Iron bis(diethyldithiocarbamate) is a coordination complex with the formula where Et = . A red solid, it is representative of several ferrous dithiocarbamates with diverse substituents in place of ethyl. In terms of structure, the species is dimeric, consisting of two pentacoordinate iron(II) centers. It is isostructural with , which in turn is similar to zinc bis(dimethyldithiocarbamate).

Reactions

The complex reacts with a variety of reagents with concomitant formation of mono-iron derivatives. 9,10-

Phenanthroline 1,10-Phenanthroline (phen) is a heterocyclic organic compound. It is a white solid that is soluble in organic solvents. The 1,10 refer to the location of the nitrogen atoms that replace CH's in the hydrocarbon called phenanthrene. Abbreviated " ...

adds to iron bis(diethyldithiocarbamate) to give the blue-octahedral complex . 3,4-Bis(trifluoromethyl)-1,2-dithiete reacts to give the

dithiolene complex Dithiolene metal complexes are complexes containing 1,2-dithiolene ligands. 1,2-Dithiolene ligands, a particular case of 1,2-dichalcogenolene species, are unsaturated bidentate ligand wherein the two donor atoms are sulfur. 1,2-Dithiolene metal ...

Nitric oxide Nitric oxide (nitrogen oxide or nitrogen monoxide) is a colorless gas with the formula . It is one of the principal oxides of nitrogen. Nitric oxide is a free radical: it has an unpaired electron, which is sometimes denoted by a dot in its che ...

and carbon monoxide to give the

nitrosyl complex Sodium nitroprusside, a medicinally significant metal nitrosyl-pentacyanoferrate (Fe-III) compound, used to treat complexes that contain nitric oxide">hypertension. Metal nitrosyl complexes are complex (chemistry)">complexes that contain nitri ...

and the

carbonyl complex Metal carbonyls are coordination complexes of transition metals with carbon monoxide ligands. Metal carbonyls are useful in organic synthesis and as catalysts or catalyst precursors in homogeneous catalysis, such as hydroformylation and Reppe ch ...

{{chem2, Fe(S2CNEt2)2(CO)2, respectively.

Related compounds

Iron tris(diethyldithiocarbamate) Iron tris(diethyldithiocarbamate) is the coordination complex of iron with diethyldithiocarbamate with the formula Fe(S2CNEt2)3 (Et = ethyl). It is a black solid that is soluble in organic solvents. Synthesis, structure, bonding Iron tris(dithio ...

References

Iron compounds

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