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Jiří Čížek (August 24, 1938 – December 24, 2024) was a Distinguished Emeritus professor at
University of Waterloo The University of Waterloo (UWaterloo, UW, or Waterloo) is a Public university, public research university located in Waterloo, Ontario, Canada. The main campus is on of land adjacent to uptown Waterloo and Waterloo Park. The university also op ...
in Canada. In 1966 he reformulated the
coupled cluster Coupled cluster (CC) is a numerical technique used for describing many-body systems. Its most common use is as one of several post-Hartree–Fock ab initio quantum chemistry methods in the field of computational chemistry, but it is also used ...
method (originally developed in the 1950s for nuclear physics) for the study of electron correlation in atoms and molecules (and later worked together with colleague Josef Paldus). He was a Fellow of the
Royal Society of Canada The Royal Society of Canada (RSC; , SRC), also known as the Academies of Arts, Humanities, and Sciences of Canada (French: ''Académies des arts, des lettres et des sciences du Canada''), is the senior national, bilingual council of distinguishe ...
and has been honored by the
International Academy of Quantum Molecular Science The International Academy of Quantum Molecular Science (IAQMS) is an international scientific learned society covering all applications of quantum theory to chemistry and chemical physics. It was created in Menton in 1967. The founding members we ...
.


Early life and education

Čížek was born on August 24, 1938, in
Prague Prague ( ; ) is the capital and List of cities and towns in the Czech Republic, largest city of the Czech Republic and the historical capital of Bohemia. Prague, located on the Vltava River, has a population of about 1.4 million, while its P ...
,
Czechoslovakia Czechoslovakia ( ; Czech language, Czech and , ''Česko-Slovensko'') was a landlocked country in Central Europe, created in 1918, when it declared its independence from Austria-Hungary. In 1938, after the Munich Agreement, the Sudetenland beca ...
, to Václav Čížek (1908–1957) and Jiřina Čížková (1908–1994), who were both physicians. In 1955 he spent a summer working with Jaroslav Koutecký (1922–2005) on problems on kinetic currents in
polarography Polarography is a type of voltammetry where the working electrode is a dropping mercury electrode (DME) or a static mercury drop electrode (SMDE), which are useful for their wide cathodic ranges and renewable surfaces. It was invented in 1922 by C ...
, before Čížek finished his high school education in 1956. He then enrolled at
Charles University of Prague Charles University (CUNI; , UK; ; ), or historically as the University of Prague (), is the largest university in the Czech Republic. It is one of the oldest universities in the world in continuous operation, the oldest university north of the ...
in the Faculty of Mathematics and Physics, during which time his father passed away in 1957, before he finished his Masters (
RNDr for, la, Doctor rerum naturalium, Doctor of Natural Sciences, paren=left, ), abbreviated Dr. rer. nat., is a doctoral academic degree awarded by universities in some European countries (e.g. Germany, Austria and Czech Republic) to graduates in phy ...
) thesis in 1961 and received the a year later for the contributions to polarography in his first 5 papers. He then began his doctoral studies at the Institute of Physical Chemistry of the
Czechoslovak Academy of Sciences The Czechoslovak Academy of Sciences (Czech: ''Československá akademie věd'', Slovak: ''Česko-slovenská akadémia vied'') was established in 1953 to be the scientific center for Czechoslovakia. It was succeeded by the Czech Academy of Science ...
(now the J. Heyrovský Institute). It was during this time that he proposed the use of the
coupled cluster Coupled cluster (CC) is a numerical technique used for describing many-body systems. Its most common use is as one of several post-Hartree–Fock ab initio quantum chemistry methods in the field of computational chemistry, but it is also used ...
method for studying
electron correlation Electronic correlation is the interaction between electrons in the electronic structure of a quantum system. The correlation energy is a measure of how much the movement of one electron is influenced by the presence of all other electrons. At ...
in atoms and molecules, in his CSc doctoral dissertation, which was completed in 1964 (in the same year his son and first child was born) and defended in 1965. He began working as a Junior Scientist at Institute of Physical Chemistry in
Prague Prague ( ; ) is the capital and List of cities and towns in the Czech Republic, largest city of the Czech Republic and the historical capital of Bohemia. Prague, located on the Vltava River, has a population of about 1.4 million, while its P ...
in 1964.


Academic career

The 1968
Warsaw Pact invasion of Czechoslovakia On 20–21 August 1968, the Czechoslovak Socialist Republic was jointly invaded by four fellow Warsaw Pact countries: the Soviet Union, the Polish People's Republic, the People's Republic of Bulgaria, and the Hungarian People's Republic. The ...
interrupted Čížek's doctoral studies, which he was pursuing while working as a Junior Scientist at the Institute of Physical Chemistry in Prague, and forced him to leave his native country. He moved to Canada to join the Department of Applied Mathematics at the
University of Waterloo The University of Waterloo (UWaterloo, UW, or Waterloo) is a Public university, public research university located in Waterloo, Ontario, Canada. The main campus is on of land adjacent to uptown Waterloo and Waterloo Park. The university also op ...
as an associate professor. Later, he was cross-appointed to the Department of Chemistry in 1973 and was promoted to full professor in 1975. He also served two terms on the University of Waterloo's Senate, the first one from 1977–80 and the second from 1985–88, and held positions as affiliate professor at
University of Florida The University of Florida (Florida or UF) is a public university, public land-grant university, land-grant research university in Gainesville, Florida, United States. It is a senior member of the State University System of Florida and a preem ...
in Gainesville (appointed in 1982) and adjunct professor at
Charles University Charles University (CUNI; , UK; ; ), or historically as the University of Prague (), is the largest university in the Czech Republic. It is one of the List of oldest universities in continuous operation, oldest universities in the world in conti ...
(appointed in 1995). Following the 1989
Velvet Revolution The Velvet Revolution () or Gentle Revolution () was a non-violent transition of power in what was then Czechoslovakia, occurring from 17 November to 28 November 1989. Popular demonstrations against the one-party government of the Communist Pa ...
, in 1991 he was able to present and defend his doctoral thesis at the Czechoslovak Academy of Sciences. He retired from the University of Waterloo in 1996 and received the title of Distinguished Professor Emeritus. He also was a permanent Visiting Professor at Charles University.


Scientific work

The numerous research contributions of Čížek throughout his career, together with a complete bibliography of his 180 peer-reviewed publications, were summarized in the AIP Proceedings of the International Conference of Computational Methods in Science and Engineering in 2010. He is internationally recognized for his work in
quantum chemistry Quantum chemistry, also called molecular quantum mechanics, is a branch of physical chemistry focused on the application of quantum mechanics to chemical systems, particularly towards the quantum-mechanical calculation of electronic contributions ...
. One particularly high-impact contribution was made in 1966, when the
coupled cluster Coupled cluster (CC) is a numerical technique used for describing many-body systems. Its most common use is as one of several post-Hartree–Fock ab initio quantum chemistry methods in the field of computational chemistry, but it is also used ...
method was reformulated for applications in the electronic structure of atoms and molecules. This work led directly to the use of coupled cluster methods in many applications of
computational chemistry Computational chemistry is a branch of chemistry that uses computer simulations to assist in solving chemical problems. It uses methods of theoretical chemistry incorporated into computer programs to calculate the structures and properties of mol ...
. Coupled cluster methods are available in many major
quantum chemistry Quantum chemistry, also called molecular quantum mechanics, is a branch of physical chemistry focused on the application of quantum mechanics to chemical systems, particularly towards the quantum-mechanical calculation of electronic contributions ...
software packages, including
Gaussian Carl Friedrich Gauss (1777–1855) is the eponym of all of the topics listed below. There are over 100 topics all named after this German mathematician and scientist, all in the fields of mathematics, physics, and astronomy. The English eponymo ...
,
Spartan Sparta was a prominent city-state in Laconia in ancient Greece. In antiquity, the city-state was known as Lacedaemon (), while the name Sparta referred to its main settlement in the valley of Evrotas river in Laconia, in southeastern Pe ...
, and GAMESS. In 1982, Čížek and E. R. Vrscay wrote a conjecture about the Binet function which was eventually proven by W. B. Jones and W. van Asschler in 1998. The Binet function is relevant to the continuous expansion of the
gamma function In mathematics, the gamma function (represented by Γ, capital Greek alphabet, Greek letter gamma) is the most common extension of the factorial function to complex numbers. Derived by Daniel Bernoulli, the gamma function \Gamma(z) is defined ...
.


Personal life

He married Ludmila Zamazalová (1939–2008) in September 1963. Together they had a son, Petr (born in 1964, now an urban planner) and a daughter, Katerina (born in 1969 and now a documentary film maker). Čížek died in late 2024.


Awards

* (1962) * (1976) Received the Medal of the International Academy of Quantum Molecular Science * (1987) Elected to International Academy of Quantum Molecular Science * (1988) Elected Fellow of the Royal Society of Canada * (1991) Recipient of the Heyrovsky Gold Medal of the
Czechoslovak Academy of Sciences The Czechoslovak Academy of Sciences (Czech: ''Československá akademie věd'', Slovak: ''Česko-slovenská akadémia vied'') was established in 1953 to be the scientific center for Czechoslovakia. It was succeeded by the Czech Academy of Science ...
* (1994) Alexander von Humboldt Senior Scientist Award * (2006) Czech Spirit Award * Honorary degrees from
Clark Atlanta University Clark Atlanta University (CAU or Clark Atlanta) is a private, Methodist, historically black research university in Atlanta, Georgia, United States. It was founded on September19, 1865, as Atlanta University, it was the first HBCU in the South ...
(1999) and Silesian University in Opava (2009)


References

{{DEFAULTSORT:Čížek, Jiří 1938 births 2024 deaths 20th-century Canadian chemists Czech chemists Academic staff of the University of Waterloo Scientists from Prague Charles University alumni Fellows of the Royal Society of Canada Czech emigrants to Canada Members of the International Academy of Quantum Molecular Science