Kaldo Process
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A Kaldo converter (using the ''Kaldo process'' or ''Stora-Kaldo process'') is a rotary vessel oxygen based metal refining method. Originally applied to the refining of iron into steel, with most installations in the 1960s, the process is (2014) used primarily to refine non ferrous metals, typically copper. In that field, it is often named TBRC, or Top Blown Rotary Converter.


History and description


Steel production

file:Affinage convertisseur Kaldo.svg, lang=en, upright=1.8, Evolution of chemical composition and temperature of the liquid steel, during the blowing in a Kaldo converter. The iron content is linked with the slag composition, the others elements are taken in the metal. The name "Kaldo" is derived from Prof. Bo Kalling, and from the Domnarvets Jernverk (''Stora Kopparbergs Bergslag'' subsidiary) both key in the development of the process. Research into the use of a stirring to promote mixing, and therefore rate of conversion was investigated from the 1940s, and investigations into the use of oxygen began c.1948. The feedstock at the Domnarvet works had a phosphorus content of 1.8-2.0% and so the process was developed with one aim being dephosphorisation. The first production unit was installed in 1954 at Domnarvet Jernverk. The converter was a top blow oxygen converter, similar to Linz-Donawitz type, using a cylindrical vessel; the vessel was tilted whilst conversion took place, with typical rotation speeds of around 30 revolutions per minute; the oxygen was injected via a lance, with slag forming materials added separately. Kaldo converters were relatively common in the 1960s in the
United Kingdom The United Kingdom of Great Britain and Northern Ireland, commonly known as the United Kingdom (UK) or Britain, is a country in Europe, off the north-western coast of the continental mainland. It comprises England, Scotland, Wales and North ...
, during the transition from predominately open hearth process steelmaking to oxygen based steelmaking techniques. Converters were installed at Consett steelworks, Park Gate, Rotherham, Shelton works, Stoke-on-Trent; and Stanton Iron Works. Before the advent of the basic-LD process the Kaldo method was a preferred one in the UK for converting high phosphorus iron. The first unit in the UK was at Park Gate Works, Rotherham. In the USA the process was installed at the
Sharon Steel Corporation Sharon ( he, שָׁרוֹן ''Šārôn'' "plain") is a given name as well as an Israeli surname. In English-speaking areas, Sharon is now predominantly a feminine given name. However, historically it was also used as a masculine given name. In I ...
(c.1962). A plant in Japan was installed for ''Sanyo Special Steel Co.'' (Himejii) in c.1965. A combined type of converter (''LD-Kaldo''), using elements of the Linz-Donawitz and Kaldo processes was installed 1965 in Belgium at Cockerill-Ougrée-Providence's plant in Marchienne-au-Pont as a multicompany research venture. In France, one Kaldo furnace was also installed (one 160t unit, 1960) at
Sollac Sollac (Société Lorraine de Laminage Continu) was a French steel company formed in December 1948 as a cooperative to produce steel rolls in Lorraine from steel provided by several other companies. There were various changes of ownership during t ...
's . It was followed in 1969 by two huge 240t units, the biggest Kaldo converters never built (two times bigger than the previous bigger ones : 1000t rotating at 30 r.p.m. !), at Wendel-Sidelor's (later
Usinor-Sacilor Usinor was a French steel making group formed in 1948. The group was merged with Sacilor in 1986, becoming Usinor-Sacilor and was privatised in 1995, and renamed Usinor in 1997. In 2001 it merged with Arbed (Luxembourg) and Aceralia (Spain) to for ...
) (Lorraine, France); these two converters did not meet expectations and the third additional planned Kaldo unit was not installed, instead two OLP (''oxygène-lance-poudre'') 240t units were used. Disadvantages of the process, compared to non-rotating oxygen furnaces (e.g. LD type) were the higher capital cost, more difficult to upscale to higher outputs, and additional complexity (i.e. rotating parts and loading thereof). Advantages included the ability to use a high proportion of scrap metal, and good controllability of final steel specification. At the Park Gate works conversion time was 90 minutes, with up to 45% scrap loading, with a capacity of 75t in a 500t total, diameter converter, with a rotation speed of 40 revs per minute. Due to high maintenance costs the Kaldo converter did not gain widespread usage in the steel industry, with non-rotating converters being preferred.


Non-ferrous production

Nickel matte was converted by
Inco Vale Canada Limited (formerly Vale Inco, CVRD Inco and Inco Limited; for corporate branding purposes simply known as "Vale" and pronounced in English) is a wholly owned subsidiary of the Brazilian mining company Vale. Vale's nickel mining and ...
(Canada) in a pilot Kaldo converter in 1959, and
Metallo-Chimique Metallo-Chimique International N.V., based in Beerse, Belgium, also described simply as Metallo, is a privately held metals and mining company. The company was incorporated in 1919. Metallo now specializes in the recycling and refining of metall ...
(Belgium) developed secondary copper smelting using the Kaldo type converters in the late 1960s. The Kaldo type converted is commonly known as a ''Top-Blown Rotary Converter'' (TBRC) in non-ferrous metal smelting terminology. By the 1970s the Kaldo furnace was in common use for copper and nickel smelting. A Kaldo converter for the smelting of lead was constructed by Boliden in Sweden in 1976. Kaldo secondary copper units were still in use worldwide at the beginning of the 21st century, but as of 2011 no new units had been commissioned for around 10 years, suggesting that the process had been superseded.


See also

*
AJAX furnace The AJAX furnace was a modification of the tilting open hearth furnace that used blown oxygen to improve productivity. The process was used in the UK during the 1960s at a time of transition from open hearth to oxygen based steel making. History a ...


References


Sources

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External links

*{{citation, title = Outotec Kaldo (TBRC) technology, url =http://www.outotec.com/en/Products--services/Process-equipment/For-smelting/Kaldo-furnace/#tabid-1, work = www.outotec.com Steelmaking Copper Smelting Swedish inventions