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Iridescence (also known as goniochromism) is the phenomenon of certain surfaces that appear to gradually change
color Color (American English) or colour (British English) is the visual perceptual property deriving from the spectrum of light interacting with the photoreceptor cells of the eyes. Color categories and physical specifications of color are associ ...
as the angle of view or the angle of illumination changes. Examples of iridescence include
soap bubble A soap bubble is an extremely thin film of soap or detergent and water enclosing air that forms a hollow sphere with an iridescent surface. Soap bubbles usually last for only a few seconds before bursting, either on their own or on contact wi ...
s,
feather Feathers are epidermal growths that form a distinctive outer covering, or plumage, on both avian (bird) and some non-avian dinosaurs and other archosaurs. They are the most complex integumentary structures found in vertebrates and a premier ...
s,
butterfly Butterflies are insects in the macrolepidopteran clade Rhopalocera from the Order (biology), order Lepidoptera, which also includes moths. Adult butterflies have large, often brightly coloured wings, and conspicuous, fluttering flight. The ...
wings and seashell
nacre Nacre ( , ), also known as mother of pearl, is an organicinorganic composite material produced by some molluscs as an inner shell layer; it is also the material of which pearls are composed. It is strong, resilient, and iridescent. Nacre is f ...
, and minerals such as
opal Opal is a hydrated amorphous form of silica (SiO2·''n''H2O); its water content may range from 3 to 21% by weight, but is usually between 6 and 10%. Due to its amorphous property, it is classified as a mineraloid, unlike crystalline forms ...
. It is a kind of structural coloration that is due to
wave interference In physics, interference is a phenomenon in which two waves combine by adding their displacement together at every single point in space and time, to form a resultant wave of greater, lower, or the same amplitude. Constructive and destructive ...
of light in microstructures or
thin films A thin film is a layer of material ranging from fractions of a nanometer (monolayer) to several micrometers in thickness. The controlled synthesis of materials as thin films (a process referred to as deposition) is a fundamental step in many ap ...
. Pearlescence is a related effect where some or most of the reflected light is white. The term pearlescent is used to describe certain paint finishes, usually in the automotive industry, which actually produce iridescent effects.


Etymology

The word ''iridescence'' is derived in part from the Greek word ἶρις ''îris'' (
gen. The Book of Genesis (from Greek language, Greek ; Hebrew language, Hebrew: בְּרֵאשִׁית ''Bəreʾšīt'', "In hebeginning") is the first book of the Hebrew Bible and the Christian Old Testament. Its Hebrew name is the same as its i ...
ἴριδος ''íridos''), meaning '' rainbow'', and is combined with the Latin suffix ''-escent'', meaning "having a tendency toward". Iris in turn derives from the goddess Iris of
Greek mythology A major branch of classical mythology, Greek mythology is the body of myths originally told by the Ancient Greece, ancient Greeks, and a genre of Ancient Greek folklore. These stories concern the Cosmogony, origin and Cosmology#Metaphysical co ...
, who is the personification of the rainbow and acted as a messenger of the gods. ''Goniochromism'' is derived from the Greek words ''gonia'', meaning "angle", and ''chroma'', meaning "colour".


Mechanisms

Iridescence is an optical phenomenon of surfaces in which hue changes with the angle of observation and the angle of illumination. It is often caused by multiple reflections from two or more semi-transparent surfaces in which phase shift and
interference Interference is the act of interfering, invading, or poaching. Interference may also refer to: Communications * Interference (communication), anything which alters, modifies, or disrupts a message * Adjacent-channel interference, caused by extra ...
of the reflections modulates the incidental
light Light or visible light is electromagnetic radiation that can be perceived by the human eye. Visible light is usually defined as having wavelengths in the range of 400–700 nanometres (nm), corresponding to frequencies of 750–420 tera ...
(by amplifying or attenuating some frequencies more than others). The thickness of the layers of the material determines the interference pattern. Iridescence can for example be due to thin-film interference, the functional analogue of selective wavelength attenuation as seen with the
Fabry–Pérot interferometer In optics, a Fabry–Pérot interferometer (FPI) or etalon is an optical cavity made from two parallel reflecting surfaces (i.e.: thin mirrors). Optical waves can pass through the optical cavity only when they are in resonance with it. It is ...
, and can be seen in oil films on water and soap bubbles. Iridescence is also found in plants, animals and many other items. The range of colours of natural iridescent objects can be narrow, for example shifting between two or three colours as the viewing angle changes, Iridescence can also be created by
diffraction Diffraction is defined as the interference or bending of waves around the corners of an obstacle or through an aperture into the region of geometrical shadow of the obstacle/aperture. The diffracting object or aperture effectively becomes a s ...
. This is found in items like CDs, DVDs, some types of
prism Prism usually refers to: * Prism (optics), a transparent optical component with flat surfaces that refract light * Prism (geometry), a kind of polyhedron Prism may also refer to: Science and mathematics * Prism (geology), a type of sedimentary ...
s, or cloud iridescence. In the case of diffraction, the entire rainbow of colours will typically be observed as the viewing angle changes. In biology, this type of iridescence results from the formation of
diffraction grating In optics, a diffraction grating is an optical component with a periodic structure that diffracts light into several beams travelling in different directions (i.e., different diffraction angles). The emerging coloration is a form of structura ...
s on the surface, such as the long rows of cells in striated muscle, or the specialized abdominal scales of
peacock spider ''Maratus'' is a spider genus of the family Salticidae (jumping spiders). These spiders are commonly referred to as peacock spiders due to the males' colorful and usually iridescent patterns on the upper surface of the abdomen often enhanced with ...
''Maratus robinsoni'' and ''M. chrysomelas''. Some types of flower petals can also generate a diffraction grating, but the iridescence is not visible to humans and flower-visiting insects as the diffraction signal is masked by the coloration due to
plant pigments Biological pigments, also known simply as pigments or biochromes, are substances produced by living organisms that have a color resulting from selective Absorption (electromagnetic radiation), color absorption. Biological pigments include plant ...
. In biological (and biomimetic) uses, colours produced other than with
pigment A pigment is a colored material that is completely or nearly insoluble in water. In contrast, dyes are typically soluble, at least at some stage in their use. Generally dyes are often organic compounds whereas pigments are often inorganic compo ...
s or
dye A dye is a colored substance that chemically bonds to the substrate to which it is being applied. This distinguishes dyes from pigments which do not chemically bind to the material they color. Dye is generally applied in an aqueous solution an ...
s are called structural coloration. Microstructures, often multilayered, are used to produce bright but sometimes non-iridescent colours: quite elaborate arrangements are needed to avoid reflecting different colours in different directions. Structural coloration has been understood in general terms since
Robert Hooke Robert Hooke FRS (; 18 July 16353 March 1703) was an English polymath active as a scientist, natural philosopher and architect, who is credited to be one of two scientists to discover microorganisms in 1665 using a compound microscope that ...
's 1665 book '' Micrographia'', where Hooke correctly noted that since the iridescence of a
peacock Peafowl is a common name for three bird species in the genera ''Pavo (genus), Pavo'' and ''Afropavo'' within the tribe Pavonini of the family Phasianidae, the pheasants and their allies. Male peafowl are referred to as peacocks, and female pea ...
's feather was lost when it was plunged into water, but reappeared when it was returned to the air, pigments could not be responsible.Hooke, Robert. Micrographia. Chapter 36 ('Observ. XXXVI. ''Of Peacoks, Ducks, and Other Feathers of Changeable Colours''.') It was later found that iridescence in the peacock is due to a complex photonic crystal.


Pearlescence

Pearlescence is an effect related to iridescence and has a similar cause. Structures within a surface cause light to be reflected back, but in the case of pearlescence some or most of the light is white, giving the object a
pearl A pearl is a hard, glistening object produced within the soft tissue (specifically the mantle) of a living shelled mollusk or another animal, such as fossil conulariids. Just like the shell of a mollusk, a pearl is composed of calcium carb ...
-like luster. Artificial pigments and paints showing an iridescent effect are often described as pearlescent, for example when used for
car paint Automotive paint is paint used on automobiles for both protective and decorative purposes. Water-based Acrylate polymer, acrylic polyurethane enamel paint is currently the most widely used paint for reasons including reducing paint's Environmenta ...
s.


Examples


Life


Invertebrates

File:Iridescent Insect Display.png, Cornell drawer displaying iridescent insects File:Female Golden Stag Beetle.jpg, The iridescent exoskeleton of a golden
stag beetle Stag beetles are a family of about 1,200 species of beetles in the family Lucanidae, currently classified in four subfamilies.Smith, A.B.T. (2006). A review of the family-group names for the superfamily Scarabaeoidea (Coleoptera) with corrections ...
File:Morpho didius Male Dos MHNT.jpg, Structurally coloured wings of '' Morpho didius'' File:Haliotis iris LC0283.jpg, The inside surface of '' Haliotis iris'', the paua shell


Vertebrates

The
feather Feathers are epidermal growths that form a distinctive outer covering, or plumage, on both avian (bird) and some non-avian dinosaurs and other archosaurs. They are the most complex integumentary structures found in vertebrates and a premier ...
s of birds such as kingfishers, birds-of-paradise,
hummingbird Hummingbirds are birds native to the Americas and comprise the biological family Trochilidae. With about 361 species and 113 genera, they occur from Alaska to Tierra del Fuego, but the vast majority of the species are found in the tropics aro ...
s, parrots, starlings, grackles,
duck Duck is the common name for numerous species of waterfowl in the family Anatidae. Ducks are generally smaller and shorter-necked than swans and geese, which are members of the same family. Divided among several subfamilies, they are a form t ...
s, and
peacock Peafowl is a common name for three bird species in the genera ''Pavo (genus), Pavo'' and ''Afropavo'' within the tribe Pavonini of the family Phasianidae, the pheasants and their allies. Male peafowl are referred to as peacocks, and female pea ...
s are iridescent. The lateral line on the
neon tetra The neon tetra (''Paracheirodon innesi'') is a Freshwater fish of the characin family (family Characidae) of order Characiformes. The type species of its genus, it is native to blackwater and clearwater streams in the Amazon basin of South Am ...
is also iridescent. A single iridescent species of gecko, '' Cnemaspis kolhapurensis'', was identified in India in 2009. The tapetum lucidum, present in the
eye Eyes are organs of the visual system. They provide living organisms with vision, the ability to receive and process visual detail, as well as enabling several photo response functions that are independent of vision. Eyes detect light and conv ...
s of many vertebrates, is also iridescent. Iridescence is known to be present among non-avian dinosaurs such as
dromaeosaurids Dromaeosauridae () is a family of feathered theropod dinosaurs. They were generally small to medium-sized feathered carnivores that flourished in the Cretaceous Period. The name Dromaeosauridae means 'running lizards', from Greek ('), meaning ...
,
enantiornithes The Enantiornithes, also known as enantiornithines or enantiornitheans in literature, are a group of extinct avialans ("birds" in the broad sense), the most abundant and diverse group known from the Mesozoic era. Almost all retained teeth and cla ...
, and lithornithids. File:Peacock 2.jpg, Both the body and the train of the peacock are iridescent File:NeonTetra.JPG, A
neon tetra The neon tetra (''Paracheirodon innesi'') is a Freshwater fish of the characin family (family Characidae) of order Characiformes. The type species of its genus, it is native to blackwater and clearwater streams in the Amazon basin of South Am ...
File:Rainbow boa peruvian.jpg, The
rainbow boa The rainbow boa (''Epicrates cenchria'') is a boa species endemic to Central and South America. A semi-arboreal species (not only do they climb in they wild but also proven in captivity), it is known for its attractive iridescent/holographic sh ...
File:Nicobar Pigeon 820.jpg, Nicobar pigeon


Plants

Many groups of plants have developed iridescence as an adaptation to use more light in dark environments such as the lower levels of tropical forests. The leaves of Southeast Asia's ''
Begonia pavonina ''Begonia pavonina'', or peacock begonia, is a species of rhizomatous plant in the family Begoniaceae. It is endemic to the dim understory in the montane forests of peninsular Malaysia Peninsular Malaysia ( ms, Semenanjung Malaysia; Jawi: ...
'', or peacock begonia, appear iridescent azure to human observers due to each leaf's thinly layered photosynthetic structures called iridoplasts that absorb and bend light much like a film of oil over water. Iridescences based on multiple layers of cells are also found in the lycophyte ''
Selaginella ''Selaginella'' is the sole genus of vascular plants in the family Selaginellaceae, the spikemosses or lesser clubmosses. This family is distinguished from Lycopodiaceae (the clubmosses) by having scale-leaves bearing a ligule and by having ...
'' and several species of ferns. File:Iridescent begonia.jpg, Iridescent ''
Begonia ''Begonia'' is a genus of perennial flowering plants in the family Begoniaceae. The genus contains more than 2,000 different plant species. The Begonias are native to moist subtropical and tropical climates. Some species are commonly grown ind ...
'' leaf


Meat

File:Meat Iridiscence.png, Iridescence in meat, caused by light
diffraction Diffraction is defined as the interference or bending of waves around the corners of an obstacle or through an aperture into the region of geometrical shadow of the obstacle/aperture. The diffracting object or aperture effectively becomes a s ...
on the exposed muscle cells


Minerals and compounds

File:Wismut Kristall und 1cm3 Wuerfel.jpg, A bismuth crystal with a thin iridescent layer of bismuth oxide, with a whitish-silver bismuth cube for comparison File:Goethite-171990.jpg, Goethite, an
iron(III) oxide-hydroxide Iron(III) oxide-hydroxide or ferric oxyhydroxideA. L. Mackay (1960): "β-Ferric Oxyhydroxide". ''Mineralogical Magazine'' (''Journal of the Mineralogical Society''), volume 32, issue 250, pages 545-557. is the chemical compound of iron, oxygen, ...
, from
Polk County, Arkansas Polk County is a county located in the U.S. state of Arkansas. As of the 2010 census, the population was 20,662. The county seat is Mena. Polk County is Arkansas's 48th county, formed on November 30, 1844; it was named for James K. Polk, 11th P ...
File:Ladrador iridescence.jpg, Polished labradorite File:Engine oil rainbow p1120058.jpg, An engine oil spill File:Irid clouds1.jpg, Cloud iridescence


Man-made objects

File:Pearlescent Toyota Supra - 002.jpg,
Pearlescent paint Iridescence (also known as goniochromism) is the phenomenon of certain surfaces that appear to gradually change color as the angle of view or the angle of illumination changes. Examples of iridescence include soap bubbles, feathers, butterfly ...
job on a Toyota Supra car File:CD-ROM.png, Playing surface of a
compact disc The compact disc (CD) is a Digital media, digital optical disc data storage format that was co-developed by Philips and Sony to store and play digital audio recordings. In August 1982, the first compact disc was manufactured. It was then rele ...
File:Glitter nail polish %28purple%29.jpg, Iridescent
glitter Glitter is an assortment of small, reflective particles that come in a variety of shapes, sizes, and colors. Glitter particles reflect light at different angles, causing the surface to sparkle or shimmer. Glitter is similar to confetti, sparkle ...
nail polish Nail polish (also known as nail varnish or nail enamel) is a lacquer that can be applied to the human fingernail or toenails to decorate and protect the nail plates. The formula has been revised repeatedly to enhance its decorative properties ...
File:Samsung Galaxy A50 back 2.jpg,
Smartphone A smartphone is a portable computer device that combines mobile telephone and computing functions into one unit. They are distinguished from feature phones by their stronger hardware capabilities and extensive mobile operating systems, whic ...
with iridescent back panel
Nanocellulose Nanocellulose is a term referring to nano-structured cellulose. This may be either cellulose nanocrystal (CNC or NCC), cellulose nanofibers (CNF) also called nanofibrillated cellulose (NFC), or bacterial nanocellulose, which refers to nano-struc ...
is sometimes iridescent, as are thin films of
gasoline Gasoline (; ) or petrol (; ) (see ) is a transparent, petroleum-derived flammable liquid that is used primarily as a fuel in most spark-ignited internal combustion engines (also known as petrol engines). It consists mostly of organic co ...
and some other
hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ex ...
s and
alcohol Alcohol most commonly refers to: * Alcohol (chemistry), an organic compound in which a hydroxyl group is bound to a carbon atom * Alcohol (drug), an intoxicant found in alcoholic drinks Alcohol may also refer to: Chemicals * Ethanol, one of sev ...
s when floating on water. To create jewelry with crystal glass that lets light refract in a rainbow spectrum,
Swarovski Swarovski (, ) is an Austrian producer of glass based in Wattens, Austria, and has existed as a family-owned business since its founding in 1895 by Daniel Swarovski. The company is split into three major industry areas: the Swarovski Crystal ...
coats some of its products with special metallic chemical coatings. For example, its ''Aurora Borealis'' gives the surface a rainbow appearance.
Optically variable ink Optically variable ink (OVI) also called color shifting ink is an anti- counterfeiting measure used on many major modern banknotes, as well as on other official documents ( professional licenses, for example). The ink displays two distinct colo ...
uses finely powdered iridescent glitter.


See also

* Anisotropy *
Bioluminescence Bioluminescence is the production and emission of light by living organisms. It is a form of chemiluminescence. Bioluminescence occurs widely in marine vertebrates and invertebrates, as well as in some fungi, microorganisms including some b ...
, irrespective of angle *
Dichroic filter A dichroic filter, thin-film filter, or interference filter is a color filter used to selectively pass light of a small range of colors while reflecting other colors. By comparison, dichroic mirrors and dichroic reflectors tend to be characteriz ...
*
Dichroism In optics, a dichroic material is either one which causes visible light to be split up into distinct beams of different wavelengths (colours) (not to be confused with dispersion), or one in which light rays having different polarizations are abs ...
*
Iridocyte Chromatophores are cells that produce color, of which many types are Biological pigment, pigment-containing cells, or groups of cells, found in a wide range of animals including amphibians, fish, reptiles, crustaceans and cephalopods. Mammals and ...
*
Labradorescence Labradorite (( Ca, Na)( Al, Si)4 O8) is a calcium-enriched feldspar mineral first identified in Labrador, Canada, which can display an iridescent effect ( schiller). Labradorite is an intermediate to calcic member of the plagioclase series. I ...
(Adularescence) *
Metallic color A metallic color is a color that appears to be that of a polished metal. The visual sensation usually associated with metals is its metallic shine. This cannot be reproduced by a simple solid color, because the shiny effect is due to the mater ...
*
Opalescence Opalescence refers to the optical phenomena displayed by the mineraloid gemstone opalopalescent. 2019. In Noah Webster's 1828 American Dictionary of the English Language. Retrieved January 7, 2019, from https://1828.mshaffer.com/d/word/opalesc ...
* Structural color *
Thin-film optics Thin-film optics is the branch of optics that deals with very thin structured layers of different materials. In order to exhibit thin-film optics, the thickness of the layers of material must be similar to the coherence length; for visible l ...
*
Nacre Nacre ( , ), also known as mother of pearl, is an organicinorganic composite material produced by some molluscs as an inner shell layer; it is also the material of which pearls are composed. It is strong, resilient, and iridescent. Nacre is f ...
*
Opal Opal is a hydrated amorphous form of silica (SiO2·''n''H2O); its water content may range from 3 to 21% by weight, but is usually between 6 and 10%. Due to its amorphous property, it is classified as a mineraloid, unlike crystalline forms ...


References


External links


A 2.2 MB GIF animation
of a morpho butterfly showing iridescence
"Article on butterfly iridescence"
{{Webarchive, url=https://web.archive.org/web/20151107012605/http://www.physics.org/featuredetail.asp?NewsId=22 , date=2015-11-07 Optics Optical phenomena Color