elements with a high melting point. It is used in the preparation of other scandium compounds as well as in high-temperature sys ...
, also known as scandia.
In addition to his work on the
analytic chemistry
Analytical chemistry studies and uses instruments and methods to separate, identify, and quantify matter. In practice, separation, identification or quantification may constitute the entire analysis or be combined with another method. Separati ...
of elements and
rare earths
The rare-earth elements (REE), also called the rare-earth metals or (in context) rare-earth oxides or sometimes the lanthanides (yttrium and scandium are usually included as rare earths), are a set of 17 nearly-indistinguishable lustrous silve ...
, he made substantial contributions to Swedish agriculture, including methods of fertilization and the introduction of
sugar beets as a crop.
Education
Nilson was born in
Skönberga parish in
Östergötland,
Sweden. Later his family moved to the island of
Gotland, where his father, Nikolaus, owned Rosendal farm in
Follingbo. In later life, Lars Fredrik Nilson retained a small holding on Gotland, which he visited yearly.
After graduating from
Wisby high school on
Gotland, Lars Fredrik Nilson enrolled at
Uppsala University
Uppsala University ( sv, Uppsala universitet) is a public research university in Uppsala, Sweden. Founded in 1477, it is the oldest university in Sweden and the Nordic countries still in operation.
The university rose to significance during ...
in 1859. There he studied the
natural sciences
Natural science is one of the branches of science concerned with the description, understanding and prediction of natural phenomena, based on empirical evidence from observation and experimentation. Mechanisms such as peer review and repeatab ...
including zoology and biology.
His work in
mineralogy drew the attention of the chemistry professor at Uppsala,
Lars Fredrik Svanberg, a former student of
Jöns Jakob Berzelius
Jöns is a Swedish given name and a surname.
Notable people with the given name include:
* Jöns Jacob Berzelius (1779–1848), Swedish chemist
* Jöns Budde (1435–1495), Franciscan friar from the Brigittine monastery in NaantaliVallis Grati ...
.
To obtain a Doctorate of Philosophy in Sweden, the candidate was expected to pass a series of examinations in all areas of study, including languages, history, and philosophy as well as their main area of study, within a fixed period of time. In 1865, just before Nilson could complete his final examination, his father became severely ill. Nilson returned home to Gotland, where he took over management of the farm, working in the fields as needed. When his father recovered some months later, the harvest and fall planting had been successfully completed, and Nilson had installed the first engine threshing machine to be used in Gotland. Nilson's own health had greatly benefited from his work on the farm: the young man who had arrived home in poor health had become much stronger. He was able to return to Uppsala and pass the next season's examinations,
becoming a doctor of chemistry in 1866.
Career
In 1866, Nilson became an associate professor of chemistry at Uppsala,
with the responsibilities of chief assistant and demonstrator of chemistry at Svanberg's laboratory. He was a calm and patient teacher, relying more on demonstrations than on lectures. He insisted that after the work of the day was completed, it was to be left behind, and not discussed during leisure. His earliest papers focused on
sulfides,
arsenical sulfosalt minerals
Sulfosalt minerals are sulfide minerals with the general formula , where
*A represents a metal such as copper, lead, silver, iron, and rarely mercury, zinc, vanadium
*B usually represents semi-metal such as arsenic, antimony, bismuth, and rarely ...
, and
selenous acid
Selenous acid (or selenious acid) is the chemical compound with the formula . Structurally, it is more accurately described by . It is the principal oxoacid of selenium; the other being selenic acid.
Formation and properties
Selenous acid is a ...
, extending the work of Berzelius.
Elements
In 1874 Nilson became professor of general and agricultural chemistry at Uppsala.
From then on he could devote more time to research. He began working on
rare earths
The rare-earth elements (REE), also called the rare-earth metals or (in context) rare-earth oxides or sometimes the lanthanides (yttrium and scandium are usually included as rare earths), are a set of 17 nearly-indistinguishable lustrous silve ...
such as
euxenite
Euxenite, or euxenite-(Y) (the official mineralogical name), is a brownish black mineral with a metallic luster.
Chemistry
It contains calcium, niobium, tantalum, cerium, titanium, yttrium, and typically uranium and thorium, with some other meta ...
and
gadolinite, using methods of successive fractionation introduced by
Nils Johan Berlin
Nils Johan Berlin (Nils Johannes Berlin) (18 February 1812 – 27 December 1891) was a Swedish chemist and physician, who held various professorships at the University of Lund from 1843 to 1864. Berlin was the first chemist who took the initiativ ...
. One of his goals was to better understand the relationship of the newly discovered
elements to the proposed
periodic system
The periodic table, also known as the periodic table of the (chemical) elements, is a rows and columns arrangement of the chemical elements. It is widely used in chemistry, physics, and other sciences, and is generally seen as an icon of ...
.
In 1879 Nilson separated out the oxide
scandia
Scandza was described as a "great island" by Gothic-Byzantine historian Jordanes in his work ''Getica''. The island was located in the Arctic regions of the sea that surrounded the world. The location is usually identified with Scandinavia.
Jor ...
. By doing so he discovered a new element,
scandium
Scandium is a chemical element with the symbol Sc and atomic number 21. It is a silvery-white metallic d-block element. Historically, it has been classified as a rare-earth element, together with yttrium and the Lanthanides. It was discovered in ...
, which he named for Scandinavia. The discovery was of particular importance because the existence of an element with such properties, "ekaboron", had been predicted by Mendeleev, based on his organization of the
periodic system
The periodic table, also known as the periodic table of the (chemical) elements, is a rows and columns arrangement of the chemical elements. It is widely used in chemistry, physics, and other sciences, and is generally seen as an icon of ...
.
Nilson's spectral analysis indicated a previously unreported pattern of lines.
Per Theodor Cleve demonstrated the equivalence of Nilson's scandium and Mendeleev's hypothetical ekaboron.
Nilson and
Sven Otto Pettersson were the first to isolate
titanium
Titanium is a chemical element with the Symbol (chemistry), symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resista ...
metal in a relatively pure form, extracting a 95% pure sample in 1887.
Jöns Jacob Berzelius had extracted titanium metal in 1825, but only in a very impure form.
In 1910
Matthew Hunter was finally able to produce 99.9% pure titanium metal, through his new
Hunter process
The Hunter process was the first industrial process to produce pure ductile metallic titanium. It was invented in 1910 by Matthew A. Hunter, a chemist born in New Zealand who worked in the United States. The process involves reducing titanium tet ...
.
Nilson also studied the gas density of metals which made it possible to determine the
valence of various metals.
Agriculture
Nilson held the chair of analytical chemistry at Uppsala from 1878 until 1883, when he became professor of chemistry of the Royal Swedish Academy of Agriculture and Forestry
The Royal Swedish Academy of Agriculture and Forestry ( sv, Kungliga Skogs- och Lantbruksakademien), formerly the Royal Swedish Academy of Agriculture (''Kungl. Lantbruksakademien''), founded in 1813 at the initiative of Crown Prince Charles, is on ...
in Stockholm. As an agricultural chemist and Director of the Agricultural Chemical Experiment Station, he published nearly sixty papers on topics such as soils and manures. As a result of his inquiries many of the swamps of Gothland were drained and put under cultivation. The sugar beet was introduced and became a major crop, as chalky moors were treated with potash
Potash () includes various mined and manufactured salts that contain potassium in water-soluble form. fertilizers.
He also conducted studies on cow's milk and various plants for cattle fodder.
Nilson was elected a foreign member of the Chemical Society of Great Britain on February 2, 1888.
Nilson was a member of several other academies as well. He received several awards, including the Order of the Polar Star
The Royal Order of the Polar Star ( Swedish: ''Kungliga Nordstjärneorden'') is a Swedish order of chivalry created by King Frederick I on 23 February 1748, together with the Order of the Sword and the Order of the Seraphim.
The Order of t ...
.
References
Further reading
*
English excerpt
*
{{DEFAULTSORT:Nilson, Nils Fredrik
Swedish chemists
Uppsala University alumni
1840 births
1899 deaths
Discoverers of chemical elements
19th-century Swedish scientists
19th-century chemists
Scandium
Order of the Polar Star
Rare earth scientists
Members of the Royal Society of Sciences in Uppsala