Labradorite (( Ca, Na)( Al, Si)4O8) is a calcium-enriched
feldspar
Feldspar ( ; sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagiocl ...
mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...
first identified in
Labrador
Labrador () is a geographic and cultural region within the Canadian province of Newfoundland and Labrador. It is the primarily continental portion of the province and constitutes 71% of the province's area but is home to only 6% of its populatio ...
, Canada, which can display an
iridescent
Iridescence (also known as goniochromism) is the phenomenon of certain surfaces that appear gradually to change colour as the angle of view or the angle of illumination changes. Iridescence is caused by wave interference of light in microstruc ...
effect ( schiller).
Labradorite is an intermediate to calcic member of the
plagioclase
Plagioclase ( ) is a series of Silicate minerals#Tectosilicates, tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continu ...
series. It has an
anorthite
Anorthite (< ''an'' 'not' + ''ortho'' 'straight') is the
specific gravity
Relative density, also called specific gravity, is a dimensionless quantity defined as the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for solids and liquids is nea ...
ranges from 2.68 to 2.72. The streak is white, like most
silicates
A silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name is also used for an ...
. The
refractive index
In optics, the refractive index (or refraction index) of an optical medium is the ratio of the apparent speed of light in the air or vacuum to the speed in the medium. The refractive index determines how much the path of light is bent, or refrac ...
ranges from 1.559 to 1.573 and twinning is common. As with all plagioclase members, the crystal system is
triclinic
class=skin-invert-image, 180px, Triclinic (a ≠ b ≠ c ≠ a and α, β, γ, 90° pairwise different)
In crystallography, the triclinic (or anorthic) crystal system is one of the seven crystal systems. A crystal system is described by three b ...
, and three directions of
cleavage
Cleavage may refer to:
Science
* Cleavage (crystal), the way in which a crystal or mineral tends to split
* Cleavage (embryo), the division of cells in an early embryo
* Cleavage (geology), foliation of rock perpendicular to stress, a result of ...
are present, two of which are nearly at right angles and are more obvious, being of good to perfect quality (while the third direction is poor). It occurs as clear, white to gray, blocky to
lath
A lath or slat is a thin, narrow strip of straight-grained wood used under roof shingles or tiles, on lath and plaster walls and ceilings to hold plaster, and in lattice and trellis work.
''Lath'' has expanded to mean any type of backing m ...
shaped grains in common
mafic
A mafic mineral or rock is a silicate mineral or igneous rock rich in magnesium and iron. Most mafic minerals are dark in color, and common rock-forming mafic minerals include olivine, pyroxene, amphibole, and biotite. Common mafic rocks include ...
igneous rocks
Igneous rock ( ), or magmatic rock, is one of the three main Rock (geology)#Classification, rock types, the others being sedimentary rock, sedimentary and metamorphic rock, metamorphic. Igneous rocks are formed through the cooling and solidifi ...
such as
basalt
Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
and
gabbro
Gabbro ( ) is a phaneritic (coarse-grained and magnesium- and iron-rich), mafic intrusive igneous rock formed from the slow cooling magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is ch ...
, as well as in
anorthosite
Anorthosite () is a phaneritic, intrusive rock, intrusive igneous rock characterized by its composition: mostly plagioclase feldspar (90–100%), with a minimal mafic component (0–10%). Pyroxene, ilmenite, magnetite, and olivine are the mafic ...
s.
Occurrence
The geological type area for labradorite is Paul's Island near the town of Nain in Labrador, Canada. It has also been reported in Poland, Norway, Finland and various other locations worldwide, with notable distribution in Madagascar, China, Australia, Slovakia and the United States.
Labradorite occurs in
mafic
A mafic mineral or rock is a silicate mineral or igneous rock rich in magnesium and iron. Most mafic minerals are dark in color, and common rock-forming mafic minerals include olivine, pyroxene, amphibole, and biotite. Common mafic rocks include ...
igneous rocks and is the feldspar variety most common in
basalt
Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
and
gabbro
Gabbro ( ) is a phaneritic (coarse-grained and magnesium- and iron-rich), mafic intrusive igneous rock formed from the slow cooling magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is ch ...
. The uncommon
anorthosite
Anorthosite () is a phaneritic, intrusive rock, intrusive igneous rock characterized by its composition: mostly plagioclase feldspar (90–100%), with a minimal mafic component (0–10%). Pyroxene, ilmenite, magnetite, and olivine are the mafic ...
bodies are composed almost entirely of labradorite.Hurlbut, Cornelius S.; Klein, Cornelis; ''Manual of Mineralogy'', Wiley, 1985, 20th ed., p. 456, It also is found in metamorphic
amphibolite
Amphibolite () is a metamorphic rock that contains amphibole, especially hornblende and actinolite, as well as plagioclase feldspar, but with little or no quartz. It is typically dark-colored and dense, with a weakly foliated or schistose ...
s and as a detrital component of some sediments. Common mineral associates in igneous rocks include
olivine
The mineral olivine () is a magnesium iron Silicate minerals, silicate with the chemical formula . It is a type of Nesosilicates, nesosilicate or orthosilicate. The primary component of the Earth's upper mantle (Earth), upper mantle, it is a com ...
,
pyroxene
The pyroxenes (commonly abbreviated Px) are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents ions of calcium (Ca), sodium (Na), iron ( ...
s,
amphibole
Amphibole ( ) is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is ...
s and
magnetite
Magnetite is a mineral and one of the main iron ores, with the chemical formula . It is one of the iron oxide, oxides of iron, and is ferrimagnetism, ferrimagnetic; it is attracted to a magnet and can be magnetization, magnetized to become a ...
.
Labradorescence
Labradorite can display an
iridescent
Iridescence (also known as goniochromism) is the phenomenon of certain surfaces that appear gradually to change colour as the angle of view or the angle of illumination changes. Iridescence is caused by wave interference of light in microstruc ...
optical effect (or '' schiller'') known as labradorescence. The term ''labradorescence'' was coined by Ove Balthasar Bøggild, who defined it (labradorization) as follows:
Contributions to the understanding of the origin and cause of the effect were made by
Robert Strutt, 4th Baron Rayleigh
Robert John Strutt, 4th Baron Rayleigh (28 August 1875 – 13 December 1947) was a British peer and physicist. He discovered "active nitrogen" and was the first to distinguish the glow of the night sky.
Early life and education
Strutt was b ...
(1923), and by Bøggild (1924).
The cause of this optical phenomenon is phase
exsolution
A solid solution, a term popularly used for metals, is a homogeneous mixture of two compounds in solid state and having a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The word "solution" ...
lamellar structure, occurring in the Bøggild
miscibility gap
A miscibility gap is a region in a phase diagram for a mixture
In chemistry, a mixture is a material made up of two or more different chemical substances which can be separated by physical method. It is an impure substance made up of 2 or more ...
. The effect is visible when the lamellar separation is between ; the lamellae are not necessarily parallel; and the lamellar structure is found to lack long range order.
The lamellar separation only occurs in plagioclases of a certain composition; those of calcic labradorite (50–70% anorthite) and bytownite (formula: , ''i.e.'', with an
anorthite
Anorthite (< ''an'' 'not' + ''ortho'' 'straight') is the
gemstone
A gemstone (also called a fine gem, jewel, precious stone, semiprecious stone, or simply gem) is a piece of mineral crystal which, when cut or polished, is used to make jewellery, jewelry or other adornments. Certain Rock (geology), rocks (such ...
varieties of labradorite exhibiting a high degree of labradorescence are called spectrolite.
Gallery
File:Labradoryt, Madagaskar.JPG, Polished block from Madagascar
File:Labradorite detail.jpg, Detail of labradorite
File:LabradoriteAMD.jpg, Polished labradorite 18 × 20 cm
File:Labradorite (UCL Geology Collections).jpg, Polished labradorite from UCL Geology collections
File:Labradorite with rare colours.JPG, Labradorite with rare colors
File:Ladrador iridescence.jpg, Polished labradorite
Lapis lazuli
Lapis lazuli (; ), or lapis for short, is a deep-blue metamorphic rock used as a semi-precious stone that has been prized since antiquity for its intense color. Originating from the Persian word for the gem, ''lāžward'', lapis lazuli is ...
Opal
Opal is a hydrated amorphous form of silicon dioxide, silica (SiO2·''n''H2O); its water content may range from 3% to 21% by weight, but is usually between 6% and 10%. Due to the amorphous (chemical) physical structure, it is classified as a ...