Jean-Servais Stas
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Jean Servais Stas (21 August 1813 – 13 December 1891) was a Belgian analytical
chemist A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a scientist trained in the study of chemistry. Chemists study the composition of matter and its properties. Chemists carefully describe th ...
who co-discovered the atomic weight of
carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent In chemistry, the valence (US spelling) or valency (British spelling) of an element is the measure of its combining capacity with o ...
.


Life and work

Stas was born in
Leuven Leuven (, ) or Louvain (, , ; german: link=no, Löwen ) is the capital and largest city of the province of Flemish Brabant in the Flemish Region of Belgium. It is located about east of Brussels. The municipality itself comprises the historic ...
and trained initially as a physician. He later switched to
chemistry Chemistry is the science, scientific study of the properties and behavior of matter. It is a natural science that covers the Chemical element, elements that make up matter to the chemical compound, compounds made of atoms, molecules and ions ...
and worked at the
École Polytechnique École may refer to: * an elementary school in the French educational stages normally followed by secondary education establishments (collège and lycée) * École (river), a tributary of the Seine flowing in région Île-de-France * École, Savoi ...
in Paris under the direction of
Jean-Baptiste Dumas Jean Baptiste André Dumas (14 July 180010 April 1884) was a French chemist, best known for his works on organic analysis and synthesis, as well as the determination of atomic weights (relative atomic masses) and molecular weights by measuring v ...
. Stas and Dumas established the atomic weight of
carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent In chemistry, the valence (US spelling) or valency (British spelling) of an element is the measure of its combining capacity with o ...
by weighing a sample of the pure material, burning it in pure
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as wel ...
, and then weighing the
carbon dioxide Carbon dioxide (chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is transpar ...
produced. In 1840, Stas was appointed professor at the Royal Military School in
Brussels Brussels (french: Bruxelles or ; nl, Brussel ), officially the Brussels-Capital Region (All text and all but one graphic show the English name as Brussels-Capital Region.) (french: link=no, Région de Bruxelles-Capitale; nl, link=no, Bruss ...
. He acquired international fame by determining the atomic weights of the elements more accurately than had ever been done before, using an
atomic mass The atomic mass (''m''a or ''m'') is the mass of an atom. Although the SI unit of mass is the kilogram (symbol: kg), atomic mass is often expressed in the non-SI unit dalton (symbol: Da) – equivalently, unified atomic mass unit (u). 1&nbs ...
of 16 for
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as wel ...
as his standard. His results disproved the hypothesis of the English physicist William Prout that all atomic weights must be integer multiples of that of
hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, an ...
. These careful, accurate atomic weight measurements of Stas helped lay the foundation for the periodic system of elements of
Dmitri Mendeleev Dmitri Ivanovich Mendeleev (sometimes transliterated as Mendeleyev or Mendeleef) ( ; russian: links=no, Дмитрий Иванович Менделеев, tr. , ; 8 February Old_Style_and_New_Style_dates">O.S._27_January.html" ;"title="O ...
and others. Following the pioneering work of
Lavoisier Antoine-Laurent de Lavoisier ( , ; ; 26 August 17438 May 1794),
CNRS (
conservation of mass, the prolonged and exhaustive experiments of Stas supported the strict accuracy of this law in
chemical reaction A chemical reaction is a process that leads to the IUPAC nomenclature for organic transformations, chemical transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the pos ...
s, even though they were carried out with other intentions. His research indicated that in certain reactions the loss or gain could not have been more than from 2 to 4 parts in 100,000. The difference in the accuracy aimed at and attained by Lavoisier on the one hand, and by Morley and Stas on the other, is enormous. In 1850, Stas gave the evidence that the Belgian Count
Hippolyte Visart de Bocarmé Hippolyte Visart de Bocarmé (Weltevreden, Java 14 June 1818 – Mons, Belgium 19 July 1851) was a Belgian nobleman and convicted murderer. He poisoned his brother-in-law in order to acquire some urgently needed money. In 1851, the chemist Jea ...
killed his brother-in-law by poisoning him with
nicotine Nicotine is a natural product, naturally produced alkaloid in the nightshade family of plants (most predominantly in tobacco and ''Duboisia hopwoodii'') and is widely used recreational drug use, recreationally as a stimulant and anxiolytic. As ...
. Stas retired in 1869 because of problems with his voice caused by a throat ailment. He became commissioner of the mint, but resigned in 1872 because he disagreed with the government's
monetary policy Monetary policy is the policy adopted by the monetary authority of a nation to control either the interest rate payable for very short-term borrowing (borrowing by banks from each other to meet their short-term needs) or the money supply, often a ...
. Jean Stas died in
Brussels Brussels (french: Bruxelles or ; nl, Brussel ), officially the Brussels-Capital Region (All text and all but one graphic show the English name as Brussels-Capital Region.) (french: link=no, Région de Bruxelles-Capitale; nl, link=no, Bruss ...
and was buried at
Leuven Leuven (, ) or Louvain (, , ; german: link=no, Löwen ) is the capital and largest city of the province of Flemish Brabant in the Flemish Region of Belgium. It is located about east of Brussels. The municipality itself comprises the historic ...
.


Honors and awards

* Foreign Member,
Royal Society of London The Royal Society, formally The Royal Society of London for Improving Natural Knowledge, is a learned society and the United Kingdom's national academy of sciences. The society fulfils a number of roles: promoting science and its benefits, re ...
(1879) * Davy Medal (1885) * On May 5, 1891 an event was held recognizing the 50th anniversary of Jean Servais Stas' membership in the
Royal Academy of Belgium The Royal Academies for Science and the Arts of Belgium (RASAB) is a non-governmental association which promotes and organises science and the arts in Belgium by coordinating the national and international activities of its constituent academies su ...
. Various presenters spoke about his significant scientific contributions. He was presented with a medal in his honor sculpted by Belgian engraver
Alphonse Michaux Alphonse Michaux (1860–1928) was a Belgian coin engraver and medalist. Michaux was born in Brussels on 15 December 1860. He was the son of Belgian engraver Robert Michaux (1824–1901), and as a young man studied at the Academy of Fine Arts ...
and with an album containing accolades authored by scientific societies from around the world.L'Academie Royale des Sciences, des Lettres et des Beaux-Arts de Belgique, ''Manifestation en L'Honneur de Jean-Servais Stas a L'Occasion du Cinquantieme Anniversaire de Sa Nomination Comme Membre Titulaire de la Classe des Sciences 1841 - 1891'', Bruxelles, 1891.


Selected writings

* * *


See also

*
Theodore William Richards Theodore William Richards (January 31, 1868 – April 2, 1928) was the first American scientist to receive the Nobel Prize in Chemistry, earning the award "in recognition of his exact determinations of the atomic weights of a large number of the ...
* Law of reciprocal proportions *
Mass spectrometry Mass spectrometry (MS) is an analytical technique that is used to measure the mass-to-charge ratio of ions. The results are presented as a ''mass spectrum'', a plot of intensity as a function of the mass-to-charge ratio. Mass spectrometry is use ...
*
Toxicology Toxicology is a scientific discipline, overlapping with biology, chemistry, pharmacology, and medicine, that involves the study of the adverse effects of chemical substances on living organisms and the practice of diagnosing and treating expo ...


Further reading

* * - translated into English by Ralph Oesper


References

{{DEFAULTSORT:Stas, Jean 1813 births 1891 deaths Belgian chemists Scientists from Leuven Foreign Members of the Royal Society Foreign associates of the National Academy of Sciences Belgian toxicologists Academic staff of Royal Military Academy (Belgium)