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Technetium Technetium is a chemical element with the symbol Tc and atomic number 43. It is the lightest element whose isotopes are all radioactive. All available technetium is produced as a synthetic element. Naturally occurring technetium is a spontaneous ...
(43Tc) is one of the two elements with that have no stable
isotope Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers (mass numb ...
s; the other such element is promethium. – Elements marked with a * have no stable isotope: 43, 61, and 83 and up. It is primarily artificial, with only trace quantities existing in nature produced by spontaneous fission (there are an estimated grams of 99Tc per gram of
pitchblende Uraninite, formerly pitchblende, is a radioactive, uranium-rich mineral and ore with a chemical composition that is largely UO2 but because of oxidation typically contains variable proportions of U3O8. Radioactive decay of the uranium causes t ...
) or
neutron capture Neutron capture is a nuclear reaction in which an atomic nucleus and one or more neutrons collide and merge to form a heavier nucleus. Since neutrons have no electric charge, they can enter a nucleus more easily than positively charged protons, ...
by molybdenum. The first isotopes to be synthesized were 97Tc and 99Tc in 1936, the first artificial element to be produced. The most stable
radioisotope A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess nuclear energy, making it unstable. This excess energy can be used in one of three ways: emitted from the nucleus as gamma radiation; transferr ...
s are 97Tc (
half-life Half-life (symbol ) is the time required for a quantity (of substance) to reduce to half of its initial value. The term is commonly used in nuclear physics to describe how quickly unstable atoms undergo radioactive decay or how long stable at ...
of 4.21 million years), 98Tc (half-life: 4.2 million years), and 99Tc (half-life: 211,100 years). Thirty-three other radioisotopes have been characterized with
atomic mass The atomic mass (''m''a or ''m'') is the mass of an atom. Although the SI unit of mass is the kilogram (symbol: kg), atomic mass is often expressed in the non-SI unit dalton (symbol: Da) – equivalently, unified atomic mass unit (u). 1&nb ...
es ranging from 85Tc to 120Tc. Most of these have half-lives that are less than an hour; the exceptions are 93Tc (half-life: 2.75 hours), 94Tc (half-life: 4.883 hours), 95Tc (half-life: 20 hours), and 96Tc (half-life: 4.28 days). Technetium also has numerous meta states. 97mTc is the most stable, with a half-life of 91.0 days (0.097 MeV). This is followed by 95mTc (half-life: 61 days, 0.038 MeV) and 99mTc (half-life: 6.04 hours, 0.143 MeV). 99mTc only emits
gamma ray A gamma ray, also known as gamma radiation (symbol γ or \gamma), is a penetrating form of electromagnetic radiation arising from the radioactive decay of atomic nuclei. It consists of the shortest wavelength electromagnetic waves, typically ...
s, subsequently decaying to 99Tc. For isotopes lighter than 98Tc, the primary decay mode is
electron capture Electron capture (K-electron capture, also K-capture, or L-electron capture, L-capture) is a process in which the proton-rich nucleus of an electrically neutral atom absorbs an inner atomic electron, usually from the K or L electron shells. Thi ...
to
isotopes of molybdenum Molybdenum (42Mo) has 33 known isotopes, ranging in atomic mass from 83 to 115, as well as four metastable nuclear isomers. Seven isotopes occur naturally, with atomic masses of 92, 94, 95, 96, 97, 98, and 100. All unstable isotopes of molybdenu ...
. For the heavier isotopes, the primary mode is
beta emission In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which a beta particle (fast energetic electron or positron) is emitted from an atomic nucleus, transforming the original nuclide to an isobar of that nuclide. For exam ...
to
isotopes of ruthenium Naturally occurring ruthenium (44Ru) is composed of seven stable isotopes. Additionally, 27 radioactive isotopes have been discovered. Of these radioisotopes, the most stable are 106Ru, with a half-life of 373.59 days; 103Ru, with a half-life of 3 ...
, with the exception that 100Tc can decay both by beta emission and electron capture.
Technetium-99m Technetium-99m (99mTc) is a metastable nuclear isomer of technetium-99 (itself an isotope of technetium), symbolized as 99mTc, that is used in tens of millions of medical diagnostic procedures annually, making it the most commonly used medical ra ...
is the hallmark technetium isotope employed in the
nuclear medicine Nuclear medicine or nucleology is a medical specialty involving the application of radioactive substances in the diagnosis and treatment of disease. Nuclear imaging, in a sense, is " radiology done inside out" because it records radiation emi ...
industry. Its low-energy isomeric transition, which yields a gamma-ray at ~140.5 keV, is ideal for imaging using Single Photon Emission Computed Tomography (SPECT). Several technetium isotopes, such as 94mTc, 95gTc, and 96gTc, which are produced via (p,n) reactions using a
cyclotron A cyclotron is a type of particle accelerator invented by Ernest O. Lawrence in 1929–1930 at the University of California, Berkeley, and patented in 1932. Lawrence, Ernest O. ''Method and apparatus for the acceleration of ions'', filed: Jan ...
on molybdenum targets, have also been identified as potential Positron Emission Tomography (PET) agents. Technetium-101 has been produced using a D-D fusion-based
neutron generator Neutron generators are neutron source devices which contain compact linear particle accelerators and that produce neutrons by fusing isotopes of hydrogen together. The fusion reactions take place in these devices by accelerating either deu ...
from the 100Mo(n,γ)101Mo reaction on natural molybdenum and subsequent beta-minus decay of 101Mo to 101Tc. Despite its shorter-half life (i.e., 14.22 min), 101Tc exhibits unique decay characteristics suitable for radioisotope diagnostic or
therapeutic A therapy or medical treatment (often abbreviated tx, Tx, or Tx) is the attempted remediation of a health problem, usually following a medical diagnosis. As a rule, each therapy has indications and contraindications. There are many different ...
procedures, where it has been proposed that its implementation, as a supplement for dual-isotopic imaging or replacement for 99mTc, could be performed by on-site production and dispensing at the point of patient care.
Technetium-99 Technetium-99 (99Tc) is an isotope of technetium which decays with a half-life of 211,000 years to stable ruthenium-99, emitting beta particles, but no gamma rays. It is the most significant long-lived fission product of uranium fission, produci ...
is the most common and most readily available isotope, as it is a major fission product from fission of
actinide The actinide () or actinoid () series encompasses the 15 metallic chemical elements with atomic numbers from 89 to 103, actinium through lawrencium. The actinide series derives its name from the first element in the series, actinium. The info ...
s like
uranium Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weak ...
and
plutonium Plutonium is a radioactive chemical element with the symbol Pu and atomic number 94. It is an actinide metal of silvery-gray appearance that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibi ...
with a
fission product yield Nuclear fission splits a heavy nucleus such as uranium or plutonium into two lighter nuclei, which are called fission products. Yield refers to the fraction of a fission product produced per fission. Yield can be broken down by: # Individual ...
of 6% or more, and in fact the most significant long-lived fission product. Lighter isotopes of technetium are almost never produced in fission because the initial fission products normally have a higher neutron/proton ratio than is stable for their mass range, and therefore undergo
beta decay In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which a beta particle (fast energetic electron or positron) is emitted from an atomic nucleus, transforming the original nuclide to an isobar of that nuclide. For ...
until reaching the ultimate product. Beta decay of fission products of mass 95–98 stops at the stable
isotopes of molybdenum Molybdenum (42Mo) has 33 known isotopes, ranging in atomic mass from 83 to 115, as well as four metastable nuclear isomers. Seven isotopes occur naturally, with atomic masses of 92, 94, 95, 96, 97, 98, and 100. All unstable isotopes of molybdenu ...
of those masses and does not reach technetium. For mass 100 and greater, the technetium isotopes of those masses are very short-lived and quickly beta decay to
isotopes of ruthenium Naturally occurring ruthenium (44Ru) is composed of seven stable isotopes. Additionally, 27 radioactive isotopes have been discovered. Of these radioisotopes, the most stable are 106Ru, with a half-life of 373.59 days; 103Ru, with a half-life of 3 ...
. Therefore, the technetium in
spent nuclear fuel Spent nuclear fuel, occasionally called used nuclear fuel, is nuclear fuel that has been irradiated in a nuclear reactor (usually at a nuclear power plant). It is no longer useful in sustaining a nuclear reaction in an ordinary thermal reactor and ...
is practically all 99Tc. In the presence of
fast neutron The neutron detection temperature, also called the neutron energy, indicates a free neutron's kinetic energy, usually given in electron volts. The term ''temperature'' is used, since hot, thermal and cold neutrons are moderated in a medium with ...
s a small amount of will be produced by (n,2n) "knockout" reactions. If nuclear transmutation of fission-derived Technetium or Technetium waste from medical applications is desired, fast neutrons are therefore not desirable as the long lived increases rather than reducing the longevity of the radioactivity in the material. One gram of 99Tc produces disintegrations a second (that is, 0.62 G Bq/g). Technetium has no stable or nearly stable isotopes, and thus a standard atomic weight cannot be given.


List of isotopes

, - , rowspan=3, 85Tc , rowspan=3 style="text-align:right" , 43 , rowspan=3 style="text-align:right" , 42 , rowspan=3, 84.94883(43)# , rowspan=3, <110 ns , β+ , 85Mo , rowspan=3, 1/2−# , rowspan=3 , , - , p , 84Mo , - , β+, p , 84Nb , - , 86Tc , style="text-align:right" , 43 , style="text-align:right" , 43 , 85.94288(32)# , 55(6) ms , β+ , 86Mo , (0+) , , - , style="text-indent:1em" , 86mTc , colspan="3" style="text-indent:2em" , 1500(150) keV , 1.11(21) µs , , , (5+, 5−) , , - , 87Tc , style="text-align:right" , 43 , style="text-align:right" , 44 , 86.93653(32)# , 2.18(16) s , β+ , 87Mo , 1/2−# , , - , style="text-indent:1em" , 87mTc , colspan="3" style="text-indent:2em" , 20(60)# keV , 2# s , , , 9/2+# , , - , 88Tc , style="text-align:right" , 43 , style="text-align:right" , 45 , 87.93268(22)# , 5.8(2) s , β+ , 88Mo , (2, 3) , , - , style="text-indent:1em" , 88mTc , colspan="3" style="text-indent:2em" , 0(300)# keV , 6.4(8) s , β+ , 88Mo , (6, 7, 8) , , - , 89Tc , style="text-align:right" , 43 , style="text-align:right" , 46 , 88.92717(22)# , 12.8(9) s , β+ , 89Mo , (9/2+) , , - , style="text-indent:1em" , 89mTc , colspan="3" style="text-indent:2em" , 62.6(5) keV , 12.9(8) s , β+ , 89Mo , (1/2−) , , - , 90Tc , style="text-align:right" , 43 , style="text-align:right" , 47 , 89.92356(26) , 8.7(2) s , β+ , 90Mo , 1+ , , - , style="text-indent:1em" , 90mTc , colspan="3" style="text-indent:2em" , 310(390) keV , 49.2(4) s , β+ , 90Mo , (8+) , , - , 91Tc , style="text-align:right" , 43 , style="text-align:right" , 48 , 90.91843(22) , 3.14(2) min , β+ , 91Mo , (9/2)+ , , - , rowspan=2 style="text-indent:1em" , 91mTc , rowspan=2 colspan="3" style="text-indent:2em" , 139.3(3) keV , rowspan=2, 3.3(1) min , β+ (99%) , 91Mo , rowspan=2, (1/2)− , rowspan=2, , - , IT (1%) , 91Tc , - , 92Tc , style="text-align:right" , 43 , style="text-align:right" , 49 , 91.915260(28) , 4.25(15) min , β+ , 92Mo , (8)+ , , - , style="text-indent:1em" , 92mTc , colspan="3" style="text-indent:2em" , 270.15(11) keV , 1.03(7) µs , , , (4+) , , - , 93Tc , style="text-align:right" , 43 , style="text-align:right" , 50 , 92.910249(4) , 2.75(5) h , β+ , 93Mo , 9/2+ , , - , rowspan=2 style="text-indent:1em" , 93m1Tc , rowspan=2 colspan="3" style="text-indent:2em" , 391.84(8) keV , rowspan=2, 43.5(10) min , IT (76.6%) , 93Tc , rowspan=2, 1/2− , rowspan=2, , - , β+ (23.4%) , 93Mo , - , style="text-indent:1em" , 93m2Tc , colspan="3" style="text-indent:2em" , 2185.16(15) keV , 10.2(3) µs , , , (17/2)− , , - , 94Tc , style="text-align:right" , 43 , style="text-align:right" , 51 , 93.909657(5) , 293(1) min , β+ , 94Mo , 7+ , , - , rowspan=2 style="text-indent:1em" , 94mTc , rowspan=2 colspan="3" style="text-indent:2em" , 75.5(19) keV , rowspan=2, 52.0(10) min , β+ (99.9%) , 94Mo , rowspan=2, (2)+ , rowspan=2, , - , IT (.1%) , 94Tc , - , 95Tc , style="text-align:right" , 43 , style="text-align:right" , 52 , 94.907657(6) , 20.0(1) h , β+ , 95Mo , 9/2+ , , - , rowspan=2 style="text-indent:1em" , 95mTc , rowspan=2 colspan="3" style="text-indent:2em" , 38.89(5) keV , rowspan=2, 61(2) d , β+ (96.12%) , 95Mo , rowspan=2, 1/2− , rowspan=2, , - , IT (3.88%) , 95Tc , - , 96Tc , style="text-align:right" , 43 , style="text-align:right" , 53 , 95.907871(6) , 4.28(7) d , β+ , 96Mo , 7+ , , - , rowspan=2 style="text-indent:1em" , 96mTc , rowspan=2 colspan="3" style="text-indent:2em" , 34.28(7) keV , rowspan=2, 51.5(10) min , IT (98%) , 96Tc , rowspan=2, 4+ , rowspan=2, , - , β+ (2%) , 96Mo , - , 97Tc , style="text-align:right" , 43 , style="text-align:right" , 54 , 96.906365(5) , 4.21×106 y , EC , 97Mo , 9/2+ , , - , rowspan=2 style="text-indent:1em" , 97mTc , rowspan=2 colspan="3" style="text-indent:2em" , 96.56(6) keV , rowspan=2, 91.0(6) d , IT (99.66%) , 97Tc , rowspan=2, 1/2− , rowspan=2, , - , EC (.34%) , 97Mo , - , 98Tc , style="text-align:right" , 43 , style="text-align:right" , 55 , 97.907216(4) , 4.2×106 y , β , 98Ru , (6)+ , , - , style="text-indent:1em" , 98mTc , colspan="3" style="text-indent:2em" , 90.76(16) keV , 14.7(3) µs , , , (2)− , , - , 99Tc Long-lived fission product , style="text-align:right" , 43 , style="text-align:right" , 56 , 98.9062547(21) , 2.111(12)×105 y , β , 99Ru , 9/2+ , trace , - , rowspan=2 style="text-indent:1em" , 99mTcUsed in medicine , rowspan=2 colspan="3" style="text-indent:2em" , 142.6832(11) keV , rowspan=2, 6.0067(5) h , IT (99.99%) , 99Tc , rowspan=2, 1/2− , rowspan=2, , - , β (.0037%) , 99Ru , - , rowspan=2, 100Tc , rowspan=2 style="text-align:right" , 43 , rowspan=2 style="text-align:right" , 57 , rowspan=2, 99.9076578(24) , rowspan=2, 15.8(1) s , β (99.99%) , 100Ru , rowspan=2, 1+ , rowspan=2, , - , EC (.0018%) , ''100Mo'' , - , style="text-indent:1em" , 100m1Tc , colspan="3" style="text-indent:2em" , 200.67(4) keV , 8.32(14) µs , , , (4)+ , , - , style="text-indent:1em" , 100m2Tc , colspan="3" style="text-indent:2em" , 243.96(4) keV , 3.2(2) µs , , , (6)+ , , - , 101Tc , style="text-align:right" , 43 , style="text-align:right" , 58 , 100.907315(26) , 14.22(1) min , β , 101Ru , 9/2+ , , - , style="text-indent:1em" , 101mTc , colspan="3" style="text-indent:2em" , 207.53(4) keV , 636(8) µs , , , 1/2− , , - , 102Tc , style="text-align:right" , 43 , style="text-align:right" , 59 , 101.909215(10) , 5.28(15) s , β , 102Ru , 1+ , , - , rowspan=2 style="text-indent:1em" , 102mTc , rowspan=2 colspan="3" style="text-indent:2em" , 20(10) keV , rowspan=2, 4.35(7) min , β (98%) , 102Ru , rowspan=2, (4, 5) , rowspan=2, , - , IT (2%) , 102Tc , - , 103Tc , style="text-align:right" , 43 , style="text-align:right" , 60 , 102.909181(11) , 54.2(8) s , β , 103Ru , 5/2+ , , - , 104Tc , style="text-align:right" , 43 , style="text-align:right" , 61 , 103.91145(5) , 18.3(3) min , β , 104Ru , (3+)# , , - , style="text-indent:1em" , 104m1Tc , colspan="3" style="text-indent:2em" , 69.7(2) keV , 3.5(3) µs , , , 2(+) , , - , style="text-indent:1em" , 104m2Tc , colspan="3" style="text-indent:2em" , 106.1(3) keV , 0.40(2) µs , , , (+) , , - , 105Tc , style="text-align:right" , 43 , style="text-align:right" , 62 , 104.91166(6) , 7.6(1) min , β , 105Ru , (3/2−) , , - , 106Tc , style="text-align:right" , 43 , style="text-align:right" , 63 , 105.914358(14) , 35.6(6) s , β , 106Ru , (1, 2) , , - , 107Tc , style="text-align:right" , 43 , style="text-align:right" , 64 , 106.91508(16) , 21.2(2) s , β , 107Ru , (3/2−) , , - , style="text-indent:1em" , 107mTc , colspan="3" style="text-indent:2em" , 65.7(10) keV , 184(3) ns , , , (5/2−) , , - , 108Tc , style="text-align:right" , 43 , style="text-align:right" , 65 , 107.91846(14) , 5.17(7) s , β , 108Ru , (2)+ , , - , rowspan=2, 109Tc , rowspan=2 style="text-align:right" , 43 , rowspan=2 style="text-align:right" , 66 , rowspan=2, 108.91998(10) , rowspan=2, 860(40) ms , β (99.92%) , 109Ru , rowspan=2, 3/2−# , rowspan=2, , - , β, n (.08%) , 108Ru , - , rowspan=2, 110Tc , rowspan=2 style="text-align:right" , 43 , rowspan=2 style="text-align:right" , 67 , rowspan=2, 109.92382(8) , rowspan=2, 0.92(3) s , β (99.96%) , 110Ru , rowspan=2, (2+) , rowspan=2, , - , β, n (.04%) , 109Ru , - , rowspan=2, 111Tc , rowspan=2 style="text-align:right" , 43 , rowspan=2 style="text-align:right" , 68 , rowspan=2, 110.92569(12) , rowspan=2, 290(20) ms , β (99.15%) , 111Ru , rowspan=2, 3/2−# , rowspan=2, , - , β, n (.85%) , 110Ru , - , rowspan=2, 112Tc , rowspan=2 style="text-align:right" , 43 , rowspan=2 style="text-align:right" , 69 , rowspan=2, 111.92915(13) , rowspan=2, 290(20) ms , β (97.4%) , 112Ru , rowspan=2, 2+# , rowspan=2, , - , β, n (2.6%) , 111Ru , - , 113Tc , style="text-align:right" , 43 , style="text-align:right" , 70 , 112.93159(32)# , 170(20) ms , β , 113Ru , 3/2−# , , - , 114Tc , style="text-align:right" , 43 , style="text-align:right" , 71 , 113.93588(64)# , 150(30) ms , β , 114Ru , 2+# , , - , 115Tc , style="text-align:right" , 43 , style="text-align:right" , 72 , 114.93869(75)# , 100# ms 300 ns, β , 115Ru , 3/2−# , , - , 116Tc , style="text-align:right" , 43 , style="text-align:right" , 73 , 115.94337(75)# , 90# ms 300 ns, , , 2+# , , - , 117Tc , style="text-align:right" , 43 , style="text-align:right" , 74 , 116.94648(75)# , 40# ms 300 ns, , , 3/2−# , , - , 118Tc , style="text-align:right" , 43 , style="text-align:right" , 75 , 117.95148(97)# , 30# ms 300 ns, , , 2+# ,


Stability of technetium isotopes

Technetium and promethium are unusual light elements in that they have no stable isotopes. Using the
liquid drop model In nuclear physics, the semi-empirical mass formula (SEMF) (sometimes also called the Weizsäcker formula, Bethe–Weizsäcker formula, or Bethe–Weizsäcker mass formula to distinguish it from the Bethe–Weizsäcker process) is used to approxi ...
for atomic nuclei, one can derive a semiempirical formula for the binding energy of a nucleus. This formula predicts a " valley of beta stability" along which nuclides do not undergo beta decay. Nuclides that lie "up the walls" of the valley tend to decay by beta decay towards the center (by emitting an electron, emitting a positron, or capturing an electron). For a fixed number of nucleons ''A'', the binding energies lie on one or more
parabola In mathematics, a parabola is a plane curve which is Reflection symmetry, mirror-symmetrical and is approximately U-shaped. It fits several superficially different Mathematics, mathematical descriptions, which can all be proved to define exact ...
s, with the most stable nuclide at the bottom. One can have more than one parabola because isotopes with an even number of protons and an even number of neutrons are more stable than isotopes with an odd number of neutrons and an odd number of protons. A single beta decay then transforms one into the other. When there is only one parabola, there can be only one stable isotope lying on that parabola. When there are two parabolas, that is, when the number of nucleons is even, it can happen (rarely) that there is a stable nucleus with an odd number of neutrons and an odd number of protons (although this happens only in four instances: 2H, 6Li, 10B, and 14N). However, if this happens, there can be no stable isotope with an even number of neutrons and an even number of protons. (see
Beta-decay stable isobars Beta-decay stable isobars are the set of nuclides which cannot undergo beta decay, that is, the transformation of a neutron to a proton or a proton to a neutron within the nucleus. A subset of these nuclides are also stable with regards to dou ...
) For technetium (''Z'' = 43), the valley of beta stability is centered at around 98 nucleons. However, for every number of nucleons from 94 to 102, there is already at least one stable nuclide of either molybdenum (''Z'' = 42) or
ruthenium Ruthenium is a chemical element with the symbol Ru and atomic number 44. It is a rare transition metal belonging to the platinum group of the periodic table. Like the other metals of the platinum group, ruthenium is inert to most other chemical ...
(''Z'' = 44), and the Mattauch isobar rule states that two adjacent isobars cannot both be stable. For the isotopes with odd numbers of nucleons, this immediately rules out a stable isotope of technetium, since there can be only one stable nuclide with a fixed odd number of nucleons. For the isotopes with an even number of nucleons, since technetium has an odd number of protons, any isotope must also have an odd number of neutrons. In such a case, the presence of a stable nuclide having the same number of nucleons and an even number of protons rules out the possibility of a stable nucleus.''Radiochemistry and Nuclear Chemistry''


References

*Isotope masses from: ** *Isotopic compositions and standard atomic masses from: ** ** *Half-life, spin, and isomer data selected from. ** ** ** {{Navbox element isotopes Technetium
Technetium Technetium is a chemical element with the symbol Tc and atomic number 43. It is the lightest element whose isotopes are all radioactive. All available technetium is produced as a synthetic element. Naturally occurring technetium is a spontaneous ...