Johannite is a rare

uranium Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weak ...

sulfate mineral The sulfate minerals are a class of minerals that include the sulfate ion () within their structure. The sulfate minerals occur commonly in primary evaporite depositional environments, as gangue minerals in hydrothermal veins and as secondary mine ...

. It crystallizes in the

triclinic crystal system 180px, Triclinic (a ≠ b ≠ c and α ≠ β ≠ γ ) In crystallography, the triclinic (or anorthic) crystal system is one of the 7 crystal systems. A crystal system is described by three basis vectors. In the triclinic system, the crystal i ...

with the chemical composition Cu O₂(OH)SO₄sub>2·8H₂O. It crystallizes in the

triclinic 180px, Triclinic (a ≠ b ≠ c and α ≠ β ≠ γ ) In crystallography, the triclinic (or anorthic) crystal system is one of the 7 crystal systems. A crystal system is described by three basis vectors. In the triclinic system, the crystal i ...

system and develops only small prism or thin to thick tabular

crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macro ...

s, usually occurs as flaky or spheroidal aggregates and efflorescent coatings. Its color is emerald-green to

apple An apple is an edible fruit produced by an apple tree (''Malus domestica''). Apple trees are cultivated worldwide and are the most widely grown species in the genus ''Malus''. The tree originated in Central Asia, where its wild ancestor, ' ...

-green and its streak is pale green. Johannite is a strong radioactive mineral with a calculated activity of 87,501,143 Bq/g (to the comparison: natural

potassium Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosph ...

: 31.2 Bq/g).

Etymology and history

Johannite was first described in 1830 by

Wilhelm Karl Ritter von Haidinger Wilhelm Karl Ritter von Haidinger (or Wilhelm von Haidinger, or most often Wilhelm Haidinger) (5 February 179519 March 1871) was an Austrian mineralogist. Early life Haidinger's father was the mineralogist Karl Haidinger (1756–1797), who died w ...

. It was named for Archduke John of Austria (1782–1859), the founder of the Landesmuseum Joanneum (Styria, Austria).

Occurrence

Johannite forms as secondary mineral by

oxidation Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a ...

from

uraninite Uraninite, formerly pitchblende, is a radioactive, uranium-rich mineral and ore with a chemical composition that is largely UO2 but because of oxidation typically contains variable proportions of U3O8. Radioactive decay of the uranium causes ...

as well as different other uranium minerals. Localities include Argentina, Czech Republic, France, Gabon, Germany, Greece, Italy, Switzerland, United Kingdom and the United States. Type locality is the “Elias Mine” in

Jáchymov Jáchymov (); german: Sankt Joachimsthal or ''Joachimsthal'') is a spa town in Karlovy Vary District in the Karlovy Vary Region of the Czech Republic. It has about 2,300 inhabitants. The historical core of the town from the 16th century is we ...

(Czech Republic).

Crystal structure

Johannite crystallizes in the triclinic crystal system in the

space group In mathematics, physics and chemistry, a space group is the symmetry group of an object in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of an object that leave it uncha ...

P with the lattice parameters a = 8.92 Å, b = 9.59 Å, c = 6.84 Å; α = 110°, β = 111.98°, γ = 100.3° and one formula unit per

unit cell In geometry, biology, mineralogy and solid state physics, a unit cell is a repeating unit formed by the vectors spanning the points of a lattice. Despite its suggestive name, the unit cell (unlike a unit vector, for example) does not necessaril ...

References

{{Commons category, Johannite, position=left

Bibliography

*Palache, P.; Berman H.; Frondel, C. (1960). "''Dana's System of Mineralogy, Volume II: Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. (Seventh Edition)"'' John Wiley and Sons, Inc., New York, pp. 606-607. Copper(II) minerals Uranium(VI) minerals Sulfate minerals Triclinic minerals Minerals in space group 2