Johann Wolfgang Döbereiner (13 December 1780 – 24 March 1849) was a German

chemist A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a scientist trained in the study of chemistry. Chemists study the composition of matter and its properties. Chemists carefully describe th ...

who is best known for work that foreshadowed the

periodic law Periodic trends are specific patterns that are present in the periodic table that illustrate different aspects of a certain element. They were discovered by the Russian chemist Dmitri Mendeleev in the year 1863. Major periodic trends include atom ...

for the

chemical element A chemical element is a species of atoms that have a given number of protons in their nuclei, including the pure substance consisting only of that species. Unlike chemical compounds, chemical elements cannot be broken down into simpler sub ...

s, and for inventing the first

lighter A lighter is a portable device which creates a flame, and can be used to ignite a variety of items, such as cigarettes, gas lighter, fireworks, candles or campfires. It consists of a metal or plastic container filled with a flammable liquid or c ...

, which was known as the

Döbereiner's lamp Döbereiner's lamp, also called a "tinderbox" ("Feuerzeug"), is a lighter invented in 1823 by the German chemist Johann Wolfgang Döbereiner. The lighter is based on the Fürstenberger lighter (invented in Basel in 1780; in which hydrogen gas i ...

. He became a professor of chemistry and pharmacy at the

University of Jena The University of Jena, officially the Friedrich Schiller University Jena (german: Friedrich-Schiller-Universität Jena, abbreviated FSU, shortened form ''Uni Jena''), is a public research university located in Jena, Thuringia, Germany. The u ...

Life and work

As a coachman's son, Döbereiner had little opportunity for formal schooling. Thus, he was apprenticed to an apothecary, and began to read widely and to attend science lectures. He eventually became a professor at the

in 1810 and also studied chemistry at

Strasbourg Strasbourg (, , ; german: Straßburg ; gsw, label= Bas Rhin Alsatian, Strossburi , gsw, label=Haut Rhin Alsatian, Strossburig ) is the prefecture and largest city of the Grand Est region of eastern France and the official seat of the Eu ...

. In work published in 1829, Döbereiner reported trends in certain properties of selected groups of elements. For example, the average of the atomic masses of

lithium Lithium (from el, λίθος, lithos, lit=stone) is a chemical element with the symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the least dense metal and the least dense solid e ...

and

potassium Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosp ...

was close to the atomic mass of

sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable is ...

. A similar pattern was found with

calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar ...

strontium Strontium is the chemical element with the symbol Sr and atomic number 38. An alkaline earth metal, strontium is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is ex ...

, and

barium Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. The ...

; with

sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...

selenium Selenium is a chemical element with the symbol Se and atomic number 34. It is a nonmetal (more rarely considered a metalloid) with properties that are intermediate between the elements above and below in the periodic table, sulfur and tellurium ...

tellurium Tellurium is a chemical element with the symbol Te and atomic number 52. It is a brittle, mildly toxic, rare, silver-white metalloid. Tellurium is chemically related to selenium and sulfur, all three of which are chalcogens. It is occasionally fou ...

; and with

chlorine Chlorine is a chemical element with the symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine is ...

bromine Bromine is a chemical element with the symbol Br and atomic number 35. It is the third-lightest element in group 17 of the periodic table (halogens) and is a volatile red-brown liquid at room temperature that evaporates readily to form a simila ...

, and

iodine Iodine is a chemical element with the symbol I and atomic number 53. The heaviest of the stable halogens, it exists as a semi-lustrous, non-metallic solid at standard conditions that melts to form a deep violet liquid at , and boils to a vi ...

. Moreover, the densities for some of these triads followed a similar pattern. These sets of elements became known as "

Döbereiner's triads In the history of the periodic table, Döbereiner's triads were an early attempt to sort the elements into some logical order and sets based on their physical properties. They are analogous to the groups (columns) on the modern periodic table. 53 ...

Döbereiner also is known for his discovery of

furfural Furfural is an organic compound with the formula C4H3OCHO. It is a colorless liquid, although commercial samples are often brown. It has an aldehyde group attached to the 2-position of furan. It is a product of the dehydration of sugars, as occurs ...

, for his work on the use of

platinum Platinum is a chemical element with the symbol Pt and atomic number 78. It is a dense, malleable, ductile, highly unreactive, precious, silverish-white transition metal. Its name originates from Spanish , a diminutive of "silver". Platin ...

as a catalyst, and for a lighter, known as

. By 1828 hundreds of thousands of these lighters had been mass produced by the German manufacturer Gottfried Piegler in

Schleiz Schleiz is a town in the district of Saale-Orla-Kreis in Thuringia, Germany. The former municipality Crispendorf was merged into Schleiz in January 2019, and Burgk in December 2019. Location Schleiz is in the Thuringian Vogtland area, an a ...

. The German writer

Goethe Johann Wolfgang von Goethe (28 August 1749 – 22 March 1832) was a German poet, playwright, novelist, scientist, statesman, theatre director, and critic. His works include plays, poetry, literature, and aesthetic criticism, as well as tre ...

was a friend of Döbereiner, attended his lectures weekly, and used his theories of

chemical affinities In chemical physics and physical chemistry, chemical affinity is the electronic property by which dissimilar chemical species are capable of forming chemical compounds. Chemical affinity can also refer to the tendency of an atom or compound to com ...

as a basis for his famous 1809 novella

Elective Affinities ''Elective Affinities'' (German: ''Die Wahlverwandtschaften''), also translated under the title ''Kindred by Choice'', is the third novel by Johann Wolfgang von Goethe, published in 1809. Situated around the city of Weimar, the book relates the ...

Works

* ''Deutsches Apothekerbuch'' . Vol. 1-3 . Balz, Stuttgart 1842-184
Digital edition
by the

University and State Library Düsseldorf The University and State Library Düsseldorf (german: Universitäts- und Landesbibliothek Düsseldorf, abbreviated ULB Düsseldorf) is a central service institution of Heinrich Heine University. Along with Bonn and Münster, it is also one of t ...

Life and work

Works

References

Further reading