James Franklin Hyde
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James Franklin Hyde (born 11 March 1903) was an American chemist and inventor. He has been called the “Father of Silicones” and is credited with the launch of the
silicone A silicone or polysiloxane is a polymer made up of siloxane (−R2Si−O−SiR2−, where R = organic group). They are typically colorless oils or rubber-like substances. Silicones are used in sealants, adhesives, lubricants, medicine, cooking ...
industry in the 1930s. His most notable contributions include his creation of silicone from silicon compounds and his method of making
fused silica Fused quartz, fused silica or quartz glass is a glass consisting of almost pure silica (silicon dioxide, SiO2) in amorphous (non-crystalline) form. This differs from all other commercial glasses in which other ingredients are added which change ...
, a high-quality glass later used in aeronautics, advanced telecommunications, and computer chips. His work led to the formation of
Dow Corning Dow Corning Corporation, was an American multinational corporation headquartered in Midland, Michigan, United States. Originally established as a joint venture between The Dow Chemical Company and Corning Incorporated, Dow bought out Corning and ...
, an alliance between the
Dow Chemical Company The Dow Chemical Company, officially Dow Inc., is an American multinational chemical corporation headquartered in Midland, Michigan, United States. The company is among the three largest chemical producers in the world. Dow manufactures plastic ...
and
Corning Glass Works Corning Incorporated is an American multinational technology company that specializes in specialty glass, ceramics, and related materials and technologies including advanced optics, primarily for industrial and scientific applications. The co ...
that was specifically created to produce silicone products.


Life


Early years and education

James Franklin Hyde was born in
Solvay, New York Solvay is a village located in the town of Geddes, Onondaga County, New York, United States, and a suburb of the city of Syracuse. According to the 2010 census, the village had a total population of 6,584. The village is named after the Solvay ...
on March 11, 1903. He attended Solvay High School and graduated on June 25, 1919, at the age of 16. He was partly encouraged by one of his science teachers to enter into the field of science. After high school, Hyde attended
Syracuse University Syracuse University (informally 'Cuse or SU) is a Private university, private research university in Syracuse, New York. Established in 1870 with roots in the Methodist Episcopal Church, the university has been nonsectarian since 1920. Locate ...
, where he earned both his
Bachelor of Arts Bachelor of arts (BA or AB; from the Latin ', ', or ') is a bachelor's degree awarded for an undergraduate program in the arts, or, in some cases, other disciplines. A Bachelor of Arts degree course is generally completed in three or four years ...
and
Master of Arts A Master of Arts ( la, Magister Artium or ''Artium Magister''; abbreviated MA, M.A., AM, or A.M.) is the holder of a master's degree awarded by universities in many countries. The degree is usually contrasted with that of Master of Science. Tho ...
degrees. Afterwards, he earned a Ph.D. in
organic chemistry Organic chemistry is a subdiscipline within chemistry involving the scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms that contain carbon atoms.Clayden, J.; ...
at the
University of Illinois The University of Illinois Urbana-Champaign (U of I, Illinois, University of Illinois, or UIUC) is a public land-grant research university in Illinois in the twin cities of Champaign and Urbana. It is the flagship institution of the University ...
. He then completed his academic education at
Harvard University Harvard University is a private Ivy League research university in Cambridge, Massachusetts. Founded in 1636 as Harvard College and named for its first benefactor, the Puritan clergyman John Harvard, it is the oldest institution of higher le ...
, where he was granted a post-doctoral fellowship under Dr. James Bryant Conant. He also received an Honorary Doctor of Science degree from Syracuse University.


Research

In 1931, Hyde became the first organic chemist to accept a position at Corning Glass Works (now
Corning Incorporated Corning Incorporated is an American multinational technology company that specializes in specialty glass, ceramics, and related materials and technologies including advanced optics, primarily for industrial and scientific applications. The co ...
). He was hired to investigate the new plastics that challenged the glass industry. Hyde had studied Kipping and Ladenburg's work in the field of organic silicon chemistry and sought to find a flexible, high temperature binder for the
glass fiber Glass fiber ( or glass fibre) is a material consisting of numerous extremely fine fibers of glass. Glassmakers throughout history have experimented with glass fibers, but mass manufacture of glass fiber was only made possible with the inventio ...
s that would allow for an increase in service temperature for insulating materials. He followed Kipping's procedure for creating organic silicon compounds by using Grignard's magnesium-containing reagent and eventually synthesized a fluid that hardened to a rubbery mass. This new composite was one of the first Class H insulators and made it possible for Corning to produce high temperature motors and generators. This silicone was used in ships and planes during World War II, as cable and wire insulation, in aeronautical equipment, and in window insulation. Future versions of this silicone would be used in breast implants and in prosthetic heart valves. In 1934, Hyde used a method called “flame hydrolysis” to create fused silica, an impurity-free glass. This method involved heating silicon and oxygen by running
silicon tetrachloride Silicon tetrachloride or tetrachlorosilane is the inorganic compound with the formula SiCl4. It is a colourless volatile liquid that fumes in air. It is used to produce high purity silicon and silica for commercial applications. Preparation Silic ...
gas through an oxygen flame. The result was a fine, glassy powder of
silicon dioxide Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
, which could be pressed into various shapes. Hyde's method proved to be a breakthrough in glass production. Fused silica was initially used in mirrors, telescopes, radar, and later in spacecraft windows and
fiber optics An optical fiber, or optical fibre in Commonwealth English, is a flexible, transparent fiber made by drawing glass (silica) or plastic to a diameter slightly thicker than that of a human hair. Optical fibers are used most often as a means to ...
. Corning researchers used this fused silica when they invented optical fiber in 1970, which provided faster transmission speeds than copper wires did. Fused silica has also made the miniaturization of
computer chips An integrated circuit or monolithic integrated circuit (also referred to as an IC, a chip, or a microchip) is a set of electronic circuits on one small flat piece (or "chip") of semiconductor material, usually silicon. Large numbers of tiny M ...
possible, as it is used in high transmission microlithographic lenses. Decades later, Hyde remarked that “
e was E, or e, is the fifth letter and the second vowel letter in the Latin alphabet, used in the modern English alphabet, the alphabets of other western European languages and others worldwide. Its name in English is ''e'' (pronounced ); plu ...
surprised at some of the things used silicahas gone into, but
e was E, or e, is the fifth letter and the second vowel letter in the Latin alphabet, used in the modern English alphabet, the alphabets of other western European languages and others worldwide. Its name in English is ''e'' (pronounced ); plu ...
not surprised at the versatility of such a beautiful and useful material.” He claims that his inspiration for developing his fused silica was the telescope that was being built at the
Palomar Observatory Palomar Observatory is an astronomical research observatory in San Diego County, California, United States, in the Palomar Mountain Range. It is owned and operated by the California Institute of Technology (Caltech). Research time at the observat ...
in California. However, he was too late to influence this telescope project, which was built by Corning using
Pyrex Pyrex (trademarked as ''PYREX'' and ''pyrex'') is a brand introduced by Corning Inc. in 1915 for a line of clear, low-thermal-expansion borosilicate glass used for laboratory glassware and kitchenware. It was later expanded to include kitchenw ...
, a glass it developed in 1915. On August 27, 1934, Hyde filed a patent application with the United States Patent Office for “ ismethod of making a transparent article of silica.” This patent was granted to him on February 10, 1942. Hyde's work led to the formation of the Dow Corning Corporation in 1943, a joint venture by Corning Glass Works and the Dow Chemical Company to produce silicone products. Dr. William Armistead, former vice chairman for technology at Corning Glass Works, not only recognizes Hyde as “the father of silicones,” but also calls him “the father of Dow Corning.” The Dow Corning Corporation now operates in more than 20 nations around the world, with $4.94 billion in revenue in 2007. In 1951, Hyde was appointed the position of senior research scientist for basic organosilicon chemistry at Dow Corning. He had previously held the position of manager of the Organic Chemistry Research Laboratory at Corning from 1938 until 1951.


Later years

In 1973, Hyde retired but continued to serve Dow Corning as a research consultant. In 1976, he published in the student magazine ''Chemistry'' an alternative periodic table of his own design, which allots a central position to the element silicon. Since 1992, the J. Franklin Hyde Scholarship in Science Education has been awarded annually by Dow Corning and the Dow Corning Foundation to outstanding students who plan to teach science at the secondary level. In 2000, Hyde was nominated by Corning Incorporated and inducted into the
National Inventors Hall of Fame The National Inventors Hall of Fame (NIHF) is an American not-for-profit organization, founded in 1973, which recognizes individual engineers and inventors who hold a U.S. patent of significant technology. Besides the Hall of Fame, it also opera ...
. He was also inducted into the Plastics Hall of Fame in 1979. For the remainder of his days, Hyde lived alone on
Marco Island, Florida Marco Island is a small sea island, or barrier island, on the Gulf Coast of the United States located 20 miles (32 km) south of Naples in Collier County, Florida. Marco Island is an affluent beach and boating resort island with a small-town ...
. His three children visited him regularly. He is proud of his accomplishments during his career and says that “it gives ima great satisfaction that edid something useful in life.” Dr. James Franklin Hyde died in his Florida home on October 11, 1999, at the age of 96, with over 100 patents held in his name while at Corning Incorporated.


Personal life

In 1930, James Franklin Hyde was married to his wife Hildegard. He has three children: James F. Hyde, Ann H. Hyde, and Sylvia Hyde Schuster. Hyde's wife Hildegard died in 1991. He said to the New York Times: “When you lose someone close to you like that, you never really get over it.”


Patents

* Hyde, , "''Method of making a transparent article of silica''"


Notes


References

*Goosey, Martin T. Plastics for Electronics. Coventry: Springer, 1999. Page 26.
Highlights from the history of Dow Corning Corporation, the silicone pioneer Dow Corning Silicones




* Peterson, Julie K. Fiber Optics Illustrated Dictionary. Florida: CRC Press, 2002.
A Future Full of Light

Inventors Hall brings energy to Akron


External links

*“J. Franklin Hyde, 96, the ‘Father of Silicones’.” New York Times. https://query.nytimes.com/gst/fullpage.html?res=9D06E1D91E30F935A25753C1A96F958260 *“Highlights from the history of Dow Corning Corporation, the silicone pioneer.” http://www.dowcorning.com/content/publishedlit/01-4027-01.pdf *“A Future Full of Light.” IEEE Journal. http://ieeexplore.ieee.org/stamp/stamp.jsp?arnumber=00902175 {{DEFAULTSORT:Hyde, James Franklin 1903 births 1999 deaths 20th-century American chemists Syracuse University alumni University of Illinois alumni People from Solvay, New York People from Marco Island, Florida 20th-century American inventors Scientists from New York (state) Harvard University alumni