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Industrial wastewater treatment describes the processes used for treating wastewater that is produced by industries as an undesirable by-product. After treatment, the treated industrial wastewater (or effluent) may be reused or released to a sanitary sewer or to a
surface water Surface water is water located on top of land forming terrestrial (inland) waterbodies, and may also be referred to as ''blue water'', opposed to the seawater and waterbodies like the ocean. The vast majority of surface water is produced by pre ...
in the environment. Some industrial facilities generate wastewater that can be treated in
sewage treatment plants Sewage treatment (or domestic wastewater treatment, municipal wastewater treatment) is a type of wastewater treatment which aims to remove contaminants from sewage to produce an effluent that is suitable for discharge to the surrounding en ...
. Most industrial processes, such as petroleum refineries, chemical and
petrochemical Petrochemicals (sometimes abbreviated as petchems) are the chemical products obtained from petroleum by refining. Some chemical compounds made from petroleum are also obtained from other fossil fuels, such as coal or natural gas, or renewabl ...
plants have their own specialized facilities to treat their wastewaters so that the pollutant concentrations in the treated wastewater comply with the regulations regarding disposal of wastewaters into sewers or into rivers, lakes or
ocean The ocean (also the sea or the world ocean) is the body of salt water that covers approximately 70.8% of the surface of Earth and contains 97% of Earth's water. An ocean can also refer to any of the large bodies of water into which the wor ...
s. This applies to industries that generate wastewater with high concentrations of organic matter (e.g. oil and grease), toxic pollutants (e.g. heavy metals, volatile organic compounds) or nutrients such as
ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous ...
. Some industries install a pre-treatment system to remove some pollutants (e.g., toxic compounds), and then discharge the partially treated wastewater to the municipal sewer system. Most industries produce some wastewater. Recent trends have been to minimize such production or to recycle treated wastewater within the production process. Some industries have been successful at redesigning their manufacturing processes to reduce or eliminate pollutants. Sources of industrial wastewater include battery manufacturing, chemical manufacturing, electric power plants,
food industry The food industry is a complex, global network of diverse businesses that supplies most of the food consumed by the world's population. The food industry today has become highly diversified, with manufacturing ranging from small, traditional, ...
, iron and steel industry, metal working, mines and quarries, nuclear industry, oil and gas extraction, petroleum refining and petrochemicals, pharmaceutical manufacturing,
pulp and paper industry The pulp and paper industry comprises companies that use wood as raw material and produce Pulp (paper), pulp, paper, paperboard and other cellulose-based products. Manufacturing process The pulp is fed to a paper machine where it is formed as ...
, smelters,
textile mill Textile Manufacturing or Textile Engineering is a major industry. It is largely based on the conversion of fibre into yarn, then yarn into fabric. These are then dyed or printed, fabricated into cloth which is then converted into useful goods ...
s, industrial oil contamination, water treatment and wood preserving. Treatment processes include brine treatment, solids removal (e.g. chemical precipitation, filtration), oils and grease removal, removal of biodegradable organics, removal of other organics, removal of acids and alkalis, and removal of toxic materials.


Types

Industrial facilities may generate the following industrial wastewater flows: * Manufacturing process wastestreams, which can include
conventional pollutant A conventional pollutant is a term used in the USA to describe a water pollutant that is amenable to treatment by a municipal sewage treatment plant. A basic list of conventional pollutants is defined in the U.S. Clean Water Act. The list has been ...
s (i.e. controllable with secondary treatment systems),
toxic Toxicity is the degree to which a chemical substance or a particular mixture of substances can damage an organism. Toxicity can refer to the effect on a whole organism, such as an animal, bacterium, or plant, as well as the effect on a sub ...
pollutants (e.g. solvents, heavy metals), and other harmful compounds such as
nutrients A nutrient is a substance used by an organism to survive, grow, and reproduce. The requirement for dietary nutrient intake applies to animals, plants, fungi, and protists. Nutrients can be incorporated into cells for metabolic purposes or excr ...
* Non-process wastestreams:
boiler blowdown Boiler blowdown is water intentionally wasted from a boiler to avoid concentration of impurities during continuing evaporation of steam. The water is blown out of the boiler with some force by steam pressure within the boiler. Bottom blowdown used ...
and
cooling water Cooling tower and water discharge of a nuclear power plant Water cooling is a method of heat removal from components and industrial equipment. Evaporative cooling using water is often more efficient than air cooling. Water is inexpensive and ...
, which produce
thermal pollution Thermal pollution, sometimes called "thermal enrichment", is the degradation of water quality by any process that changes ambient water temperature. Thermal pollution is the rise or fall in the temperature of a natural body of water caused by hum ...
and other pollutants * Industrial site drainage, generated both by manufacturing facilities, service industries and energy and mining sites * Wastestreams from the energy and mining sectors: acid mine drainage,
produced water Produced water is a term used in the oil industry or geothermal industry to describe water that is produced as a byproduct during the extraction of oil and natural gas, or used as a medium for heat extraction. Produced water is the kind of brackis ...
from oil and gas extraction,
radionuclide A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess nuclear energy, making it unstable. This excess energy can be used in one of three ways: emitted from the nucleus as gamma radiation; transfer ...
s * Wastestreams that are by-products of treatment or cooling processes:
backwashing (water treatment) In terms of water treatment, including water purification and sewage treatment, backwashing refers to pumping water backwards through the filters media, sometimes including intermittent use of compressed air during the process. Backwashing i ...
, brine.


Contaminants


Industrial sectors

The specific pollutants generated and the resultant effluent concentrations can vary widely among the industrial sectors.


Battery manufacturing

Battery Battery most often refers to: * Electric battery, a device that provides electrical power * Battery (crime), a crime involving unlawful physical contact Battery may also refer to: Energy source *Automotive battery, a device to provide power t ...
manufacturers specialize in fabricating small devices for electronics and portable equipment (e.g., power tools), or larger, high-powered units for cars, trucks and other motorized vehicles. Pollutants generated at manufacturing plants includes cadmium, chromium, cobalt, copper, cyanide, iron, lead, manganese, mercury, nickel, silver, zinc, oil and grease.


Centralized waste treatment

A centralized waste treatment (CWT) facility processes liquid or solid industrial wastes generated by off-site manufacturing facilities. A manufacturer may send its wastes to a CWT plant, rather than perform treatment on site, due to constraints such as limited land availability, difficulty in designing and operating an on-site system, or limitations imposed by environmental regulations and permits. A manufacturer may determine that using a CWT is more cost-effective than treating the waste itself; this is often the case where the manufacturer is a small business. CWT plants often receive wastes from a wide variety of manufacturers, including chemical plants, metal fabrication and finishing; and used oil and petroleum products from various manufacturing sectors. The wastes may be classified as hazardous, have high pollutant concentrations or otherwise be difficult to treat. In 2000 the U.S. Environmental Protection Agency published wastewater regulations for CWT facilities in the US.


Chemical manufacturing


Organic chemicals manufacturing

The specific pollutants discharged by organic chemical manufacturers vary widely from plant to plant, depending on the types of products manufactured, such as bulk organic chemicals, resins, pesticides, plastics, or synthetic fibers. Some of the organic compounds that may be discharged are
benzene Benzene is an organic chemical compound with the molecular formula C6H6. The benzene molecule is composed of six carbon atoms joined in a planar ring with one hydrogen atom attached to each. Because it contains only carbon and hydrogen atoms ...
,
chloroform Chloroform, or trichloromethane, is an organic compound with formula C H Cl3 and a common organic solvent. It is a colorless, strong-smelling, dense liquid produced on a large scale as a precursor to PTFE. It is also a precursor to various ...
,
naphthalene Naphthalene is an organic compound with formula . It is the simplest polycyclic aromatic hydrocarbon, and is a white crystalline solid with a characteristic odor that is detectable at concentrations as low as 0.08  ppm by mass. As an aromat ...
,
phenol Phenol (also called carbolic acid) is an aromatic organic compound with the molecular formula . It is a white crystalline solid that is volatile. The molecule consists of a phenyl group () bonded to a hydroxy group (). Mildly acidic, it r ...
s,
toluene Toluene (), also known as toluol (), is a substituted aromatic hydrocarbon. It is a colorless, water-insoluble liquid with the smell associated with paint thinners. It is a mono-substituted benzene derivative, consisting of a methyl group (CH3) ...
and
vinyl chloride Vinyl chloride is an organochloride with the formula H2C=CHCl. It is also called vinyl chloride monomer (VCM) or chloroethene. This colorless compound is an important industrial chemical chiefly used to produce the polymer polyvinyl chloride (PVC ...
. Biochemical oxygen demand (BOD), which is a gross measurement of a range of organic pollutants, may be used to gauge the effectiveness of a biological wastewater treatment system, and is used as a regulatory parameter in some discharge permits. Metal pollutant discharges may include
chromium Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal. Chromium metal is valued for its high corrosion resistance and hard ...
,
copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pink ...
,
lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, ...
,
nickel Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive but large pieces are slow t ...
and
zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
.


Inorganic chemicals manufacturing

The
inorganic chemicals In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemi ...
sector covers a wide variety of products and processes, although an individual plant may produce a narrow range of products and pollutants. Products include aluminum compounds; calcium carbide and calcium chloride; hydrofluoric acid; potassium compounds; borax; chrome and fluorine-based compounds; cadmium and zinc-based compounds. The pollutants discharged vary by product sector and individual plant, and may include arsenic, chlorine, cyanide, fluoride; and heavy metals such as chromium, copper, iron, lead, mercury, nickel and zinc.


Electric power plants

Fossil-fuel power stations, particularly
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when ...
-fired plants, are a major source of industrial wastewater. Many of these plants discharge wastewater with significant levels of metals such as
lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, ...
, mercury,
cadmium Cadmium is a chemical element with the Symbol (chemistry), symbol Cd and atomic number 48. This soft, silvery-white metal is chemically similar to the two other stable metals in group 12 element, group 12, zinc and mercury (element), mercury. Li ...
and
chromium Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal. Chromium metal is valued for its high corrosion resistance and hard ...
, as well as
arsenic Arsenic is a chemical element with the symbol As and atomic number 33. Arsenic occurs in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Arsenic is a metalloid. It has various allotropes, b ...
, selenium and
nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...
compounds (
nitrate Nitrate is a polyatomic ion with the chemical formula . Salts containing this ion are called nitrates. Nitrates are common components of fertilizers and explosives. Almost all inorganic nitrates are soluble in water. An example of an insolu ...
s and
nitrite The nitrite ion has the chemical formula . Nitrite (mostly sodium nitrite) is widely used throughout chemical and pharmaceutical industries. The nitrite anion is a pervasive intermediate in the nitrogen cycle in nature. The name nitrite also ...
s). Wastewater streams include
flue-gas desulfurization Flue-gas desulfurization (FGD) is a set of technologies used to remove sulfur dioxide () from exhaust flue gases of fossil-fuel power plants, and from the emissions of other sulfur oxide emitting processes such as waste incineration. Methods ...
,
fly ash Fly ash, flue ash, coal ash, or pulverised fuel ash (in the UK) plurale tantum: coal combustion residuals (CCRs)is a coal combustion product that is composed of the particulates (fine particles of burned fuel) that are driven out of coal-fired ...
,
bottom ash Bottom ash is part of the non- combustible residue of combustion in a power plant, boiler, furnace or incinerator. In an industrial context, it has traditionally referred to coal combustion and comprises traces of combustibles embedded in formi ...
and
flue gas Flue gas is the gas exiting to the atmosphere via a flue, which is a pipe or channel for conveying exhaust gases from a fireplace, oven, furnace, boiler or steam generator. Quite often, the flue gas refers to the combustion exhaust gas produc ...
mercury control. Plants with air pollution controls such as wet scrubbers typically transfer the captured pollutants to the wastewater stream. Ash ponds, a type of surface impoundment, are a widely used treatment technology at coal-fired plants. These ponds use gravity to settle out large particulates (measured as total suspended solids) from power plant wastewater. This technology does not treat dissolved pollutants. Power stations use additional technologies to control pollutants, depending on the particular wastestream in the plant. These include dry ash handling, closed-loop ash recycling, chemical precipitation, biological treatment (such as an activated sludge process), membrane systems, and evaporation-crystallization systems. Technological advancements in ion-exchange membranes and electrodialysis systems has enabled high efficiency treatment of
flue-gas desulfurization Flue-gas desulfurization (FGD) is a set of technologies used to remove sulfur dioxide () from exhaust flue gases of fossil-fuel power plants, and from the emissions of other sulfur oxide emitting processes such as waste incineration. Methods ...
wastewater to meet recent EPA discharge limits. The treatment approach is similar for other highly scaling industrial wastewaters.


Food industry

Wastewater generated from agricultural and
food processing Food processing is the transformation of agricultural products into food, or of one form of food into other forms. Food processing includes many forms of processing foods, from grinding grain to make raw flour to home cooking to complex in ...
operations has distinctive characteristics that set it apart from common municipal wastewater managed by public or private
sewage treatment Sewage treatment (or domestic wastewater treatment, municipal wastewater treatment) is a type of wastewater treatment which aims to remove contaminants from sewage to produce an effluent that is suitable for discharge to the surrounding en ...
plants throughout the world: it is
biodegradable Biodegradation is the breakdown of organic matter by microorganisms, such as bacteria and fungi. It is generally assumed to be a natural process, which differentiates it from composting. Composting is a human-driven process in which biodegrada ...
and non-toxic, but has high Biological Oxygen Demand (BOD) and
suspended solids Suspended solids refers to small solid particles which remain in suspension in water as a colloid or due to motion of the water. Suspended solids can be removed by sedimentation if their size or density is comparatively large, or by filtration. ...
(SS). The constituents of food and agriculture wastewater are often complex to predict, due to the differences in BOD and pH in effluents from vegetable, fruit, and meat products and due to the seasonal nature of food processing and post-harvesting. Processing of food from raw materials requires large volumes of high grade water. Vegetable washing generates waters with high loads of particulate matter and some dissolved
organic matter Organic matter, organic material, or natural organic matter refers to the large source of carbon-based compounds found within natural and engineered, terrestrial, and aquatic environments. It is matter composed of organic compounds that have c ...
. It may also contain surfactants and pesticides.
Aquaculture Aquaculture (less commonly spelled aquiculture), also known as aquafarming, is the controlled cultivation ("farming") of aquatic organisms such as fish, crustaceans, mollusks, algae and other organisms of value such as aquatic plants (e.g. lot ...
facilities (fish farms) often discharge large amounts of nitrogen and phosphorus, as well as suspended solids. Some facilities use drugs and pesticides, which may be present in the wastewater. Dairy processing plants generate
conventional pollutant A conventional pollutant is a term used in the USA to describe a water pollutant that is amenable to treatment by a municipal sewage treatment plant. A basic list of conventional pollutants is defined in the U.S. Clean Water Act. The list has been ...
s (BOD, SS). Animal slaughter and processing produces organic waste from body fluids, such as
blood Blood is a body fluid in the circulatory system of humans and other vertebrates that delivers necessary substances such as nutrients and oxygen to the cells, and transports metabolic waste products away from those same cells. Blood in the cir ...
, and gut contents. Pollutants generated include BOD, SS, coliform bacteria, oil and grease,
organic nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at seven ...
and
ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous ...
. Processing food for sale produces wastes generated from cooking which are often rich in plant organic material and may also contain
salt Salt is a mineral composed primarily of sodium chloride (NaCl), a chemical compound belonging to the larger class of salts; salt in the form of a natural crystalline mineral is known as rock salt or halite. Salt is present in vast quant ...
,
flavouring A flavoring (or flavouring), also known as flavor (or flavour) or flavorant, is a food additive used to improve the taste or smell of food. It changes the perceptual impression of food as determined primarily by the chemoreceptors of the gus ...
s, colouring material and
acid In computer science, ACID ( atomicity, consistency, isolation, durability) is a set of properties of database transactions intended to guarantee data validity despite errors, power failures, and other mishaps. In the context of databases, a se ...
s or
alkali In chemistry, an alkali (; from ar, القلوي, al-qaly, lit=ashes of the saltwort) is a basic, ionic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a ...
. Large quantities of fats, oil and grease ("FOG") may also be present, which in sufficient concentrations can clog sewer lines. Some municipalities require restaurants and food processing businesses to use
grease interceptor A grease trap (also known as grease interceptor, grease recovery device, grease capsule and grease converter) is a plumbing device (a type of trap) designed to intercept most greases and solids before they enter a wastewater disposal system. C ...
s and regulate the disposal of FOG in the sewer system. Food processing activities such as plant cleaning, material conveying, bottling, and product washing create wastewater. Many food processing facilities require on-site treatment before operational wastewater can be land applied or discharged to a waterway or a sewer system. High suspended solids levels of organic particles increase BOD and can result in significant sewer surcharge fees. Sedimentation, wedgewire screening, or rotating belt filtration (microscreening) are commonly used methods to reduce suspended organic solids loading prior to discharge.


Iron and steel industry

The production of iron from its ores involves powerful reduction reactions in blast furnaces. Cooling waters are inevitably contaminated with products especially
ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous ...
and
cyanide Cyanide is a naturally occurring, rapidly acting, toxic chemical that can exist in many different forms. In chemistry, a cyanide () is a chemical compound that contains a functional group. This group, known as the cyano group, consists of ...
. Production of coke from coal in coking plants also requires water cooling and the use of water in by-products separation. Contamination of waste streams includes gasification products such as
benzene Benzene is an organic chemical compound with the molecular formula C6H6. The benzene molecule is composed of six carbon atoms joined in a planar ring with one hydrogen atom attached to each. Because it contains only carbon and hydrogen atoms ...
,
naphthalene Naphthalene is an organic compound with formula . It is the simplest polycyclic aromatic hydrocarbon, and is a white crystalline solid with a characteristic odor that is detectable at concentrations as low as 0.08  ppm by mass. As an aromat ...
,
anthracene Anthracene is a solid polycyclic aromatic hydrocarbon (PAH) of formula C14H10, consisting of three fused benzene rings. It is a component of coal tar. Anthracene is used in the production of the red dye alizarin and other dyes. Anthracene is co ...
, cyanide, ammonia,
phenol Phenol (also called carbolic acid) is an aromatic organic compound with the molecular formula . It is a white crystalline solid that is volatile. The molecule consists of a phenyl group () bonded to a hydroxy group (). Mildly acidic, it r ...
s,
cresol Cresols (also hydroxytoluene or cresylic acid) are a group of aromatic organic compounds. They are widely-occurring phenols (sometimes called ''phenolics'') which may be either natural or manufactured. They are also categorized as methylphenol ...
s together with a range of more complex
organic compound In chemistry, organic compounds are generally any chemical compounds that contain carbon-hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. Th ...
s known collectively as polycyclic aromatic hydrocarbons (PAH). The conversion of iron or steel into sheet, wire or rods requires hot and cold mechanical transformation stages frequently employing water as a lubricant and coolant. Contaminants include hydraulic oils,
tallow Tallow is a rendered form of beef or mutton fat, primarily made up of triglycerides. In industry, tallow is not strictly defined as beef or mutton fat. In this context, tallow is animal fat that conforms to certain technical criteria, includ ...
and particulate solids. Final treatment of iron and steel products before onward sale into manufacturing includes ''pickling'' in strong mineral acid to remove rust and prepare the surface for tin or
chromium Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal. Chromium metal is valued for its high corrosion resistance and hard ...
plating or for other surface treatments such as galvanisation or painting. The two acids commonly used are
hydrochloric acid Hydrochloric acid, also known as muriatic acid, is an aqueous solution of hydrogen chloride. It is a colorless solution with a distinctive pungent smell. It is classified as a strong acid. It is a component of the gastric acid in the dige ...
and
sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid ( Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen and hydrogen, with the molecular fo ...
. Wastewaters include acidic rinse waters together with waste acid. Although many plants operate acid recovery plants (particularly those using hydrochloric acid), where the mineral acid is boiled away from the iron salts, there remains a large volume of highly acid ferrous sulfate or ferrous chloride to be disposed of. Many steel industry wastewaters are contaminated by hydraulic oil, also known as ''soluble oil.''


Metal working

Many industries perform work on metal feedstocks (e.g. sheet metal, ingots) as they fabricate their final products. The industries include automobile, truck and aircraft manufacturing; tools and hardware manufacturing; electronic equipment and office machines; ships and boats; appliances and other household products; and stationary industrial equipment (e.g. compressors, pumps, boilers). Typical processes conducted at these plants include grinding, machining,
coating A coating is a covering that is applied to the surface of an object, usually referred to as the substrate. The purpose of applying the coating may be decorative, functional, or both. Coatings may be applied as liquids, gases or solids e.g. Pow ...
and painting, chemical etching and milling,
solvent degreasing Solvent degreasing is a process used to prepare a part for further operations such as electroplating or painting. Typically it uses petroleum, chlorine, dry ice or alcohol based solvents to dissolve the machining fluids and other contaminants that ...
,
electroplating Electroplating, also known as electrochemical deposition or electrodeposition, is a process for producing a metal coating on a solid substrate through the reduction of cations of that metal by means of a direct electric current. The part to be ...
and anodizing. Wastewater generated from these industries may contain heavy metals such as cadmium, chromium, copper, lead, nickel, silver and zinc; cyanide and various organic chemical solvents; and oil and grease.


Mines and quarries

The principal waste-waters associated with mines and quarries are slurries of rock particles in water. These arise from rainfall washing exposed surfaces and haul roads and also from rock washing and grading processes. Volumes of water can be very high, especially rainfall related arisings on large sites. Some specialized separation operations, such as
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when ...
washing to separate coal from native rock using density gradients, can produce wastewater contaminated by fine particulate
haematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . I ...
and surfactants. Oils and hydraulic oils are also common contaminants. Wastewater from metal mines and ore recovery plants are inevitably contaminated by the minerals present in the native rock formations. Following crushing and extraction of the desirable materials, undesirable materials may enter the wastewater stream. For metal mines, this can include unwanted metals such as
zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
and other materials such as
arsenic Arsenic is a chemical element with the symbol As and atomic number 33. Arsenic occurs in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Arsenic is a metalloid. It has various allotropes, b ...
. Extraction of high value metals such as
gold Gold is a chemical element with the symbol Au (from la, aurum) and atomic number 79. This makes it one of the higher atomic number elements that occur naturally. It is a bright, slightly orange-yellow, dense, soft, malleable, and ductile ...
and
silver Silver is a chemical element with the symbol Ag (from the Latin ', derived from the Proto-Indo-European ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, white, lustrous transition metal, it exhibits the highest electrical ...
may generate slimes containing very fine particles in where physical removal of contaminants becomes particularly difficult. Additionally, the geologic formations that harbour economically valuable metals such as
copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pink ...
and gold very often consist of sulphide-type ores. The processing entails grinding the rock into fine particles and then extracting the desired metal(s), with the leftover rock being known as tailings. These tailings contain a combination of not only undesirable leftover metals, but also sulphide components which eventually form sulphuric acid upon the exposure to air and water that inevitably occurs when the tailings are disposed of in large impoundments. The resulting acid mine drainage, which is often rich in heavy metals (because acids dissolve metals), is one of the many environmental impacts of mining.


Nuclear industry

The waste production from the nuclear and radio-chemicals industry is dealt with as ''
Radioactive waste Radioactive waste is a type of hazardous waste that contains radioactive material. Radioactive waste is a result of many activities, including nuclear medicine, nuclear research, nuclear power generation, rare-earth mining, and nuclear weapon ...
.'' Researchers have looked at the bioaccumulation of
strontium Strontium is the chemical element with the symbol Sr and atomic number 38. An alkaline earth metal, strontium is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is e ...
by '' Scenedesmus spinosus'' (
algae Algae (; singular alga ) is an informal term for a large and diverse group of photosynthetic eukaryotic organisms. It is a polyphyletic grouping that includes species from multiple distinct clades. Included organisms range from unicellular micr ...
) in simulated wastewater. The study claims a highly selective biosorption capacity for strontium of S. spinosus, suggesting that it may be appropriate for use of nuclear wastewater.


Oil and gas extraction

Oil and gas well operations generate
produced water Produced water is a term used in the oil industry or geothermal industry to describe water that is produced as a byproduct during the extraction of oil and natural gas, or used as a medium for heat extraction. Produced water is the kind of brackis ...
, which may contain oils, toxic metals (e.g.
arsenic Arsenic is a chemical element with the symbol As and atomic number 33. Arsenic occurs in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Arsenic is a metalloid. It has various allotropes, b ...
,
cadmium Cadmium is a chemical element with the Symbol (chemistry), symbol Cd and atomic number 48. This soft, silvery-white metal is chemically similar to the two other stable metals in group 12 element, group 12, zinc and mercury (element), mercury. Li ...
,
chromium Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal. Chromium metal is valued for its high corrosion resistance and hard ...
, mercury, lead), salts, organic chemicals and solids. Some produced water contains traces of naturally occurring radioactive material.
Offshore oil Offshore drilling is a mechanical process where a wellbore is drilled below the seabed. It is typically carried out in order to explore for and subsequently extract petroleum that lies in rock formations beneath the seabed. Most commonly, the te ...
and gas platforms also generate deck drainage, domestic waste and sanitary waste. During the drilling process, well sites typically discharge
drill cuttings Drill cuttings are broken bits of solid material removed from a borehole drilled by rotary, percussion, or auger methods and brought to the surface in the drilling mud. Boreholes drilled in this way include oil or gas wells, water wells, an ...
and
drilling mud In geotechnical engineering, drilling fluid, also called drilling mud, is used to aid the drilling of boreholes into the earth. Often used while drilling oil and natural gas wells and on exploration drilling rigs, drilling fluids are als ...
(drilling fluid).


Petroleum refining and petrochemicals

Pollutants discharged at petroleum refineries and
petrochemical Petrochemicals (sometimes abbreviated as petchems) are the chemical products obtained from petroleum by refining. Some chemical compounds made from petroleum are also obtained from other fossil fuels, such as coal or natural gas, or renewabl ...
plants include
conventional pollutant A conventional pollutant is a term used in the USA to describe a water pollutant that is amenable to treatment by a municipal sewage treatment plant. A basic list of conventional pollutants is defined in the U.S. Clean Water Act. The list has been ...
s (BOD, oil and grease,
suspended solids Suspended solids refers to small solid particles which remain in suspension in water as a colloid or due to motion of the water. Suspended solids can be removed by sedimentation if their size or density is comparatively large, or by filtration. ...
), ammonia, chromium, phenols and sulfides.


Pharmaceutical manufacturing

Pharmaceutical plants typically generate a variety of process wastewaters, including solvents, spent acid and caustic solutions, water from chemical reactions, product wash water, condensed steam, blowdown from air pollution control scrubbers, and equipment washwater. Non-process wastewaters typically include cooling water and site runoff. Pollutants generated by the industry include
acetone Acetone (2-propanone or dimethyl ketone), is an organic compound with the formula . It is the simplest and smallest ketone (). It is a colorless, highly volatile and flammable liquid with a characteristic pungent odour. Acetone is miscibl ...
, ammonia, benzene, BOD, chloroform, cyanide,
ethanol Ethanol (abbr. EtOH; also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound. It is an alcohol with the chemical formula . Its formula can be also written as or (an ethyl group linked to a ...
, ethyl acetate,
isopropanol Isopropyl alcohol (IUPAC name propan-2-ol and also called isopropanol or 2-propanol) is a colorless, flammable organic compound with a pungent alcoholic odor. As an isopropyl group linked to a hydroxyl group (chemical formula ) it is the sim ...
, methylene chloride,
methanol Methanol (also called methyl alcohol and wood spirit, amongst other names) is an organic chemical and the simplest aliphatic alcohol, with the formula C H3 O H (a methyl group linked to a hydroxyl group, often abbreviated as MeOH). It is ...
, phenol and toluene. Treatment technologies used include advanced biological treatment (e.g. activated sludge with nitrification), multimedia filtration, cyanide destruction (e.g.
hydrolysis Hydrolysis (; ) is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution, elimination, and solvation reactions in which water is the nucleophile. Biological hydrolysi ...
), steam stripping and wastewater recycling.


Pulp and paper industry

Effluent from the
pulp and paper industry The pulp and paper industry comprises companies that use wood as raw material and produce Pulp (paper), pulp, paper, paperboard and other cellulose-based products. Manufacturing process The pulp is fed to a paper machine where it is formed as ...
is generally high in
suspended solids Suspended solids refers to small solid particles which remain in suspension in water as a colloid or due to motion of the water. Suspended solids can be removed by sedimentation if their size or density is comparatively large, or by filtration. ...
and BOD. Plants that bleach wood pulp for paper making may generate
chloroform Chloroform, or trichloromethane, is an organic compound with formula C H Cl3 and a common organic solvent. It is a colorless, strong-smelling, dense liquid produced on a large scale as a precursor to PTFE. It is also a precursor to various ...
, dioxins (including 2,3,7,8-TCDD), furans, phenols and chemical oxygen demand (COD). Stand-alone paper mills using imported pulp may only require simple primary treatment, such as sedimentation or dissolved air flotation. Increased BOD or COD loadings, as well as organic pollutants, may require biological treatment such as activated sludge or upflow anaerobic sludge blanket reactors. For mills with high inorganic loadings like salt, tertiary treatments may be required, either general membrane treatments like ultrafiltration or
reverse osmosis Reverse osmosis (RO) is a water purification process that uses a partially permeable membrane to separate ions, unwanted molecules and larger particles from drinking water. In reverse osmosis, an applied pressure is used to overcome osmotic ...
or treatments to remove specific contaminants, such as nutrients.


Smelters

The pollutants discharged by nonferrous smelters vary with the base metal ore.
Bauxite Bauxite is a sedimentary rock with a relatively high aluminium content. It is the world's main source of aluminium and gallium. Bauxite consists mostly of the aluminium minerals gibbsite (Al(OH)3), boehmite (γ-AlO(OH)) and diaspore (α-AlO ...
smelters generate phenols but typically use
settling basin A settling basin, settling pond or decant pond is an earthen or concrete structure using sedimentation to remove settleable matter and turbidity from wastewater. The basins are used to control water pollution in diverse industries such as agri ...
s and evaporation to manage these wastes, with no need to routinely discharge wastewater.
Aluminum Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It ha ...
smelters typically discharge
fluoride Fluoride (). According to this source, is a possible pronunciation in British English. is an inorganic, monatomic anion of fluorine, with the chemical formula (also written ), whose salts are typically white or colorless. Fluoride salts ty ...
,
benzo(a)pyrene Benzo 'a''yrene (B''a''P or B ) is a polycyclic aromatic hydrocarbon and the result of incomplete combustion of organic matter at temperatures between and . The ubiquitous compound can be found in coal tar, tobacco smoke and many foods, esp ...
,
antimony Antimony is a chemical element with the symbol Sb (from la, stibium) and atomic number 51. A lustrous gray metalloid, it is found in nature mainly as the sulfide mineral stibnite (Sb2S3). Antimony compounds have been known since ancient ti ...
and
nickel Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive but large pieces are slow t ...
, as well as aluminum. Copper smelters typically generate
cadmium Cadmium is a chemical element with the Symbol (chemistry), symbol Cd and atomic number 48. This soft, silvery-white metal is chemically similar to the two other stable metals in group 12 element, group 12, zinc and mercury (element), mercury. Li ...
, lead, zinc, arsenic and nickel, in addition to copper, in their wastewater. Lead smelters discharge lead and zinc. Nickel and cobalt smelters discharge ammonia and copper in addition to the base metals. Zinc smelters discharge arsenic, cadmium, copper, lead, selenium and zinc. Typical treatment processes used in the industry are chemical precipitation, sedimentation and filtration.


Textile mills

Textile mills, including
carpet A carpet is a textile floor covering typically consisting of an upper layer of pile attached to a backing. The pile was traditionally made from wool, but since the 20th century synthetic fibers such as polypropylene, nylon, or polyester ...
manufacturers, generate wastewater from a wide variety of processes, including
cleaning Cleaning is the process of removing unwanted substances, such as dirt, infectious agents, and other impurities, from an object or environment. Cleaning is often performed for aesthetic, hygienic, functional, environmental, or safety purposes. ...
and finishing,
yarn Yarn is a long continuous length of interlocked fibres, used in sewing, crocheting, knitting, weaving, embroidery, ropemaking, and the production of textiles. Thread is a type of yarn intended for sewing by hand or machine. Modern manu ...
manufacturing and fabric finishing (such as
bleaching Bleach is the generic name for any chemical product that is used industrially or domestically to remove color (whitening) from a fabric or fiber or to clean or to remove stains in a process called bleaching. It often refers specifically, to ...
, dyeing,
resin In polymer chemistry and materials science, resin is a solid or highly viscous substance of plant or synthetic origin that is typically convertible into polymers. Resins are usually mixtures of organic compounds. This article focuses on nat ...
treatment,
waterproofing Waterproofing is the process of making an object or structure waterproof or water-resistant so that it remains relatively unaffected by water or resisting the ingress of water under specified conditions. Such items may be used in wet environme ...
and retardant flameproofing). Pollutants generated by textile mills include BOD, SS, oil and grease, sulfide, phenols and chromium.
Insecticide Insecticides are substances used to kill insects. They include ovicides and larvicides used against insect eggs and larvae, respectively. Insecticides are used in agriculture, medicine, industry and by consumers. Insecticides are claimed t ...
residues in fleeces are a particular problem in treating waters generated in wool processing. Animal fats may be present in the wastewater, which if not contaminated, can be recovered for the production of tallow or further rendering. Textile dyeing plants generate wastewater that contain synthetic (e.g., reactive dyes, acid dyes, basic dyes, disperse dyes, vat dyes, sulphur dyes, mordant dyes, direct dyes, ingrain dyes, solvent dyes, pigment dyes) and natural dyestuff, gum thickener (guar) and various wetting agents, pH buffers and dye retardants or accelerators. Following treatment with polymer-based flocculants and settling agents, typical monitoring parameters include BOD, COD, color (ADMI), sulfide, oil and grease, phenol, TSS and heavy metals (chromium,
zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
, lead, copper).


Industrial oil contamination

Industrial applications where oil enters the wastewater stream may include vehicle wash bays, workshops, fuel storage depots, transport hubs and power generation. Often the wastewater is discharged into local sewer or trade waste systems and must meet local environmental specifications. Typical contaminants can include solvents, detergents, grit, lubricants and hydrocarbons.


Water treatment

Many industries have a need to treat water to obtain very high quality water for their processes. This might include pure chemical synthesis or boiler feed water. Also, some water treatment processes produce organic and mineral sludges from
filtration Filtration is a physical separation process that separates solid matter and fluid from a mixture using a ''filter medium'' that has a complex structure through which only the fluid can pass. Solid particles that cannot pass through the filter ...
and sedimentation which require treatment. Ion exchange using natural or synthetic resins removes
calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar ...
,
magnesium Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ...
and
carbonate A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate ...
ions from water, typically replacing them with
sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable ...
,
chloride The chloride ion is the anion (negatively charged ion) Cl−. It is formed when the element chlorine (a halogen) gains an electron or when a compound such as hydrogen chloride is dissolved in water or other polar solvents. Chloride s ...
,
hydroxyl In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical formula and composed of one oxygen atom covalently bonded to one hydrogen atom. In organic chemistry, alcohols and carboxylic acids contain one or more hydrox ...
and/or other ions. Regeneration of ion-exchange columns with strong acids and alkalis produces a wastewater rich in hardness ions which are readily precipitated out, especially when in admixture with other wastewater constituents.


Wood preserving

Wood preserving plants generate conventional and toxic pollutants, including arsenic, COD, copper, chromium, abnormally high or low pH, phenols, suspended solids, oil and grease.


Treatment methods

The various types of contamination of wastewater require a variety of strategies to remove the contamination. Most industrial processes, such as petroleum refineries, chemical and
petrochemical Petrochemicals (sometimes abbreviated as petchems) are the chemical products obtained from petroleum by refining. Some chemical compounds made from petroleum are also obtained from other fossil fuels, such as coal or natural gas, or renewabl ...
plants have onsite facilities to treat their wastewaters so that the pollutant concentrations in the treated wastewater comply with the regulations regarding disposal of wastewaters into sewers or into rivers, lakes or oceans. Constructed wetlands are being used in an increasing number of cases as they provided high quality and productive on-site treatment. Other industrial processes that produce a lot of waste-waters such as
paper and pulp production The pulp and paper industry comprises companies that use wood as raw material and produce pulp, paper, paperboard and other cellulose-based products. Manufacturing process The pulp is fed to a paper machine where it is formed as a paper web an ...
have created environmental concern, leading to development of processes to recycle water use within plants before they have to be cleaned and disposed. An industrial wastewater treatment plant may include one or more of the following rather than the conventional treatment sequence of sewage treatment plants: * An API oil-water separator, for removing separate phase oil from wastewater. * A
clarifier Clarifiers are settling tanks built with mechanical means for continuous removal of solids being deposited by sedimentation. A clarifier is generally used to remove solid particulates or suspended solids from liquid for clarification and/or thi ...
, for removing solids from wastewater.Kemmer, Frank N. (1979). ''The Nalco Water Handbook''. New York: McGraw-Hill Book Company. . * A roughing filter, to reduce the biochemical oxygen demand of wastewater. * A
carbon filtration Carbon filtering is a method of filtering that uses a bed of activated carbon to remove impurities from a fluid using adsorption. Mechanism Carbon filtering works by adsorption, in which pollutants in the fluid to be treated are trapped inside the ...
plant, to remove toxic dissolved organic compounds from wastewater. * An advanced
electrodialysis reversal Electrodialysis reversal (EDR) is an electrodialysis reversal water desalination membrane process that has been commercially used since the early 1960s. An electric current migrates dissolved salt ions, including fluorides, nitrates and sulfat ...
(EDR) system with ion-exchange membranes.


Brine treatment

Brine treatment involves removing dissolved salt ions from the waste stream. Although similarities to seawater or brackish water
desalination Desalination is a process that takes away mineral components from saline water. More generally, desalination refers to the removal of salts and minerals from a target substance, as in soil desalination, which is an issue for agriculture. Salt ...
exist, industrial brine treatment may contain unique combinations of dissolved ions, such as hardness ions or other metals, necessitating specific processes and equipment. Brine treatment systems are typically optimized to either reduce the volume of the final discharge for more economic disposal (as disposal costs are often based on volume) or maximize the recovery of fresh water or salts. Brine treatment systems may also be optimized to reduce electricity consumption, chemical usage, or physical footprint. Brine treatment is commonly encountered when treating cooling tower blowdown,
produced water Produced water is a term used in the oil industry or geothermal industry to describe water that is produced as a byproduct during the extraction of oil and natural gas, or used as a medium for heat extraction. Produced water is the kind of brackis ...
from steam-assisted gravity drainage (SAGD), produced water from
natural gas Natural gas (also called fossil gas or simply gas) is a naturally occurring mixture of gaseous hydrocarbons consisting primarily of methane in addition to various smaller amounts of other higher alkanes. Low levels of trace gases like carbon d ...
extraction such as
coal seam gas Coalbed methane (CBM or coal-bed methane), coalbed gas, coal seam gas (CSG), or coal-mine methane (CMM) is a form of natural gas extracted from coal beds. In recent decades it has become an important source of energy in United States, Canada, Au ...
, frac flowback water, acid mine or acid rock drainage, reverse osmosis reject, chlor-alkali wastewater, pulp and paper mill effluent, and waste streams from food and beverage processing. Brine treatment technologies may include: membrane filtration processes, such as
reverse osmosis Reverse osmosis (RO) is a water purification process that uses a partially permeable membrane to separate ions, unwanted molecules and larger particles from drinking water. In reverse osmosis, an applied pressure is used to overcome osmotic ...
;
ion-exchange Ion exchange is a reversible interchange of one kind of ion present in an insoluble solid with another of like charge present in a solution surrounding the solid with the reaction being used especially for softening or making water demineralised, ...
processes such as electrodialysis or weak acid cation exchange; or evaporation processes, such as brine concentrators and crystallizers employing mechanical vapour recompression and steam. Due to the ever increasing discharge standards, there has been an emergence of the use of advance oxidation processes for the treatment of brine. Some notable examples such as Fenton's oxidation and
ozonation Ozone (), or trioxygen, is an inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , breaking down in the lo ...
have been employed for degradation of recalcitrant compounds in brine from industrial plants. Reverse osmosis may not be viable for brine treatment, due to the potential for fouling caused by hardness salts or organic contaminants, or damage to the reverse osmosis membranes from
hydrocarbons In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ...
. Evaporation processes are the most widespread for brine treatment as they enable the highest degree of concentration, as high as solid salt. They also produce the highest purity effluent, even distillate-quality. Evaporation processes are also more tolerant of organics, hydrocarbons, or hardness salts. However, energy consumption is high and corrosion may be an issue as the prime mover is concentrated salt water. As a result, evaporation systems typically employ
titanium Titanium is a chemical element with the symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion i ...
or duplex stainless steel materials.


Brine management

Brine management examines the broader context of brine treatment and may include consideration of government policy and regulations, corporate sustainability, environmental impact, recycling, handling and transport, containment, centralized compared to on-site treatment, avoidance and reduction, technologies, and economics. Brine management shares some issues with leachate management and more general
waste management Waste management or waste disposal includes the processes and actions required to manage waste from its inception to its final disposal. This includes the collection, transport, treatment and disposal of waste, together with monitorin ...
. In the recent years, there has been greater prevalence in brine management due to global push for zero liquid discharge (ZLD)/minimal liquid discharge (MLD). In ZLD/MLD techniques, a closed water cycle is used to minimize water discharges from a system for
water reuse Water reclamation (also called wastewater reuse, water reuse or water recycling) is the process of converting municipal wastewater (sewage) or industrial wastewater into water that can be reused for a variety of purposes. Types of reuse include: ...
. This concept has been gaining traction in recent years, due to increased water discharges and recent advancement in membrane technology.


Solids removal

Most solids can be removed using simple sedimentation techniques with the solids recovered as slurry or sludge. Very fine solids and solids with densities close to the density of water pose special problems. In such case filtration or ultrafiltration may be required. Although
flocculation Flocculation, in the field of chemistry, is a process by which colloidal particles come out of suspension to sediment under the form of floc or flake, either spontaneously or due to the addition of a clarifying agent. The action differs from ...
may be used, using
alum An alum () is a type of chemical compound, usually a hydrated double sulfate salt of aluminium with the general formula , where is a monovalent cation such as potassium or ammonium. By itself, "alum" often refers to potassium alum, with the ...
salts or the addition of polyelectrolytes. Wastewater from industrial food processing often requires on-site treatment before it can be discharged to prevent or reduce sewer surcharge fees. The type of industry and specific operational practices determine what types of wastewater is generated and what type of treatment is required. Reducing solids such as waste product, organic materials, and sand is often a goal of industrial wastewater treatment. Some common ways to reduce solids include primary sedimentation (clarification), dissolved air flotation (DAF), belt filtration (microscreening), and drum screening.


Oils and grease removal

The effective removal of oils and grease is dependent on the characteristics of the oil in terms of its suspension state and droplet size, which will in turn affect the choice of separator technology. Oil in industrial waste water may be free light oil, heavy oil, which tends to sink, and emulsified oil, often referred to as soluble oil. Emulsified or soluble oils will typically required "cracking" to free the oil from its emulsion. In most cases this is achieved by lowering the pH of the water matrix. Most separator technologies will have an optimum range of oil droplet sizes that can be effectively treated. Each separator technology will have its own performance curve outlining optimum performance based on oil droplet size. the most common separators are gravity tanks or pits, API oil-water separators or plate packs, chemical treatment via dissolved air flotations, centrifuges, media filters and hydrocyclones. Analyzing the oily water to determine droplet size can be performed with a video particle analyser.


API oil-water separators


Hydrocyclone oil separators

Hydrocyclone oil separators operate on the process where wastewater enters the cyclone chamber and is spun under extreme centrifugal forces more than 1000 times the force of gravity. This force causes the water and oil droplets to separate. The separated oil is discharged from one end of the cyclone where treated water is discharged through the opposite end for further treatment, filtration or discharge.


Removal of biodegradable organics

Biodegradable organic material of plant or animal origin is usually possible to treat using extended conventional
sewage treatment Sewage treatment (or domestic wastewater treatment, municipal wastewater treatment) is a type of wastewater treatment which aims to remove contaminants from sewage to produce an effluent that is suitable for discharge to the surrounding en ...
processes such as activated sludge or trickling filter. Problems can arise if the wastewater is excessively diluted with washing water or is highly concentrated such as undiluted blood or milk. The presence of cleaning agents, disinfectants, pesticides, or antibiotics can have detrimental impacts on treatment processes.


Activated sludge process


Trickling filter process

A trickling filter consists of a bed of rocks,
gravel Gravel is a loose aggregation of rock fragments. Gravel occurs naturally throughout the world as a result of sedimentary and erosive geologic processes; it is also produced in large quantities commercially as crushed stone. Gravel is classifi ...
, slag,
peat moss ''Sphagnum'' is a genus of approximately 380 accepted species of mosses, commonly known as sphagnum moss, peat moss, also bog moss and quacker moss (although that term is also sometimes used for peat). Accumulations of ''Sphagnum'' can store wa ...
, or plastic media over which wastewater flows downward and contacts a layer (or film) of
microbial A microorganism, or microbe,, ''mikros'', "small") and ''organism'' from the el, ὀργανισμός, ''organismós'', "organism"). It is usually written as a single word but is sometimes hyphenated (''micro-organism''), especially in olde ...
slime covering the bed media. Aerobic conditions are maintained by forced air flowing through the bed or by natural convection of air. The process involves
adsorption Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the ''adsorbate'' on the surface of the ''adsorbent''. This process differs from absorption, in which a ...
of organic compounds in the wastewater by the microbial slime layer, diffusion of air into the slime layer to provide the oxygen required for the biochemical
oxidation Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or ...
of the organic compounds. The end products include
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is t ...
gas, water and other products of the oxidation. As the slime layer thickens, it becomes difficult for the air to penetrate the layer and an inner anaerobic layer is formed.


Removal of other organics

Synthetic organic materials including solvents, paints, pharmaceuticals, pesticides, products from coke production and so forth can be very difficult to treat. Treatment methods are often specific to the material being treated. Methods include
advanced oxidation process Advanced oxidation processes (AOPs), in a broad sense, are a set of chemical treatment procedures designed to remove organic (and sometimes inorganic) materials in water and wastewater by oxidation through reactions with hydroxyl radicals (·OH) ...
ing,
distillation Distillation, or classical distillation, is the process of separating the components or substances from a liquid mixture by using selective boiling and condensation, usually inside an apparatus known as a still. Dry distillation is the he ...
, adsorption, ozonation, vitrification, incineration, chemical immobilisation or landfill disposal. Some materials such as some detergents may be capable of biological degradation and in such cases, a modified form of wastewater treatment can be used.


Removal of acids and alkalis

Acids and alkalis can usually be neutralised under controlled conditions. Neutralisation frequently produces a precipitate that will require treatment as a solid residue that may also be toxic. In some cases, gases may be evolved requiring treatment for the gas stream. Some other forms of treatment are usually required following neutralisation. Waste streams rich in
hardness In materials science, hardness (antonym: softness) is a measure of the resistance to localized plastic deformation induced by either mechanical indentation or abrasion. In general, different materials differ in their hardness; for example hard ...
ions as from de-ionisation processes can readily lose the hardness ions in a buildup of precipitated calcium and magnesium salts. This precipitation process can cause severe ''furring'' of pipes and can, in extreme cases, cause the blockage of disposal pipes. A 1-metre diameter industrial marine discharge pipe serving a major chemicals complex was blocked by such salts in the 1970s. Treatment is by concentration of de-ionisation waste waters and disposal to landfill or by careful pH management of the released wastewater.


Removal of toxic materials

Toxic materials including many organic materials, metals (such as zinc, silver,
cadmium Cadmium is a chemical element with the Symbol (chemistry), symbol Cd and atomic number 48. This soft, silvery-white metal is chemically similar to the two other stable metals in group 12 element, group 12, zinc and mercury (element), mercury. Li ...
,
thallium Thallium is a chemical element with the symbol Tl and atomic number 81. It is a gray post-transition metal that is not found free in nature. When isolated, thallium resembles tin, but discolors when exposed to air. Chemists William Crookes an ...
, etc.) acids, alkalis, non-metallic elements (such as arsenic or selenium) are generally resistant to biological processes unless very dilute. Metals can often be precipitated out by changing the pH or by treatment with other chemicals. Many, however, are resistant to treatment or mitigation and may require concentration followed by landfilling or recycling. Dissolved organics can be ''incinerated'' within the wastewater by the advanced oxidation process.


Smart capsules

Molecular encapsulation is a technology that has the potential to provide a system for the recyclable removal of lead and other ions from polluted sources. Nano-, micro- and milli- capsules, with sizes in the ranges 10 nm–1μm,1μm–1mm and >1mm, respectively, are particles that have an active reagent (core) surrounded by a carrier (shell).There are three types of capsule under investigation: alginate-based capsules,
carbon nanotubes A scanning tunneling microscopy image of a single-walled carbon nanotube Rotating single-walled zigzag carbon nanotube A carbon nanotube (CNT) is a tube made of carbon with diameters typically measured in nanometers. ''Single-wall carbon na ...
, polymer swelling capsules. These capsules provide a possible means for the remediation of contaminated water.


Removal of thermal pollution

To remove heat from wastewater generated by power plants or manufacturing plants, and thus to reduce
thermal pollution Thermal pollution, sometimes called "thermal enrichment", is the degradation of water quality by any process that changes ambient water temperature. Thermal pollution is the rise or fall in the temperature of a natural body of water caused by hum ...
, the following technologies are used: *
cooling pond A cooling pond is a man-made body of water primarily formed for the purpose of cooling heated water and/or to store and supply cooling water to a nearby power plant or industrial facility such as a petroleum refinery, pulp and paper mill, chemica ...
s, engineered bodies of water designed for cooling by
evaporation Evaporation is a type of vaporization that occurs on the surface of a liquid as it changes into the gas phase. High concentration of the evaporating substance in the surrounding gas significantly slows down evaporation, such as when h ...
,
convection Convection is single or multiphase fluid flow that occurs spontaneously due to the combined effects of material property heterogeneity and body forces on a fluid, most commonly density and gravity (see buoyancy). When the cause of the c ...
, and
radiation In physics, radiation is the emission or transmission of energy in the form of waves or particles through space or through a material medium. This includes: * ''electromagnetic radiation'', such as radio waves, microwaves, infrared, visi ...
*
cooling tower A cooling tower is a device that rejects waste heat to the atmosphere through the cooling of a coolant stream, usually a water stream to a lower temperature. Cooling towers may either use the evaporation of water to remove process heat an ...
s, which transfer
waste heat Waste heat is heat that is produced by a machine, or other process that uses energy, as a byproduct of doing work. All such processes give off some waste heat as a fundamental result of the laws of thermodynamics. Waste heat has lower utilit ...
to the
atmosphere An atmosphere () is a layer of gas or layers of gases that envelop a planet, and is held in place by the gravity of the planetary body. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A ...
through
evaporation Evaporation is a type of vaporization that occurs on the surface of a liquid as it changes into the gas phase. High concentration of the evaporating substance in the surrounding gas significantly slows down evaporation, such as when h ...
or
heat transfer Heat transfer is a discipline of thermal engineering that concerns the generation, use, conversion, and exchange of thermal energy ( heat) between physical systems. Heat transfer is classified into various mechanisms, such as thermal conducti ...
*
cogeneration Cogeneration or combined heat and power (CHP) is the use of a heat engine or power station to generate electricity and useful heat at the same time. Cogeneration is a more efficient use of fuel or heat, because otherwise- wasted heat from elec ...
, a process where waste heat is recycled for domestic or industrial heating purposes.


Other disposal methods

Some facilities such as oil and gas wells may be permitted to pump their wastewater underground through injection wells. However, wastewater injection has been linked to
induced seismicity Induced seismicity is typically minor earthquakes and tremors that are caused by human activity that alters the stresses and strains on Earth's crust. Most induced seismicity is of a low magnitude. A few sites regularly have larger quakes, such a ...
.


Costs and trade waste charges

Disposal of wastewaters from an industrial plant is a difficult and costly problem. Although
economies of scale In microeconomics, economies of scale are the cost advantages that enterprises obtain due to their scale of operation, and are typically measured by the amount of output produced per unit of time. A decrease in cost per unit of output enables ...
may favor use of a large municipal sewage treatment plant for disposal of small volumes of industrial wastewater, industrial wastewater treatment and disposal may be less expensive than correctly apportioned costs for larger volumes of industrial wastewater not requiring the conventional sewage treatment sequence of a small municipal sewage treatment plant. Industrial wastewater plants may reduce raw water costs by converting selected wastewaters to reclaimed water used for different purposes. Industrial wastewater treatment plants may reduce wastewater treatment charges collected by municipal sewage treatment plants by pre-treating wastewaters to reduce concentrations of pollutants measured to determine user fees.


Society and culture


Global goals

The
international community The international community is an imprecise phrase used in geopolitics and international relations to refer to a broad group of people and governments of the world. As a rhetorical term Aside from its use as a general descriptor, the term is t ...
has defined the treatment of industrial wastewater as an important part of
sustainable development Sustainable development is an organizing principle for meeting human development goals while also sustaining the ability of natural systems to provide the natural resources and ecosystem services on which the economy and society depend. The ...
by including it in Sustainable Development Goal 6. Target 6.3 of this goal is to "By 2030, improve
water quality Water quality refers to the chemical, physical, and biological characteristics of water based on the standards of its usage. It is most frequently used by reference to a set of standards against which compliance, generally achieved through tr ...
by reducing
pollution Pollution is the introduction of contaminants into the natural environment that cause adverse change. Pollution can take the form of any substance (solid, liquid, or gas) or energy (such as radioactivity, heat, sound, or light). Pollutants, th ...
, eliminating dumping and minimizing release of hazardous chemicals and materials, halving the proportion of untreated wastewater and substantially increasing recycling and safe reuse globally". One of the indicators for this target is the "proportion of domestic and industrial wastewater flows safely treated".Ritchie, Roser, Mispy, Ortiz-Ospina.
Measuring progress towards the Sustainable Development Goals, Goal 6
''SDG-Tracker.org, website'' (2018).


See also

*
Best management practice for water pollution Best management practices (BMPs) is a term used in the United States and Canada to describe a type of water pollution control. Historically the term has referred to auxiliary pollution controls in the fields of industrial wastewater control an ...
(BMP) * List of waste water treatment technologies *
Purified water Purified water is water that has been mechanically filtered or processed to remove impurities and make it suitable for use. Distilled water was, formerly, the most common form of purified water, but, in recent years, water is more frequently pur ...
(for industrial use) * Water purification (for drinking water)


References


Further reading

*


External links


Water Environment Federation
- Professional society
Industrial Wastewater Treatment Technology Database
- EPA {{waste Waste treatment technology Sewerage Industrial processes Water pollution Sanitation cs:Čištění odpadních vod