Lambertianin C is an
ellagitannin
The ellagitannins are a diverse class of hydrolyzable tannins, a type of polyphenol formed primarily from the oxidative linkage of galloyl groups in 1,2,3,4,6-pentagalloyl glucose. Ellagitannins differ from gallotannins, in that their galloyl ...
.
Natural occurrence
Lambertianin C can be found in ''
Rubus
''Rubus'' is a large and diverse genus of flowering plants in the rose family, Rosaceae, subfamily Rosoideae, with over 1,350 species.
Raspberries, blackberries, and dewberries are common, widely distributed members of the genus. Most of the ...
'' species such as ''
Rubus lambertianus'',
in cloudberries (''
Rubus chamaemorus
''Rubus chamaemorus'' is a species of flowering plant in the rose family Rosaceae, native to cool temperate regions, alpine and arctic tundra and boreal forest. This herbaceous perennial produces amber-colored edible fruit similar to the blackbe ...
'')
and in red raspberries (''
Rubus idaeus
''Rubus idaeus'' (raspberry, also called red raspberry or occasionally European red raspberry to distinguish it from other raspberry species) is a red-fruited species of ''Rubus'' native to Europe and northern Asia and commonly cultivated in othe ...
'').
Chemistry
Lambertianin C is
trimer of
casuarictin
Casuarictin is an ellagitannin, a type of hydrolysable tannin. It can be found in ''Casuarina'' and ''Stachyurus'' species.Tannins of Casuarina and Stachyurus species. I: Structures of pendunculagin, casuarictin, strictinin, casuarinin, casuariin, ...
linked by
sanguisorbic acid
Sanguisorbic acid is a constituent of some ellagitannins. It is constituted by a hexahydroxydiphenic acid unit linked by an O-C bond to a gallic acid. The differences with its isomers, valoneic acid and nonahydroxytriphenic acid, are that the hydr ...
ester groups between glucopyranose moieties.
[ It contributes to the antioxidant capacity of raspberries.]
References
External links
Lambertianin C at www.phenol-explorer.eu
{{Ellagitannin
Ellagitannins
Natural phenol trimers
Rubus