Kopp's law can refer to either of two relationships discovered by the German chemist
Hermann Franz Moritz Kopp
Hermann Franz Moritz Kopp (30 October 1817 – 20 February 1892), German chemist, was born at Hanau, where his father, Johann Heinrich Kopp (1777–1858), a physician, was professor of chemistry, physics and natural history at the local lyce ...
(1817–1892).
#Kopp found "that the molecular heat capacity of a solid compound is the sum of the atomic heat capacities of the elements composing it; the elements having atomic heat capacities lower than those required by the
Dulong–Petit law
The Dulong–Petit law, a thermodynamic law proposed by French physicists Pierre Louis Dulong and Alexis Thérèse Petit, states that the classical expression for the molar specific heat capacity of certain chemical elements is constant for tempe ...
retain these lower values in their compounds."
#In studying organic compounds, Kopp found a regular relationship between boiling points and the number of CH
2 groups present.
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Kopp–Neumann law
The Kopp–Neumann law, named for Kopp and
Franz Ernst Neumann
Franz Ernst Neumann (11 September 1798 – 23 May 1895) was a German mineralogist, physicist and mathematician.
Biography
Neumann was born in Joachimsthal, Margraviate of Brandenburg, near Berlin. In 1815 he interrupted his studies at Berlin to ...
, is a common approach for determining the
specific heat
In thermodynamics, the specific heat capacity (symbol ) of a substance is the heat capacity of a sample of the substance divided by the mass of the sample, also sometimes referred to as massic heat capacity. Informally, it is the amount of heat t ...
''C'' (in J·kg
−1·K
−1) of compounds using the following equation:
where ''N'' is the total number of compound constituents, and ''C
i'' and ''f
i'' denote the
specific heat
In thermodynamics, the specific heat capacity (symbol ) of a substance is the heat capacity of a sample of the substance divided by the mass of the sample, also sometimes referred to as massic heat capacity. Informally, it is the amount of heat t ...
and
mass fraction of the ''i''-th constituent. This law works surprisingly well at room-temperature conditions, but poorly at elevated temperatures.
See also
*
Rule of mixtures
In materials science, a general rule of mixtures is a weighted mean used to predict various properties of a composite material . It provides a theoretical upper- and lower-bound on properties such as the elastic modulus, mass density, ultimate te ...
References
*
Frederick Seitz, The Modern Theory of Solids, McGraw-Hill, New York, USA, 1940,
ASIN
Asin Thottumkal (born 26 October 1985), known mononymously as Asin, is a former Indian actress who appeared predominantly in Tamil, Hindi and Telugu films. She is a trained Bharatanatyam dancer. She has received three Filmfare Awards. She beg ...
: B000OLCK08
Further reading
*
Laws of thermodynamics
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