Kačák Event
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The Kačák Event (), also known as the Kačák-''otomari'' Event, is a widely recognised
bioevent A bioevent or bio-event (a shortening of 'biotic event' or 'biological event') is an event recognised in a sequence of sedimentary rocks, where there is a significant change in the biota as recorded by assemblages of fossils over a relatively shor ...
or series of events that occurred close to the end of the
Eifelian The Eifelian is the first of two faunal stages in the Middle Devonian Epoch. It lasted from 393.3 ± 1.2 million years ago to 387.7 ± 0.8 million years ago. It was preceded by the Emsian Stage and followed by the Givetian Stage. North American ...
Age Age or AGE may refer to: Time and its effects * Age, the amount of time someone has been alive or something has existed ** East Asian age reckoning, an Asian system of marking age starting at 1 * Ageing or aging, the process of becoming older ...
of the Middle
Devonian The Devonian ( ) is a period (geology), geologic period and system (stratigraphy), system of the Paleozoic era (geology), era during the Phanerozoic eon (geology), eon, spanning 60.3 million years from the end of the preceding Silurian per ...
Epoch. It involved a global
eustatic Mean sea level (MSL, often shortened to sea level) is an average surface level of one or more among Earth's coastal bodies of water from which heights such as elevation may be measured. The global MSL is a type of vertical datuma standardised ...
rise in sea level The sea level has been rising from the end of the last ice age, which was around 20,000 years ago. Between 1901 and 2018, the average sea level rose by , with an increase of per year since the 1970s. This was faster than the sea level had e ...
and ecological turnover. It was named for the Kačák Member of the Srbsko Formation in
Bohemia Bohemia ( ; ; ) is the westernmost and largest historical region of the Czech Republic. In a narrow, geographic sense, it roughly encompasses the territories of present-day Czechia that fall within the Elbe River's drainage basin, but historic ...
, where it is represented by a
black shale Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g., kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especiall ...
interval within a sequence of
limestone Limestone is a type of carbonate rock, carbonate sedimentary rock which is the main source of the material Lime (material), lime. It is composed mostly of the minerals calcite and aragonite, which are different Polymorphism (materials science) ...
. In
marine environments A marine habitat is a habitat that supports marine life. Marine life depends in some way on the seawater, saltwater that is in the sea (the term ''marine'' comes from the Latin ''mare'', meaning sea or ocean). A habitat is an ecological or Na ...
, this appears as an
anoxic event An anoxic event describes a period wherein large expanses of Earth's oceans were depleted of dissolved oxygen (O2), creating toxic, euxinic ( anoxic and sulfidic) waters. Although anoxic events have not happened for millions of years, the geol ...
, often forming potential
hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and Hydrophobe, hydrophobic; their odor is usually fain ...
source rock In petroleum geology, source rock is a sedimentary rock which has generated hydrocarbons or which has the potential to generate hydrocarbons. Source rocks are one of the necessary elements of a working petroleum system. They are organic-rich sedim ...
s such as the
Marcellus Shale Marcellus may refer to: People * Marcellus (name) * Marcellus of Ancyra, fourth-century Christian bishop and theologian * Marcus Claudius Marcellus, Roman commander * Marcellus of Tangier * Marcellus Empiricus * Marcellus (nephew of Augustu ...
. Within the
Old Red Sandstone continent Laurasia () was the more northern of two large landmasses that formed part of the Pangaea supercontinent from around ( Mya), the other being Gondwana. It separated from Gondwana (beginning in the late Triassic period) during the breakup of Pan ...
, it is represented by the Achanarras lake, the deepest and most widespread lake that developed within the Orcadian Basin. The event is associated with significant extinctions, particularly amongst the
Ammonoidea Ammonoids are extinct, (typically) coiled-shelled cephalopods comprising the subclass Ammonoidea. They are more closely related to living octopuses, squid, and cuttlefish (which comprise the clade Coleoidea) than they are to nautiluses (family N ...
.


Age and duration

The event occurred towards the end of the Eifelian, extending into the earliest part of the Givetian, in the mid-
Devonian The Devonian ( ) is a period (geology), geologic period and system (stratigraphy), system of the Paleozoic era (geology), era during the Phanerozoic eon (geology), eon, spanning 60.3 million years from the end of the preceding Silurian per ...
period. The duration of the event has been estimated as 700,000 years from the seven cycles involved in the Achanarras interval (each cycle interpreted to represent 100,000 years), but only 200,000 years using geochemical and magnetic resonance data from the Eifelian-Givetian boundary in Morocco.


Occurrence

The Kačák interval was first named from its occurrence in
Bohemia Bohemia ( ; ; ) is the westernmost and largest historical region of the Czech Republic. In a narrow, geographic sense, it roughly encompasses the territories of present-day Czechia that fall within the Elbe River's drainage basin, but historic ...
as a black shale unit, known as the Kačák Member. This organic rich shale is found within a sequence of shallow water limestones forming the Srbsko Formation of the Prague Basin. The event has also been recognised at
Eifel The Eifel (; , ) is a low mountain range in western Germany, eastern Belgium and northern Luxembourg. It occupies parts of southwestern North Rhine-Westphalia, northwestern Rhineland-Palatinate and the southern area of the German-speaking Com ...
in Germany, Gorodenka (near
Omsk Omsk (; , ) is the administrative center and largest types of inhabited localities in Russia, city of Omsk Oblast, Russia. It is situated in southwestern Siberia and has a population of over one million. Omsk is the third List of cities and tow ...
, Russia) and in
Ontario Ontario is the southernmost Provinces and territories of Canada, province of Canada. Located in Central Canada, Ontario is the Population of Canada by province and territory, country's most populous province. As of the 2021 Canadian census, it ...
and
New York State New York, also called New York State, is a state in the northeastern United States. Bordered by New England to the east, Canada to the north, and Pennsylvania and New Jersey to the south, its territory extends into both the Atlantic Ocean and ...
in eastern North America, all localities lying on the then continental shelf around the Old Red continent. Further afield at the time of the event, on the continental shelf on the other side of the
Rheic Ocean The Rheic Ocean (; ) was an ocean which separated two major paleocontinents, Gondwana and Laurussia ( Laurentia- Baltica- Avalonia). One of the principal oceans of the Paleozoic, its sutures today stretch from Mexico to Turkey and its closure r ...
, it has been recognised in
Morocco Morocco, officially the Kingdom of Morocco, is a country in the Maghreb region of North Africa. It has coastlines on the Mediterranean Sea to the north and the Atlantic Ocean to the west, and has land borders with Algeria to Algeria–Morocc ...
,
Cantabria Cantabria (, ; ) is an autonomous community and Provinces of Spain, province in northern Spain with Santander, Cantabria, Santander as its capital city. It is called a , a Nationalities and regions of Spain, historic community, in its current ...
in northern Spain, the
Carnic Alps The Carnic Alps (; ; ; ) are a range of the Southern Limestone Alps in Austria and northeastern Italy. They are within Austrian East Tyrol and Carinthia, and Italian Friuli (Province of Udine) and marginally in Veneto. Etymology They are ...
and
Graz Graz () is the capital of the Austrian Federal states of Austria, federal state of Styria and the List of cities and towns in Austria, second-largest city in Austria, after Vienna. On 1 January 2025, Graz had a population of 306,068 (343,461 inc ...
Paleozoic in Italy and Austria, the
Montagne Noire The Montagne Noire (; , known as the 'Black Mountain' in English) is a mountain range in central southern France. It is located at the southwestern end of the Massif Central at the juncture of the Tarn, Hérault and Aude departments. Its highe ...
in France and in the Barrandian area of the Czech Republic. The Orcadian Basin of Scotland is the only locality within the continent itself that the event is recognised. Similar events have also been correlated with the Kačák Event in China and Australia. In
Brazil Brazil, officially the Federative Republic of Brazil, is the largest country in South America. It is the world's List of countries and dependencies by area, fifth-largest country by area and the List of countries and dependencies by population ...
, the event was registered in the Paraná Basin. In the Horn River Group of
Canada Canada is a country in North America. Its Provinces and territories of Canada, ten provinces and three territories extend from the Atlantic Ocean to the Pacific Ocean and northward into the Arctic Ocean, making it the world's List of coun ...
, the Kačák interval corresponds to an appearance of anoxic sedimentation and a termination of carbonate platform deposition.


Geochemistry

At the level of the Kačák Event there is a marked negative excursion in the δ13C level, interpreted to be a result of the anoxic event. This reduction matches closely to an increase in both
total organic carbon Total organic carbon (TOC) is an analytical parameter representing the concentration of organic carbon in a sample. TOC determinations are made in a variety of application areas. For example, TOC may be used as a non-specific indicator of wa ...
and a change in the fractionation of carbon between carbonates and organic 'reservoirs'.


Cause

The cause of this event is interpreted to be a period of high temperatures resulting from high
insolation Solar irradiance is the power per unit area ( surface power density) received from the Sun in the form of electromagnetic radiation in the wavelength range of the measuring instrument. Solar irradiance is measured in watts per square metre ...
levels. This explains both the transgressive event recognised at the margins of the Old Red continent, caused by thermal expansion of the oceans, and the formation of the Achanarras lake within the continent due to the increased intensity of
monsoon A monsoon () is traditionally a seasonal reversing wind accompanied by corresponding changes in precipitation but is now used to describe seasonal changes in Atmosphere of Earth, atmospheric circulation and precipitation associated with annu ...
conditions.


Extinctions

The Kačák Event was a period of significant extinctions, although not as marked as those of the subsequent
Late Devonian extinction The Late Devonian mass extinction, also known as the Kellwasser event, was a mass extinction event which occurred around 372 million years ago, at the boundary between the Frasnian and Famennian ages of the Late Devonian period.Racki, 2005McGh ...
s.
Pelagic The pelagic zone consists of the water column of the open ocean and can be further divided into regions by depth. The word ''pelagic'' is derived . The pelagic zone can be thought of as an imaginary cylinder or water column between the sur ...
or
nektonic Nekton or necton (from the ) is any aquatic organism that can actively and persistently propel itself through a water column (i.e. swimming) without touching the bottom. Nektons generally have powerful tails and appendages (e.g. fins, pleopods ...
animals (which inhabited open ocean basins) were the most strongly affected. The ancestral
ammonoid Ammonoids are extinct, (typically) coiled-shelled cephalopods comprising the subclass Ammonoidea. They are more closely related to living octopuses, squid, and cuttlefish (which comprise the clade Coleoidea) than they are to nautiluses (family N ...
group, the agoniatitids, suffered heavy losses, while their descendants in the group
Tornoceratina Tornoceratina is one of two suborders included in the Goniatitida, characterized by generally involute, subdiscoidal shells and by sutures in which the ventral ones are undivided. Sutural lobes increase in number during the course of life of th ...
diversified at the same time. Conodonts also experienced a turnover, and the Kačák Event is equivalent to the '' Polygnathus ensensis'' conodont zone. The first part of the extinction is sometimes known as the ''otomari'' event, named after ''
Nowakia otomari ''Nowakia'' is an extinct genus of free living animals from Family Nowakiidae. References * Le genre Nowakia (Dacryoconarides) dans le Praguien (Dévonien) de la République Tcheque: Biométrie, systématique, Phylogénie, Paléoenvironnemen ...
'', a widespread species of dacryconarid which appeared during the event while other dacryconarids died out.


Economic importance

Organic-rich black shales that formed during this anoxic event occur in several countries. In the eastern United States the
Marcellus shale Marcellus may refer to: People * Marcellus (name) * Marcellus of Ancyra, fourth-century Christian bishop and theologian * Marcus Claudius Marcellus, Roman commander * Marcellus of Tangier * Marcellus Empiricus * Marcellus (nephew of Augustu ...
is in the early stages of being exploited for
shale gas Shale gas is an unconventional natural gas that is found trapped within shale formations. Since the 1990s, a combination of horizontal drilling and hydraulic fracturing has made large volumes of shale gas more economical to produce, and ...
, with large recoverable reserves predicted. An initial
USGS The United States Geological Survey (USGS), founded as the Geological Survey, is an government agency, agency of the United States Department of the Interior, U.S. Department of the Interior whose work spans the disciplines of biology, geograp ...
assessment from 2002 suggested about 2 TCF of recoverable gas, while in 2009, a study by the
United States Department of Energy The United States Department of Energy (DOE) is an executive department of the U.S. federal government that oversees U.S. national energy policy and energy production, the research and development of nuclear power, the military's nuclear w ...
gave an estimate of 262 TCF.US Department of Energy (April 2009)
''Modern shale gas development in the United States: a primer''
, p.17, PDF file, downloaded 7 March 2012.


References

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