kiloelectronvolt

In physics, an electronvolt (symbol eV, also written electron-volt and electron volt) is the measure of an amount of kinetic energy gained by a single electron accelerating from rest through an electric potential difference of one volt in vacuum. When used as a unit of energy, the numerical value of 1 eV in joules (symbol J) is equivalent to the numerical value of the charge of an electron in coulombs (symbol C). Under the 2019 redefinition of the SI base units, this sets 1 eV equal to the exact value

Historically, the electronvolt was devised as a standard unit of measure through its usefulness in electrostatic particle accelerator sciences, because a particle with electric charge ''q'' gains an energy after passing through a voltage of ''V.'' Since ''q'' must be an integer multiple of the elementary charge ''e'' for any isolated particle, the gained energy in units of electronvolts conveniently equals that integer times the voltage.

It is a common unit of energy within physics, widely used in solid state, atomic, nuclear, and particle physics, and high-energy astrophysics. It is commonly used with SI prefixes milli-, kilo-, mega-, giga-, tera-, peta- or exa- (meV, keV, MeV, GeV, TeV, PeV and EeV respectively). In some older documents, and in the name Bevatron, the symbol BeV is used, which stands for billion (10⁹) electronvolts; it is equivalent to the GeV.

Definition

An electronvolt is the amount of kinetic energy gained or lost by a single electron accelerating from rest through an electric potential difference of one volt in vacuum. Hence, it has a value of one volt, , multiplied by the elementary charge Therefore, one electronvolt is equal to

The electronvolt (eV) is a unit of energy, but is not an SI unit. The SI unit of energy is the joule (J).

Relation to other physical properties and units

Mass

By mass–energy equivalence, the electronvolt corresponds to a unit of mass. It is common in particle physics, where units of mass and energy are often interchanged, to express mass in units of eV/''c''², where ''c'' is the speed of light in vacuum (from ). It is common to informally express mass in terms of eV as a unit of mass, effectively using a system of natural units with ''c'' set to 1. The kilogram equivalent of is:

$1\; \text/c^2 = \frac = 1.782\ 661\ 92 \times 10^\; \text.$

For example, an electron and a positron, each with a mass of , can annihilate to yield of energy. A proton has a mass of . In general, the masses of all hadrons are of the order of , which makes the GeV/''c''² a convenient unit of mass for particle physics:

The atomic mass constant (''m''_u), one twelfth of the mass a carbon-12 atom, is close to the mass of a proton. To convert to electronvolt mass-equivalent, use the formula:

Momentum

By dividing a particle's kinetic energy in electronvolts by the fundamental constant ''c'' (the speed of light), one can describe the particle's momentum in units of eV/''c''. In natural units in which the fundamental velocity constant ''c'' is numerically 1, the ''c'' may informally be omitted to express momentum as electronvolts.

The energy momentum relation

$E^2 = p^2 c^2 + m_0^2 c^4$

in natural units (with $c=1$)

$E^2 = p^2 + m_0^2$

is a Pythagorean equation. When a relatively high energy is applied to a particle with relatively low rest mass, it can be approximated as $E \simeq p$ in high-energy physics such that an applied energy in units of eV conveniently results in an approximately equivalent change of momentum in units of eV/''c''.

The dimensions of momentum units are . The dimensions of energy units are . Dividing the units of energy (such as eV) by a fundamental constant (such as the speed of light) that has units of velocity () facilitates the required conversion for using energy units to describe momentum.

For example, if the momentum ''p'' of an electron is said to be , then the conversion to MKS system of units can be achieved by:
$p = 1\; \text/c = \frac = 5.344\ 286 \times 10^\; \text \text/\text.$

Distance

In particle physics, a system of natural units in which the speed of light in vacuum ''c'' and the reduced Planck constant ''ħ'' are dimensionless and equal to unity is widely used: . In these units, both distances and times are expressed in inverse energy units (while energy and mass are expressed in the same units, see mass–energy equivalence). In particular, particle scattering lengths are often presented in units of inverse particle masses.

Outside this system of units, the conversion factors between electronvolt, second, and nanometer are the following:
:$\hbar = 1.054\ 571\ 817\ 646\times 10^\ \mathrm = 6.582\ 119\ 569\ 509\times 10^\ \mathrm.$

The above relations also allow expressing the mean lifetime ''τ'' of an unstable particle (in seconds) in terms of its decay width Γ (in eV) via . For example, the meson has a lifetime of 1.530(9) picoseconds, mean decay length is , or a decay width of .

Conversely, the tiny meson mass differences responsible for meson oscillations are often expressed in the more convenient inverse picoseconds.

Energy in electronvolts is sometimes expressed through the wavelength of light with photons of the same energy:

:$\frac = \frac \thickapprox 8065.5439 \; \text^.$

Temperature

In certain fields, such as plasma physics, it is convenient to use the electronvolt to express temperature. The electronvolt is divided by the Boltzmann constant to convert to the Kelvin scale:

:$= = 11\ 604.518\ 12 \text,$

where ''k''_B is the Boltzmann constant.

The ''k''_B is assumed when using the electronvolt to express temperature, for example, a typical magnetic confinement fusion plasma is (kiloelectronvolt), which is equal to 174 MK (megakelvin).

As an approximation: ''k''_B''T'' is about (≈ ) at a temperature of .

Wavelength

The energy ''E'', frequency ''v'', and wavelength ''λ'' of a photon are related by

$E = h\nu = \frac = \frac$

where ''h'' is the Planck constant, ''c'' is the speed of light. This reduces to
\begin
E\mathrm
&=4.135\, 667\, 516 \times 10^\,\mathrm\times\nu \\ pt&=\frac.
\end
A photon with a wavelength of (green light) would have an energy of approximately . Similarly, would correspond to an infrared photon of wavelength or frequency .

Scattering experiments

In a low-energy nuclear scattering experiment, it is conventional to refer to the nuclear recoil energy in units of eVr, keVr, etc. This distinguishes the nuclear recoil energy from the "electron equivalent" recoil energy (eVee, keVee, etc.) measured by scintillation light. For example, the yield of a phototube is measured in phe/keVee (photoelectrons per keV electron-equivalent energy). The relationship between eV, eVr, and eVee depends on the medium the scattering takes place in, and must be established empirically for each material.

Energy comparisons

Per mole

One mole of particles given 1 eV of energy each has approximately 96.5 kJ of energy – this corresponds to the Faraday constant (''F'' ≈ ), where the energy in joules of ''n'' moles of particles each with energy ''E'' eV is equal to ''E''·''F''·''n''.

See also

*Orders of magnitude (energy)

References

External links

BIPM's definition of the electronvoltphysical constants reference; CODATA data

{{DEFAULTSORT:Electron Volt
Particle physics
Units of chemical measurement
Units of energy
Voltage