Johann Wilhelm Hittorf (27 March 1824 – 28 November 1914) was a German physicist who was born in

Bonn The federal city of Bonn ( lat, Bonna) is a city on the banks of the Rhine in the German state of North Rhine-Westphalia, with a population of over 300,000. About south-southeast of Cologne, Bonn is in the southernmost part of the Rhine-Ru ...

and died in

Münster Münster (; nds, Mönster) is an independent city (''Kreisfreie Stadt'') in North Rhine-Westphalia, Germany. It is in the northern part of the state and is considered to be the cultural centre of the Westphalia region. It is also a state di ...

, Germany. Hittorf was the first to compute the electricity-carrying capacity of charged atoms and molecules (

ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...

s), an important factor in understanding

electrochemical reaction Electrochemistry is the branch of physical chemistry concerned with the relationship between electrical potential difference, as a measurable and quantitative phenomenon, and identifiable chemical change, with the potential difference as an outco ...

s. He formulated ion transport numbers and the first method for their measurements. He observed

tubes Tube or tubes may refer to: * ''Tube'' (2003 film), a 2003 Korean film * ''The Tube'' (TV series), a music related TV series by Channel 4 in the United Kingdom * "Tubes" (Peter Dale), performer on the Soccer AM television show * Tube (band), a ...

with energy rays extending from a negative

electrode An electrode is an electrical conductor used to make contact with a nonmetallic part of a circuit (e.g. a semiconductor, an electrolyte, a vacuum or air). Electrodes are essential parts of batteries that can consist of a variety of materials d ...

. These rays produced a fluorescence when they hit the glass walls of the tubes. In 1876 the effect was named "

cathode ray Cathode rays or electron beam (e-beam) are streams of electrons observed in discharge tubes. If an evacuated glass tube is equipped with two electrodes and a voltage is applied, glass behind the positive electrode is observed to glow, due to el ...

s" by Eugen Goldstein. Hittorf's early investigations were on the allotropes of

phosphorus Phosphorus is a chemical element with the symbol P and atomic number 15. Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Ear ...

and

selenium Selenium is a chemical element with the symbol Se and atomic number 34. It is a nonmetal (more rarely considered a metalloid) with properties that are intermediate between the elements above and below in the periodic table, sulfur and tellurium, ...

. Between 1853 and 1859 his most important work was on ion movement caused by electric current. In 1853 Hittorf pointed out that some ions traveled more rapidly than others. This observation led to the concept of transport number, the fraction of the electric current carried by each ionic species. He measured the changes in the concentration of electrolyzed solutions, computed from these the transport numbers (relative carrying capacities) of many ions, and, in 1869, published his laws governing the migration of ions. He became professor of physics and chemistry at the

University of Münster The University of Münster (german: Westfälische Wilhelms-Universität Münster, WWU) is a public research university located in the city of Münster, North Rhine-Westphalia in Germany. With more than 43,000 students and over 120 fields of stud ...

and director of laboratories there from 1879 until 1889. He also investigated the light spectra of gases and vapours, worked on the passage of electricity through gases, and discovered new properties of cathode rays (electron rays). In 1869 he ascertained that the cathode rays glowed different colours because of different gasses and pressures. He noticed that when there was any object placed between the cathode and the illuminating side of the tube, then the shadow of that object appeared. His work led toward development of

X-ray An X-ray, or, much less commonly, X-radiation, is a penetrating form of high-energy electromagnetic radiation. Most X-rays have a wavelength ranging from 10 picometers to 10 nanometers, corresponding to frequencies in the range 30&nb ...

s and cathode ray tubes. The measurement of current in a vacuum tube was an important step towards the creation of a vacuum tube diode.

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{{DEFAULTSORT:Hittorf, Johann Wilhelm 1824 births 1914 deaths 19th-century German physicists Electrochemists Recipients of the Pour le Mérite (civil class) Scientists from Bonn

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