Kalai (process)
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The art of kalai (kalhai or qalai) is the process of coating an
alloy An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductilit ...
surface such as
copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...
or
brass Brass is an alloy of copper (Cu) and zinc (Zn), in proportions which can be varied to achieve different mechanical, electrical, and chemical properties. It is a substitutional alloy: atoms of the two constituents may replace each other wit ...
by deposition of metal
tin Tin is a chemical element with the symbol Sn (from la, stannum) and atomic number 50. Tin is a silvery-coloured metal. Tin is soft enough to be cut with little force and a bar of tin can be bent by hand with little effort. When bent, t ...
on it. The word "kalai" is derived from
Sanskrit Sanskrit (; attributively , ; nominally , , ) is a classical language belonging to the Indo-Aryan branch of the Indo-European languages. It arose in South Asia after its predecessor languages had diffused there from the northwest in the late ...
word ''kalya lepa'', which means "white wash or tin". A cultural Sanskrit work by Keladi Basava called "Sivatattva Ratnakara" (1699) mentions "kalaya-lepa" in the chapter of cookery or "''supashashtra''" which means applying kalai on utensils. People practicing the art of kalai are called Kalaiwala or Kalaigar. Basically, Kalaigars or Kalaiwalas are community craftsmen.


History

Vessels with kalai, both on its interior and exterior have been found in the
excavations In archaeology, excavation is the exposure, processing and recording of archaeological remains. An excavation site or "dig" is the area being studied. These locations range from one to several areas at a time during a project and can be condu ...
of
Bramhapuri Bramhapuri is a town and municipal council in Chandrapur district in the state of Maharashtra, India. Geography Bramhapuri is one of the six divisions located in the northeastern part of Chandrapur district, Maharashtra at and has an av ...
at
Kolhapur Kolhapur () is a city on the banks of the Panchganga River in the southern part of the Indian state of Maharashtra. It is the administrative headquarter of the Kolhapur district. In, around 2 C.E. Kolapur's name was 'Kuntal'. Kolhapur is kn ...
,
Maharashtra Maharashtra (; , abbr. MH or Maha) is a states and union territories of India, state in the western India, western peninsular region of India occupying a substantial portion of the Deccan Plateau. Maharashtra is the List of states and union te ...
which adds to the archeological evidence of kalai art. From this evidence, P K. Gode, who studied tin coating on metallic vessels in
India India, officially the Republic of India (Hindi: ), is a country in South Asia. It is the seventh-largest country by area, the second-most populous country, and the most populous democracy in the world. Bounded by the Indian Ocean on the so ...
, stated that the history of tin coating dates back to 1300 C.E. The history of kalai is also recorded in “Parsibhashanushasana” of Vikaramasimha (before Samvat 1600 i.e. C.E. 1544) and also in the famous Ain- I -Akbari (C.E. 1590) by Abul Fazal.


Spiritual approach

The copper vessels with kalai were used to store water and cook food earlier because of a spiritual belief that copper attracts and transmits a divine consciousness also called “Chaitanya”. The spiritual approach to the use of copper vessels to store water is that copper and tin have Sattva-Raja (the basic component of creation/universe) component that is transferred to water.


Scientific approach

Earlier, copper and brass vessels were used because of their high
conductivity Conductivity may refer to: *Electrical conductivity, a measure of a material's ability to conduct an electric current **Conductivity (electrolytic), the electrical conductivity of an electrolyte in solution ** Ionic conductivity (solid state), ele ...
. High conductivity of copper vessels reduces the fuel cost. However, a chemical reaction between copper and oxygen called oxidization turns the copper vessels black. Copper also reacts with the moisture in air and creates
copper carbonate Copper carbonate may refer to : ;Copper (II) compounds and minerals * Copper(II) carbonate proper, (neutral copper carbonate): a rarely seen moisture-sensitive compound. * Basic copper carbonate (the "copper carbonate" of commerce), actually a cop ...
, which can be noticed as light green rust on the surface. Copper carbonate is poisonous and can make a person severely ill if it gets mixed with food. The copper can get dissolved in water in trace amounts when the water is stored in copper vessels for a long period of time. The process is known as the “
oligodynamic effect The oligodynamic effect (from Greek ''oligos'', "few", and ''dynamis'', "force") is a biocidal effect of metals, especially heavy metals, that occurs even in low concentrations. In modern times, the effect was observed by Carl Nägeli, althoug ...
”. Kalai protects from food poisoning and blackening of copper vessels by preventing direct contact of air with the copper or brass surface. Tin is also a good conductor of heat like copper, hence applying kalai does not result in loss of heat conductivity for the utensil. The kalai is required to be done on the vessels approximately every two months. Tin will melt if the temperature is above 425 degrees Fahrenheit (218.333 degrees Celsius). Also, the tin coating wears away with time. In order to protect the coating, one should use wooden or
silicon Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic tab ...
spatulas A spatula is a broad, flat, flexible blade used to mix, spread and lift material including foods, drugs, plaster and paints. In medical applications, "spatula" may also be used synonymously with tongue depressor. The word ''spatula'' derives f ...
and avoid cooking acidic foods.


Process

Kalai
can be done in various ways. Virgin grade tin (called ‘ranga’ in
Hindi Hindi (Devanāgarī: or , ), or more precisely Modern Standard Hindi (Devanagari: ), is an Indo-Aryan language spoken chiefly in the Hindi Belt region encompassing parts of northern, central, eastern, and western India. Hindi has been de ...
),
caustic soda Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations and hydroxide anions . Sodium hydroxide is a highly caustic base and alkali ...
,
sal ammoniac Salammoniac, also sal ammoniac or salmiac, is a rare naturally occurring mineral composed of ammonium chloride, NH4Cl. It forms colorless, white, or yellow-brown crystals in the isometric-hexoctahedral class. It has very poor cleavage and is ...
or ammonium chloride (called ‘nausadar’ powder in Hindi), and water are used in the process. The first step of kalai is to clean the utensil with water. There are two ways of cleaning the utensil further to remove any impurities such as dust. The first is to clean it with caustic soda. The other is to wash it with dilute acid solution which contains a gold purifying compound known as ‘sufa’. If the latter is used, the utensil should be cleaned immediately after applying the dilute acidic solution as it may bear a mark if not done immediately. After the cleaning, the vessel is heated on burning coal for about 2 to 3 minutes. The Kalaiwala, Kalaigar or Kalaikar then digs a small pit in the ground to burn the coal. He/she prepares a temporary
blast furnace A blast furnace is a type of metallurgical furnace used for smelting to produce industrial metals, generally pig iron, but also others such as lead or copper. ''Blast'' refers to the combustion air being "forced" or supplied above atmospheric ...
to do kalai and blows air through bellows. After the vessel turns pinkish hot, virgin grade tin (in the form of strips) is applied on the hot vessel. This step is called ‘casting’ by the Kalaigars. The ‘nausadar’ powder is sprinkled on the vessel. The tin melts rapidly which is then rubbed evenly on the utensil with the help of a cotton cloth or a swab of cotton. The rubbing process is known as ‘majaay’ in Hindi. A whitish smoke with the peculiar smell of
ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous was ...
is released when the ‘nausadar’ powder is rubbed on the utensil. A silvery lining appears on the vessel with a shine. The final step of kalai is to dip the utensil in cold water.


Present scenario

Kalai was earlier done with
silver Silver is a chemical element with the Symbol (chemistry), symbol Ag (from the Latin ', derived from the Proto-Indo-European wikt:Reconstruction:Proto-Indo-European/h₂erǵ-, ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, whi ...
instead of tin but now it would be too expensive. As
stainless steel Stainless steel is an alloy of iron that is resistant to rusting and corrosion. It contains at least 11% chromium and may contain elements such as carbon, other nonmetals and metals to obtain other desired properties. Stainless steel's corros ...
and
aluminum Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It has ...
ware came into being, the usage of copper and brass utensils decreased, which led the Kalaigars to suffer losses. Nowadays only some hotels and a very few people use vessels with kalai. As a result, there are a very few Kalaigars left and the art of kalai is vanishing.


References

{{reflist Alloys Copper Brass Tin