Keith James Laidler (January 3, 1916 – August 26, 2003), born in
England
England is a country that is part of the United Kingdom. It shares land borders with Wales to its west and Scotland to its north. The Irish Sea lies northwest and the Celtic Sea to the southwest. It is separated from continental Europe b ...
, was notable as a pioneer in
chemical kinetics
Chemical kinetics, also known as reaction kinetics, is the branch of physical chemistry that is concerned with understanding the rates of chemical reactions. It is to be contrasted with chemical thermodynamics, which deals with the direction in ...
and authority on the
physical chemistry
Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistica ...
of
enzymes.
Education
Laidler received his early education at
Liverpool College
Liverpool College is a school in Mossley Hill, Liverpool, England. It was one of the thirteen founding members of the Headmasters' Conference (HMC).
History
Liverpool College was the first of many public schools founded in the Victorian ...
. He received his BA (1934) and MA (1938) degrees from Trinity College,
Oxford University
Oxford () is a city in England. It is the county town and only city of Oxfordshire. In 2020, its population was estimated at 151,584. It is north-west of London, south-east of Birmingham and north-east of Bristol. The city is home to th ...
.
[Keith James Laidler, Physical Chemistry, A pioneer in the field of chemical kinetics and activated-complex theory]
The science.ca team, GCS Research Society (2001 and 2015).[Keith J. Laidler (1916–2003)]
Division of History of Chemistry of the American Chemical Society (2006) His MA was in the area of
chemical kinetics
Chemical kinetics, also known as reaction kinetics, is the branch of physical chemistry that is concerned with understanding the rates of chemical reactions. It is to be contrasted with chemical thermodynamics, which deals with the direction in ...
under
Cyril Norman Hinshelwood
Sir Cyril Norman Hinshelwood (19 June 1897 – 9 October 1967) was a British physical chemist and expert in chemical kinetics. His work in reaction mechanisms earned the 1956 Nobel Prize in chemistry.
Education
Born in London, his parents we ...
. He completed his PhD in 1940 from
Princeton University
Princeton University is a private research university in Princeton, New Jersey. Founded in 1746 in Elizabeth as the College of New Jersey, Princeton is the fourth-oldest institution of higher education in the United States and one of the ...
,
[ with a thesis entitled: ''The Kinetics of Reactions in Condensed and Heterogeneous Systems,'' under Henry Eyring.][ He was a ]National Research Council of Canada
The National Research Council Canada (NRC; french: Conseil national de recherches Canada) is the primary national agency of the Government of Canada dedicated to science and technology research & development. It is the largest federal research ...
Postdoctoral Fellow (1940–1942).
Career
After a decade at the Catholic University of America (1946-1955), he spent the remainder of his academic career at the University of Ottawa
The University of Ottawa (french: Université d'Ottawa), often referred to as uOttawa or U of O, is a bilingual public research university in Ottawa, Ontario, Canada. The main campus is located on directly to the northeast of Downtown Ottaw ...
(1955–1981), where he served as Chairman of the Department of Chemistry and Vice-Dean of the Faculty of Science.[ He was the author of 13 books and more than 250 articles.][ In his early years he worked with ]Cyril Hinshelwood
Sir Cyril Norman Hinshelwood (19 June 1897 – 9 October 1967) was a British physical chemist and expert in chemical kinetics. His work in reaction mechanisms earned the 1956 Nobel Prize in chemistry.
Education
Born in London, his parents we ...
on the theory of chemical kinetics, extending this during his doctoral work to the theory of absolute reaction rates with Henry Eyring and Samuel Glasstone
Samuel Glasstone (3 May 1897 – 16 November 1986) was a British-born American academic and writer of scientific books. He authored over 40 popular textbooks on physical chemistry and electrochemistry, reaction rates, nuclear weapons effec ...
. As an independent researcher in Ottawa he worked increasingly on enzymes, with both theoretical and experimental studies. He wrote several books of chemistry, and among these ''The Chemical Kinetics of Enzyme Action'' was for more than ten years by far the most important source of information on the subject. After his retirement Laidler increasingly worked on the history of science, and wrote books on the history of physical chemistry and its relationship with technology.
Laidler was a Fellow of the Royal Society of Canada, who described him "as one of the twentieth-century pioneers in the remarkable progress made in chemical kinetics
Chemical kinetics, also known as reaction kinetics, is the branch of physical chemistry that is concerned with understanding the rates of chemical reactions. It is to be contrasted with chemical thermodynamics, which deals with the direction in ...
leading to the development of transition state theory
In chemistry, transition state theory (TST) explains the reaction rates of elementary chemical reactions. The theory assumes a special type of chemical equilibrium (quasi-equilibrium) between reactants and activated transition state complexes.
T ...
which provides the modern kinetic theory. Laidler's work includes seminal contributions in several areas of the field: gas phase reactions; kinetic aspects of reactivity of electronically excited molecules and construction of potential energy surface
A potential energy surface (PES) describes the energy of a system, especially a collection of atoms, in terms of certain parameters, normally the positions of the atoms. The surface might define the energy as a function of one or more coordinat ...
s for such processes; development of treatments for kinetics and mechanisms for surface reactions and solution
Solution may refer to:
* Solution (chemistry), a mixture where one substance is dissolved in another
* Solution (equation), in mathematics
** Numerical solution, in numerical analysis, approximate solutions within specified error bounds
* Soluti ...
reactions, introducing modern concepts of solvation
Solvation (or dissolution) describes the interaction of a solvent with dissolved molecules. Both ionized and uncharged molecules interact strongly with a solvent, and the strength and nature of this interaction influence many properties of the ...
through dielectric polarization
In electromagnetism, a dielectric (or dielectric medium) is an electrical insulator that can be polarised by an applied electric field. When a dielectric material is placed in an electric field, electric charges do not flow through the mater ...
effects in the treatment of ionic redox
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a ...
reactions and of reactions producing or consuming ions; gas phase free-radical
In chemistry, a radical, also known as a free radical, is an atom, molecule, or ion that has at least one unpaired valence electron.
With some exceptions, these unpaired electrons make radicals highly chemically reactive. Many radicals spon ...
reactions involving pyrolysis
The pyrolysis (or devolatilization) process is the thermal decomposition of materials at elevated temperatures, often in an inert atmosphere. It involves a change of chemical composition. The word is coined from the Greek-derived elements ''py ...
and other thermal decomposition
Thermal decomposition, or thermolysis, is a chemical decomposition caused by heat. The decomposition temperature of a substance is the temperature at which the substance chemically decomposes. The reaction is usually endothermic as heat is re ...
processes; and … the kinetics of enzyme-catalyzed reactions."[
]
Honors
Laidler’s numerous honors include the University of Ottawa’s Award for Excellence in Research (1971), the Chemical Institute of Canada’s Union Carbide Award for Chemical Education (1974) as well as the Queen’s Jubilee Medal (1977), the Centenary Medal (1982), and the Henry Marshall Tory Medal
The Henry Marshall Tory Medal is an award of the Royal Society of Canada "for outstanding research in a branch of astronomy, chemistry, mathematics, physics, or an allied science". It is named in honour of Henry Marshall Tory and is awarded bi-ann ...
(1987), all from the Royal Society of Canada,[ and honorary degrees from ]Simon Fraser University
Simon Fraser University (SFU) is a public research university in British Columbia, Canada, with three campuses, all in Greater Vancouver: Burnaby (main campus), Surrey, and Vancouver. The main Burnaby campus on Burnaby Mountain, located ...
, Burnaby
Burnaby is a city in the Lower Mainland region of British Columbia, Canada. Located in the centre of the Burrard Peninsula, it neighbours the City of Vancouver to the west, the District of North Vancouver across the confluence of the Burrard I ...
, British Columbia
British Columbia (commonly abbreviated as BC) is the westernmost province of Canada, situated between the Pacific Ocean and the Rocky Mountains. It has a diverse geography, with rugged landscapes that include rocky coastlines, sandy beaches, ...
, Canada (1997) and from the University of Lethbridge
, mottoeng = '' Let there be light''
, type = Public
, established =
, academic_affiliations = Universities Canada
, endowment = $73 million (2019)
, chancellor = Charles Wease ...
, Alberta
Alberta ( ) is one of the thirteen provinces and territories of Canada. It is part of Western Canada and is one of the three prairie provinces. Alberta is bordered by British Columbia to the west, Saskatchewan to the east, the Northwest Ter ...
, Canada (1999). For his work in the history of physical chemistry the American Chemical Society’s Division of the History of Chemistry awarded him its Dexter Award The HIST Award for Outstanding Achievement in the History of Chemistry (2013-present) is given by the Division of the History of Chemistry of the American Chemical Society (ACS). The award was originally known as the Dexter Award (1956-2001) and th ...
"for outstanding contributions to the history of chemistry" (1996).[
Laidler retired in 1981 but continued to lecture as professor emeritus. He died on August 26, 2003.][ In 2004, the Canadian Society for Chemistry renamed their Noranda Award as the Keith Laidler Award in his memory.][
]
See also
* Chemical kinetics
Chemical kinetics, also known as reaction kinetics, is the branch of physical chemistry that is concerned with understanding the rates of chemical reactions. It is to be contrasted with chemical thermodynamics, which deals with the direction in ...
* Enzymes
References
{{DEFAULTSORT:Laidler, Keith J.
1916 births
2003 deaths
Princeton University alumni
Catholic University of America faculty
Alumni of Trinity College, Oxford
Canadian physical chemists
English physical chemists
University of Ottawa faculty
Fellows of the Royal Society of Canada
Scientists from Liverpool
People educated at Liverpool College
British emigrants to Canada