Knudsen layer
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The Knudsen layer, also known as
evaporation Evaporation is a type of vaporization that occurs on the surface of a liquid as it changes into the gas phase. High concentration of the evaporating substance in the surrounding gas significantly slows down evaporation, such as when humidi ...
layer, is the thin layer of vapor near a liquid or solid. It is named after
Danish Danish may refer to: * Something of, from, or related to the country of Denmark People * A national or citizen of Denmark, also called a "Dane," see Demographics of Denmark * Culture of Denmark * Danish people or Danes, people with a Danish a ...
physicist
Martin Knudsen Martin Hans Christian Knudsen (February 15, 1871 in Hasmark on Funen – May 27, 1949 in Copenhagen) was a Danish physicist who taught and conducted research at the Technical University of Denmark. He is primarily known for his study of molec ...
(1871–1949).


Definition

At the interface of a vapor and a liquid/solid, the gas interaction with the liquid/solid dominates the gas behavior, and the gas is, very locally, not in equilibrium. This region, several
mean free path In physics, mean free path is the average distance over which a moving particle (such as an atom, a molecule, or a photon) travels before substantially changing its direction or energy (or, in a specific context, other properties), typically as a ...
lengths thick, is called the Knudsen layer.


Knudsen layer thickness

The Knudsen layer thickness can be approximated by l_c, given by l_c =\frac, where k is
Boltzmann's constant The Boltzmann constant ( or ) is the proportionality factor that relates the average relative kinetic energy of particles in a gas with the thermodynamic temperature of the gas. It occurs in the definitions of the kelvin and the gas constant, ...
, T_s is the temperature, d is the molecular diameter and p_s is the pressure.


Applications

One of the applications of Knudsen layer is in the coma of comets. It has been used specially in the coma chemistry model (ComChem model).


References

Fluid dynamics {{fluiddynamics-stub